A kind of preparation method of antibacterial nanoporous material
A nanoporous and porous titanium technology, which is applied in the fields of botanical equipment and methods, metal material coating process, chemicals for biological control, etc. It is suitable for large-scale industrial production, with low production cost and enhanced antibacterial effect.
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Embodiment 1
[0019] This embodiment includes the following steps:
[0020] Step 1. The porous titanium plate prepared by titanium powder is used as the cathode, the graphite is used as the anode, and the copper sulfate solution with a mass concentration of 25% is used as the electrolyte, and electrodeposition is carried out to make the Cu in the electrolyte 2+ Deposited on the surface of the porous titanium plate;
[0021] Step 2, depositing Cu on the surface in step 1 2+ The porous titanium plate is put into an argon furnace for heat treatment; the temperature of the heat treatment is 600°C, and the holding time is 2h;
[0022] Step 3, depositing Cu on the heat-treated surface in step 2 2+ The porous titanium plate is placed in a nitric acid solution with a mass concentration of 45%, and is subjected to acid leaching treatment at a temperature of 70° C. to obtain a nanoporous material; the nanoporous material is composed of a porous titanium matrix and acicular nanoporous titanium oxide...
Embodiment 2
[0025] This embodiment includes the following steps:
[0026] Step 1. The porous titanium alloy plate prepared by titanium alloy fiber is used as the cathode, the platinum sheet is used as the anode, and the copper sulfate solution with a mass concentration of 25% is used as the electrolyte for electrodeposition to make the Cu in the electrolyte 2+ Deposited on the surface of the porous titanium plate;
[0027] Step 2, depositing Cu on the surface in step 1 2+ The porous titanium alloy plate is put into an argon furnace for heat treatment; the temperature of the heat treatment is 600°C, and the holding time is 2h;
[0028] Step 3, depositing Cu on the heat-treated surface in step 2 2+ The porous titanium alloy plate is placed in a nitric acid solution with a mass concentration of 45%, and is subjected to acid leaching treatment at a temperature of 70° C. to obtain a nanoporous material; the nanoporous material is composed of a porous titanium alloy matrix and acicular nanopo...
Embodiment 3
[0031] This embodiment includes the following steps:
[0032] Step 1. The porous titanium alloy plate prepared by titanium alloy powder is used as the cathode, the graphite is used as the anode, and the copper sulfate solution with a mass concentration of 20% is used as the electrolyte to conduct electrodeposition to make the Cu in the electrolyte 2+ Deposited on the surface of the porous titanium plate;
[0033] Step 2, depositing Cu on the surface in step 1 2+ The porous titanium plate is put into an argon furnace for heat treatment; the temperature of the heat treatment is 500°C, and the holding time is 2h;
[0034] Step 3, depositing Cu on the heat-treated surface in step 2 2+ The porous titanium plate is placed in a nitric acid solution with a mass concentration of 40%, and is subjected to acid leaching treatment at a temperature of 60° C. to obtain a nanoporous material; the nanoporous material is composed of a porous titanium alloy matrix and acicular nanoporous titan...
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