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A kind of phosphate binder modified by sorbitol, its preparation method and use method

A technology of sorbitol and phosphate, applied in the field of casting, can solve the problems of low tensile strength, poor storage stability, and insignificant improvement of sand sample strength, and achieve fast hardening and demoulding, low cost, and stable storage The effect of green protection and pollution-free

Active Publication Date: 2021-04-16
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Phosphate binder, as a green and environmentally friendly casting inorganic binder, has the characteristics of good collapsibility, colorless and odorless, but compared with traditional organic resin binders, it has lower tensile strength and stable storage Sexual difference and other characteristics
According to the related characteristics of phosphate binder, modifying it, such as the addition of some simple acid modifiers, can improve the performance of phosphate binder to a certain extent, but the improvement of sand sample strength not obvious

Method used

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  • A kind of phosphate binder modified by sorbitol, its preparation method and use method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Add 10g of sorbitol-modified phosphate binder (code A) Proportioning: 85% industrial phosphoric acid 338g, 320 mesh aluminum hydroxide powder 77.5g, boric acid 12g, silicic acid 2g, light magnesium oxide 8g, light Zinc oxide 6g, copper oxide 0.25g, nanometer yttrium oxide 0.25g, sorbitol 10g, purified water 200g;

[0053] Preparation:

[0054] 1) Add phosphoric acid into the reaction kettle, turn on the stirrer and heater, and slowly heat to 180-200°C;

[0055] 2) Add a small amount of aluminum hydroxide powder to the reaction kettle several times, and continue to stir and react until the solution in the reaction kettle is transparent;

[0056] 3) Add 50g of pure water, heat and stir until the solution temperature returns to the temperature before adding water;

[0057] 4) Add boric acid and silicic acid powder in turn, continue heating and stirring until the solution is transparent;

[0058] 5) Add 50g of pure water, heat and stir until the solution temperature return...

Embodiment 2

[0069] Add 20g of sorbitol-modified phosphate binder (code B) proportioning: 85% industrial phosphoric acid 338g, 320 mesh aluminum hydroxide powder 77.5g, boric acid 12g, silicic acid 2g, light magnesium oxide 8g, light Zinc oxide 6g, copper oxide 0.25g, nanometer yttrium oxide 0.25g, sorbitol 20g, purified water 200g;

[0070] Preparation:

[0071] 1) Add phosphoric acid into the reaction kettle, turn on the stirrer and heater, and slowly heat to 180-200°C;

[0072] 2) Add a small amount of aluminum hydroxide powder to the reaction kettle several times, and continue to stir and react until the solution in the reaction kettle is transparent;

[0073] 3) Add 50g of pure water, heat and stir until the solution temperature returns to the temperature before adding water;

[0074] 4) Add boric acid and silicic acid powder in turn, continue heating and stirring until the solution is transparent;

[0075] 5) Add 50g of pure water, heat and stir until the solution temperature retu...

Embodiment 3

[0086] Add 30g of sorbitol-modified phosphate binder (code name C) proportioning: 85% industrial phosphoric acid 338g, 320 mesh aluminum hydroxide powder 77.5g, boric acid 12g, silicic acid 2g, light magnesium oxide 8g, light Zinc oxide 6g, copper oxide 0.25g, nanometer yttrium oxide 0.25g, sorbitol 30g, purified water 200g;

[0087] Preparation:

[0088] 1) Add phosphoric acid into the reaction kettle, turn on the stirrer and heater, and slowly heat to 180-200°C;

[0089] 2) Add a small amount of aluminum hydroxide powder to the reaction kettle several times, and continue to stir and react until the solution in the reaction kettle is transparent;

[0090] 3) Add 50g of pure water, heat and stir until the solution temperature returns to the temperature before adding water;

[0091] 4) Add boric acid and silicic acid powder in turn, continue heating and stirring until the solution is transparent;

[0092] 5) Add 50g of pure water, heat and stir until the solution temperature...

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Abstract

The invention belongs to the field of foundry industry, and specifically relates to a sorbitol-modified phosphate binder, a preparation method and a use method thereof. The sorbitol-modified phosphate binder comprises: phosphoric acid, Aluminum hydroxide, boric acid, silicic acid, magnesium oxide, zinc oxide, copper oxide, nano-yttrium oxide, sorbitol, purified water. Compared with the traditional phosphate binder, the sorbitol-modified phosphate binder of the present invention has the advantages of higher bonding strength and better storage stability; For the strength of the sand sample, the sand sample can still maintain high strength under the addition of 2.5% phosphate binder.

Description

technical field [0001] The invention belongs to the field of foundry industry, and in particular relates to a sorbitol-modified phosphate binder, a preparation method and a use method thereof. Background technique [0002] Phosphate binder, as a green and environmentally friendly casting inorganic binder, has the characteristics of good collapsibility, colorless and odorless, but compared with traditional organic resin binders, it has lower tensile strength and stable storage characteristics such as poor sex. According to the related characteristics of phosphate binder, modifying it, such as the addition of some simple acid modifiers, can improve the performance of phosphate binder to a certain extent, but the improvement of sand sample strength Not obvious. In order to reduce the difference in strength with traditional organic resin binders, more phosphate binders need to be added. How to modify the phosphate binder, improve its strength to reduce the amount of phosphate...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22C1/18
CPCB22C1/185
Inventor 夏露高瑞张友寿任彦臻
Owner HUBEI UNIV OF TECH