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Low-initial adhesion high-holding adhesion paint protective film and application thereof

A technology for protective film and paint surface, which is applied in the direction of adhesives, adhesive types, pressure-sensitive films/sheets, etc. It can solve the problems of large attenuation of holding force, low holding force, low initial tack, etc., and achieve sticking Effects of reduced force decay, low initial tack, and high holding power

Inactive Publication Date: 2019-10-18
宁波激智创新材料研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the problems of high initial tack and large attenuation of holding power of the current paint protection film during use, the present invention provides a paint protection film with low initial tack and high stickiness
The paint protective film with low initial tack and high stickiness prepared by the present invention not only has higher light transmittance and ultraviolet absorption rate, but also has low initial tack, so that it has good workability and less decay of stickiness, that is, it has Excellent performance such as high sticking force, solves the problems of high initial sticking force and large sticking force attenuation (that is, low sticking force) of the current paint protection film during use

Method used

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  • Low-initial adhesion high-holding adhesion paint protective film and application thereof
  • Low-initial adhesion high-holding adhesion paint protective film and application thereof
  • Low-initial adhesion high-holding adhesion paint protective film and application thereof

Examples

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preparation example Construction

[0074] A kind of preparation method of the paint protective film with low initial viscosity and high stickiness provided by the invention comprises the steps:

[0075] a. Accurately weigh and add to the organic solvent according to the parts by weight of each component of the pressure-sensitive adhesive layer, and stir evenly to obtain the pressure-sensitive adhesive glue coating liquid;

[0076] b. Apply thermosetting self-repairing glue evenly on the upper surface of the substrate layer, and then bake in an oven at a temperature of 40-125°C to form a self-repairing layer on the upper surface of the substrate layer to obtain a paint surface semi-finished protective film;

[0077] c. Coat the pressure-sensitive adhesive glue coating solution on the lower surface of the base material layer of the semi-finished product, and then bake in an oven at a temperature of 40-150°C to form a pressure-sensitive adhesive layer on the lower surface of the base material layer of the semi-fin...

Embodiment 1

[0085] The present invention provides a low initial viscosity and high stickiness paint surface protection film and a preparation method thereof, wherein the low initial viscosity and high stickiness paint surface protection film comprises a self-repairing layer, a substrate layer and a pressure-sensitive adhesive layer; wherein The self-healing layer is provided on one side of the substrate layer, and the pressure-sensitive adhesive layer is provided on the other side of the substrate layer.

[0086] The raw material of the pressure-sensitive adhesive layer is composed of the following materials: crystalline hydroxyl polyurethane resin: 26 parts by weight; polyol resin: 36 parts by weight; crosslinking agent: 7 parts by weight; tackifying resin: 30 parts by weight; : 0.5 parts by weight; UV absorber: 0.5 parts by weight; wherein the crystalline hydroxyl polyurethane resin is UXP2702 of Covestro Company, and its crystallization time is 120h; the polyol resin is UXP2702 of Coves...

Embodiment 2

[0093] The raw material of the pressure-sensitive adhesive layer of the paint protective film with low initial viscosity and high stickiness described in Example 1 is made up of the following materials: crystalline hydroxyl polyurethane resin: 15 parts by weight; polyol resin: 55 parts by weight; Joint agent: 2 parts by weight; Tackifying resin: 24 parts by weight; Antioxidant: 1.0 parts by weight; Ultraviolet absorber: 1.0 parts by weight; Wherein the crystalline hydroxyl polyurethane resin is 213-1 of Covestro Company, and its crystallization time is 55h; the polyol resin is AV 2113 of Covestro, and its number average molecular weight is 1650; the crosslinking agent is hexamethylene diisocyanate (HDI); the tackifying resin is terpene-phenol resin; Phosphate ester; UV absorber is formamidine UV absorber. Wherein, the molar ratio of hydroxyl groups to isocyanate groups in the raw material of the pressure-sensitive adhesive layer -OH / -NCO=1.30.

[0094] Wherein, the organic so...

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Abstract

The invention relates to the field of functional films, in particular to a low-initial adhesion high-holding adhesion paint protective film and application thereof. The low-initial adhesion high-holding adhesion paint protective film is to solve the problems of high initial adhesion, poor construction and damped holding adhesion of a current paint protective film in the using process. The low-initial adhesion high-holding adhesion paint protective film comprises a self-repairing layer, a base material layer and a pressure-sensitive adhesive layer; and a raw material of the pressure-sensitive adhesive layer is prepared from the following materials in parts by weight: 30-48 parts of crystalline hydroxyl polyurethane resin, 5-32 parts of pokyhydric alcohol resin, 15-40 parts of tackifying resin, 0.5-10 parts of a cross-linking agent, 0.5-3 parts of an ultraviolet light absorber and 0.5-3 parts of an antioxidant. The paint protective film has higher light transmittance and ultraviolet light absorptivity, and has the excellent properties of the low-initial adhesion, the high-holding adhesion and the like at the same time. The low-initial adhesion high-holding adhesion paint protective film is simple in preparation technology, easy in operation, and convenient in industrial production.

Description

technical field [0001] The invention relates to the field of functional films, more specifically, to a paint surface protective film with low initial viscosity and high stickiness and application thereof. Background technique [0002] With the development of economy, China has become the world's largest automobile consumer. More and more cars have entered thousands of households. Simultaneously rising with the automobile consumer market is the automobile maintenance market. [0003] Paint Protective Film (PPF for short), also known as "invisible car cover", is a layer of transparent protective film attached to the surface of the car body. Its main function is to protect the original car paint of the car from damage. This product not only has strong toughness, but also has a self-repair function, which can effectively prevent scratches and sand hits, and also isolates the contact between the car paint and the air, and can prevent acid rain, asphalt, bird droppings, etc. fro...

Claims

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Application Information

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IPC IPC(8): C09J7/24C09J7/25C09J7/38C09J175/04C09J11/08C09J11/06C08J7/04C09D175/04C08L27/06C08L75/04
CPCC09J7/245C09J7/25C09J7/38C09J175/04C09J11/08C09J11/06C09D175/04C08J2327/06C08J2475/04C08J2375/04C09J2427/006C09J2475/006C09J2475/00C09J2301/122C09J2301/302C08J7/0427C08L23/22C08K5/3475C08L93/04C08K5/29
Inventor 唐海江任远飞薛永富徐升杨科彦李旭李刚张彦
Owner 宁波激智创新材料研究院有限公司
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