Curing agents for two-component adhesives, two-component adhesives, laminated films, and packages
An adhesive, two-component technology, applied in the direction of adhesives, chemical instruments and methods, polyurea/polyurethane adhesives, etc., can solve the problems of high viscosity, short pot life, and long pot life of non-target substances Solve problems such as two-component adhesives, achieve excellent adhesion, excellent operability, and excellent long-term storage effects
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[0141] Next, the present invention will be specifically described by way of examples and comparative examples. Unless otherwise specified in the example, "minute" and "%" are mass standards.
Synthetic example 1
[0142] Synthesis Example 1 [Synthesis of Polyol Component A1]
[0143] 560 parts by mass of diethylene glycol was added to a reaction container, and it heated to 80 degreeC, stirring under nitrogen flow. Furthermore, 600 parts by mass of adipic acid was added to the reaction container while stirring, and it heated at 150 degreeC - 240 degreeC, and performed esterification reaction. When the acid value reaches below 5mgKOH / g, the reaction vessel is slowly decompressed, and the reaction is carried out at 200-240°C for 1 hour under 1mmHg to obtain a polyester having hydroxyl groups at both ends with an acid value of 0.8mgKOH / g and a molecular weight of about 840. Polyol resin (hereinafter, this is simply referred to as "polyol component A1").
Synthetic example 2
[0144] Synthesis Example 2 [Synthesis of Polyol Component A2]
[0145] 690 parts by mass of diethylene glycol and 8 parts by mass of trimethylolpropane were added to a reaction container, and heated to 80°C while stirring under a nitrogen stream to dissolve. Furthermore, 810 parts by mass of adipic acid was added to the reaction container, stirring, and it heated at 150 degreeC - 240 degreeC, and performed esterification reaction. When the acid value reaches below 5mgKOH / g, the reaction vessel is slowly decompressed, and the reaction is carried out at 200-220°C for 1 hour under 1mmHg to obtain a polyester having hydroxyl groups at both ends with an acid value of 0.8mgKOH / g and a molecular weight of about 1270. Polyol resin (hereinafter, this is simply referred to as "polyol component A2").
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