Unlock instant, AI-driven research and patent intelligence for your innovation.

A method for preparing gold mine filling cementitious material by using cyanogen-containing gold tailings

A cementitious material, mine filling technology, applied in the fields of inorganic non-metallic materials, resource recycling and environmental protection, can solve the problems of difficult industrial application, high energy consumption, inability to dispose of, and achieve the effect of resource utilization

Active Publication Date: 2021-07-09
山东生态环境研究院有限公司
View PDF11 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the above two methods can achieve the purpose of reutilization and harmless disposal of cyanogen-containing gold tailings, CN 104046783A will cause harm to on-site workers and the surrounding environment in the process of recovering valuable metals, and there will be high energy consumption and high pollution; CN106238440B has the problem that the waste water produced after disposal is still hazardous waste and cannot be disposed of, and the efficiency of this method is very low at the same time
Furthermore, gold tailings, as hazardous waste, are subject to strict restrictions on transportation and use, making industrial application difficult

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] 1) Send the cyanide-containing gold tailings into a cement kiln at 1500-1600°C for high-temperature calcination for 30 minutes; Under the condition of producing water vapor at a high temperature), the following reactions exist to achieve the purpose of completely decomposing cyanide.

[0038] HCN+0.5O 2 →HCNO

[0039] HCN+H 2 O→HCOONH 4 →NH 3 +HCOOH

[0040] 2) The gold tailings calcined at high temperature are quenched in water (water temperature 20°C) for 5 minutes to stimulate the activity of gold tailings;

[0041] 3) Formula of gold mine filling cementitious material

[0042] In terms of weight ratio, 82.5% of gold tailings after the treatment in step 2), 7.5% of cement clinker, 0.15% of reinforcing agent, and the rest is water.

[0043] The composition and weight ratio of the strengthening agent are: 12% of silane coupling agent, 30% of diethanol monoisopropanolamine, 15% of alpha-alkenyl sulfonate sodium, and the rest is water.

[0044] After testing: the...

Embodiment 2

[0046] 1) Send the cyanide-containing gold tailings into a cement kiln at 1550-1650°C for high-temperature calcination for 28 minutes; Under the condition of producing water vapor at a high temperature), the following reactions exist to achieve the purpose of completely decomposing cyanide.

[0047] HCN+0.5O 2 →HCNO

[0048] HCN+H 2 O→HCOONH 4 →NH 3 +HCOOH

[0049] 2) The gold tailings calcined at high temperature are chilled in water (water temperature 20°C) for 5 minutes to stimulate the activity of the gold tailings;

[0050] 3) Recipe for filling cementitious material in gold mines

[0051] By weight, the gold tailings treated in step 2) are 82%, cement clinker is 8%, reinforcing agent is 0.15%, and the rest is water.

[0052] The components and weight ratio of the reinforcing agent are: 12% of silane coupling agent, 28% of diethanol monoisopropanolamine, 15% of sodium α-alkenyl sulfonate, and the rest are water.

[0053] Tested: The cyanide-containing gold tailings ...

Embodiment 3

[0055] 1) Send the cyanide-containing gold tailings into a cement kiln at 1450-1550℃ for 40 minutes of high temperature calcination; Under the condition that water vapor is generated at high temperature), the following reactions exist to achieve the purpose of completely decomposing cyanide.

[0056] HCN+0.5O 2 →HCNO

[0057] HCN+H 2 O→HCOONH 4 →NH 3 +HCOOH

[0058] 2) The gold tailings calcined at high temperature are chilled in water (water temperature 20°C) for 5 minutes to stimulate the activity of the gold tailings;

[0059] 3) Recipe for filling cementitious material in gold mines

[0060] By weight, the gold tailings treated in step 2) are 83%, cement clinker 7%, reinforcing agent is 0.15%, and the rest is water.

[0061] The components and weight ratio of the reinforcing agent are: 13% of silane coupling agent, 35% of diethanol monoisopropanolamine, 12% of sodium α-alkenyl sulfonate, and the rest are water.

[0062] Tested: The cyanide-containing gold tailings ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
compressive strengthaaaaaaaaaa
flexural strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses a method for preparing gold mine filling cementitious material by utilizing cyanide-containing gold tailings. The invention utilizes a high-temperature calcination method to harmlessly dispose of cyanide-containing gold tailings, and then conducts water quenching to activate the activity, and becomes an important raw material for preparing gold mine filling cementitious materials, and then prepares gold mines with cement clinker and a reinforcing agent Fill with gelling material. The invention not only solves the problem of harmless disposal of cyanide-containing gold tailings, but also realizes the resourceful utilization of a large amount of decyanation gold tailings.

Description

technical field [0001] The invention relates to a method for preparing gold mine filling cementitious material by utilizing cyanide-containing gold tailings, and belongs to the field of inorganic non-metallic materials and the fields of resource recycling and environmental protection. Background technique [0002] Cyanide-containing gold tailings are the product of gold extraction from gold ore by cyanide gold extraction method. Because it contains highly toxic cyanide, it has been included in the "National Hazardous Waste List" and belongs to HW33 category. At present, the disposal of cyanide-containing gold tailings adopts the safe landfill method, but long-term storage not only easily causes secondary pollution, but also causes serious waste of resources. [0003] At present, research on gold tailings mainly focuses on the recovery and harmless disposal of valuable metals in gold tailings. Chinese patent document CN 104046783A discloses a method for recovering gold, silv...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/00
CPCC04B28/00C04B2111/00724C04B2201/50C04B18/144C04B24/42C04B24/122C04B24/16
Inventor 于吉涛岳光亮李开彬程伟
Owner 山东生态环境研究院有限公司