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A kind of graphene oxide conductive glass and preparation method thereof

A technology of conductive glass and graphene, which is applied in computer materials science, instruments, coatings, etc., can solve the problems of complex preparation process and high cost of conductive glass, and achieve the effect of shortening the exploration process, low production cost and simple process

Active Publication Date: 2022-01-04
JIAXING UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to solve the problem of complex preparation process and high cost of conductive glass in the prior art, and to provide a graphene oxide conductive glass and its preparation method

Method used

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  • A kind of graphene oxide conductive glass and preparation method thereof
  • A kind of graphene oxide conductive glass and preparation method thereof
  • A kind of graphene oxide conductive glass and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] A kind of preparation of graphene oxide conductive glass, concrete steps are as follows:

[0056] (1) Glass surface impurity removal treatment: soak the glass in acetone, ultrasonically treat it for 30 minutes at a temperature of 20°C, and then clean and dry the glass with deionized water;

[0057] (2) Hydrophilic treatment of the glass surface: first soak the glass in a hydrophilic treatment solution (a mixture of NaOH, ethanol and water), ultrasonically treat it for 60 minutes at a temperature of 20°C, and then leave the glass in the hydrophilic treatment solution. liquid, and the hydrophilic treatment solution was sealed and left for 6 hours, and finally the glass was washed and dried with deionized water, wherein the mass volume ratio of NaOH, ethanol and water was 1.0g:60mL:40mL;

[0058] (3) Dip-coating the graphene oxide dispersion on the glass surface: first soak the glass in the graphene oxide dispersion, ultrasonically treat it for 15 minutes at a temperature ...

Embodiment 2

[0070] A kind of preparation of graphene oxide conductive glass, concrete steps are as follows:

[0071] (1) Glass surface removal treatment: soak the glass in acetone, ultrasonically treat it for 10 minutes at a temperature of 20°C, and then clean and dry the glass with deionized water;

[0072] (2) Hydrophilic treatment of the glass surface: first soak the glass in a hydrophilic treatment solution (a mixture of NaOH, ethanol and water), ultrasonically treat it for 30 minutes at a temperature of 20°C, and then leave the glass in the hydrophilic treatment solution. liquid, and the hydrophilic treatment solution was sealed and left for 6 hours, and finally the glass was washed and dried with deionized water, wherein the mass volume ratio of NaOH, ethanol and water was 1.0g:60mL:40mL;

[0073] (3) Dip-coating the graphene oxide dispersion on the glass surface: first soak the glass in the graphene oxide dispersion, ultrasonically treat it for 3 minutes at a temperature of 20°C, a...

Embodiment 3

[0079] A kind of preparation of graphene oxide conductive glass, concrete steps are as follows:

[0080] (1) Glass surface impurity removal treatment: first soak the glass in ethanol, ultrasonically treat it for 16 minutes at a temperature of 22°C, and then clean and dry the glass with deionized water;

[0081] (2) Hydrophilic treatment of the glass surface: first soak the glass in a hydrophilic treatment solution (a mixture of NaOH, ethanol and water), ultrasonically treat it for 36 minutes at a temperature of 24°C, and then leave the glass in the hydrophilic treatment solution. liquid, and seal the hydrophilic treatment solution for 9 hours, and finally wash and dry the glass with deionized water, wherein the mass volume ratio of NaOH, ethanol and water is 1.0g:60mL:40mL;

[0082] (3) Dip-coating the graphene oxide dispersion on the glass surface: first soak the glass in the graphene oxide dispersion, ultrasonically treat it for 5 minutes at a temperature of 27°C, and then w...

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Abstract

The invention relates to a graphene oxide conductive glass and a preparation method thereof. The preparation method is as follows: loading graphene oxide on the surface of the glass, and using metal ions to connect two adjacent layers of graphene oxide to obtain a graphene oxide conductive glass. Ion is Mn 2+ The prepared graphene oxide conductive glass is mainly composed of glass, graphene oxide and metal ions. When the number of graphene layers increases from 10 to 15, the resistivity of graphene oxide conductive glass changes from ρ 1 down to ρ 2 , ρ 1 9~50Ω·mm, ρ 2 for ρ 1 0.7 to 1.0 times of that. The preparation process of the invention is simple, the production cost is low, and can be used in industrialized production; the prepared graphene oxide conductive glass has excellent conductivity.

Description

technical field [0001] The invention belongs to the technical field of conductive glass, and relates to a graphene oxide conductive glass and a preparation method thereof. Background technique [0002] At present, the conductive films of transparent conductive glass widely used in the industry mainly include indium tin oxide, zinc aluminum oxide and fluorine-doped tin oxide. Among them, the preparation of the indium tin oxide conductive film requires a large amount of expensive indium metal, which is a rare earth metal, and its material cost is relatively high, which greatly limits its application. The photoelectric properties of zinc aluminum oxide and fluorine-doped tin oxide films are similar to those of indium tin oxide films, but the preparation conditions of their conductive films are relatively harsh, usually by vacuum evaporation, magnetron sputtering, physical or chemical coating, etc. on the glass surface. The above-mentioned metal oxide conductive film can be mad...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C17/22G16C60/00
CPCC03C17/22G16C60/00C03C2217/70C03C2218/111C03C2218/32
Inventor 程娜赵健伟张柳悦庄再裕于晓辉
Owner JIAXING UNIV