A kind of puerarin freeze-dried Pickering emulsion and preparation method thereof
A technology of Pickering emulsion and puerarin, which is applied in the direction of freeze-drying transportation, pharmaceutical formula, emulsion transportation, etc. It can solve the problems of poor stability and achieve the effect of good stability and easy transportation and storage
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Embodiment 1
[0039] Weigh 350mg of puerarin, add 63mL of water phase (with 1mol L -1 The pH of the aqueous phase adjusted by sodium hydroxide is 11.5), 19000rpm high-speed shearing 2min, 800bar high-pressure homogenization 3min, then measure 7mL oil phase (chuanxiong oil: oleic acid macrogolglyceride=9:1, v / v ), added in a high-pressure homogenizer, 80MPa continued homogenization for 3min, and obtained puerarin nanocrystal self-stabilizing Pickering emulsion.
[0040] Take 2 mL of newly prepared puerarin nanocrystalline self-stabilizing Pickering emulsion and add it to a vial, add 0.16 g (8%) of lyoprotectant (trehalose, maltose), mix well, and process according to the following process conditions respectively , to obtain the puerarin freeze-dried emulsion.
[0041] Process A: Pre-freeze at -40°C for 6 hours, then sublimate and dry according to the following procedures: -40°C for 18h, -15°C for 6h, 0°C for 4h, 15°C for 4h, and the vacuum degree is lower than 5Pa.
[0042] Process B: Pre-...
Embodiment 2
[0049] Weigh 350mg of puerarin, add 63mL of the water phase (use 1mol L-1 sodium hydroxide to adjust the pH of the water phase to 11.5), high-speed shear at 19000rpm for 2min, and high-pressure homogenization at 800bar for 3min, then measure 7mL of the oil phase (Chuanxiong Oil: oleic acid polyethylene glycol glyceride=9:1, v / v), add in the high-pressure homogenizer, 80MPa continues homogeneous 3min, obtains puerarin nanocrystal self-stabilizing Pickering emulsion (puerarin nanocrystal self-stabilizing Stabilized Pickering Emulsion).
[0050] Take 2 mL of newly prepared puerarin nanocrystalline self-stabilizing Pickering emulsion and add it to a vial, add different kinds of compatible freeze-drying protectants, trehalose, maltose and HPMC K4M, HP-β-CYD and PVP K30 respectively by 1 : 1 ratio, the dosage is 8%, mixed evenly, pre-frozen at -80°C for 24 hours, sublimated and dried according to the following procedure: 10°C for 15 hours, and the vacuum degree is lower than 5Pa to ...
Embodiment 3
[0057] Weigh 350mg of puerarin, add 63mL of the water phase (use 1mol L-1 sodium hydroxide to adjust the pH of the water phase to 11.5), high-speed shear at 19000rpm for 2min, and high-pressure homogenization at 800bar for 3min, then measure 7mL of the oil phase (Chuanxiong Oil: oleic acid polyethylene glycol glyceride=9:1, v / v), add in the high-pressure homogenizer, 80MPa continues homogeneous 3min, obtains puerarin nanocrystal self-stabilizing Pickering emulsion (puerarin nanocrystal self-stabilizing Stabilized Pickering Emulsion).
[0058] Take 2 mL of newly prepared puerarin nanocrystalline self-stabilizing Pickering emulsion and add it to a vial, and mix maltose, trehalose and PVP K30 at 1:1, 2:1, 4:1, 8:1 and 16:1 respectively , added at 4%, 8% and 12%, mixed evenly, pre-frozen at -80°C for 24 hours, sublimated and dried according to the following procedure: 10°C for 15 hours, and the vacuum degree was lower than 5Pa to obtain a puerarin freeze-dried emulsion.
[0059] ...
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