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Process method for preparing thickening agent by using ethoxylated bisphenol A diacrylate wastewater

A technology of ethoxylated bisphenols and diacrylates, which is applied in the field of chemical waste liquid treatment, can solve problems such as technical problems that cannot be effectively overcome, high water inlet conditions, high treatment costs, etc., and achieve reliable performance and preparation Simple method and easy-to-operate effect

Active Publication Date: 2020-01-24
DUPLUS CHEM OF ZHANGJIAGANG CITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The treatment methods commonly used at home and abroad all adopt the incineration method. Since the waste water cannot be directly burned, heavy oil needs to be added to support the combustion, and the treatment cost per ton is high. If the treatment is not timely, the waste liquid will automatically explode and generate a large amount of solid waste. It will release dioxins into the atmosphere and cause secondary pollution; although the catalytic oxidation method can effectively decompose pollutants, the key lies in the catalyst, which has strong specificity and has high restrictions on water inflow conditions. Only a few acrylic acid manufacturers adopt this method. In addition, the catalytic wet oxidation method requires high temperature and high pressure conditions to treat wastewater, and there are also potential safety hazards.
However, its anaerobic method, aerobic method, ion exchange fiber method, etc. are still in the theoretical research stage, and there are still many technical problems that have not been effectively overcome and cannot be promoted.

Method used

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  • Process method for preparing thickening agent by using ethoxylated bisphenol A diacrylate wastewater
  • Process method for preparing thickening agent by using ethoxylated bisphenol A diacrylate wastewater
  • Process method for preparing thickening agent by using ethoxylated bisphenol A diacrylate wastewater

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Embodiment Construction

[0024] Below in conjunction with specific embodiment, content of the present invention is described in further detail:

[0025] An embodiment of the present invention provides a process for preparing a thickener using ethoxylated bisphenol A diacrylate wastewater, comprising the following steps:

[0026] Sending waste water containing acrylic acid into the reactor and adding styrene, diallyl terephthalate and acrylamide to obtain a mixed solution for free radical copolymerization;

[0027] replacing the gas phase part inside the reactor with nitrogen, and heating the mixed solution to 75°C-85°C;

[0028] Add sodium persulfate aqueous solution to the reactor regularly, and control the mixed solution to maintain at 75°C-85°C;

[0029] After the free radical copolymerization of the mixed liquid is completed, the mixed liquid is cooled and an aqueous sodium hydroxide solution and water are added to adjust the pH value and concentration of the reaction liquid to obtain a thickener...

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Abstract

The invention discloses a process method for preparing a thickening agent by using ethoxylated bisphenol A diacrylate wastewater. Wastewater of ethoxylated bisphenol A diacrylate synthesis is used asa raw material, and free radical polymerization is carried out on a mixed solution of the wastewater, styrene, terephthalic acid diallyl ester and acrylamide to prepare a thickening agent. The processflow is complete, the preparation method is simple, the raw material is cheap, operation is easy, deep resource utilization and near-zero emission of wastewater are realized, and new industrial output is created. In addition, compared with an existing thickening agent on the market, the prepared thickening agent prepared by the process method has reliable performance, and even partial parametersare slightly better than parameters of similar products, so that the thickening agent extracted from the wastewater has good market competitiveness.

Description

technical field [0001] The invention relates to the field of chemical waste liquid treatment, in particular to a process for preparing a thickener by using ethoxylated bisphenol A diacrylate wastewater. Background technique [0002] In the printing process, the high shear force will reduce the consistency of the color paste, and it is necessary to use a thickener to increase the viscosity of the system, so that the system has good rheological properties, so that the dye and the fiber can be better combined. The properties of the thickener determine the properties of the printing paste, and directly affect the color brilliance, pattern clarity, hand feel and other properties of the printed product. Therefore, when printing, it is very important to select a stable, safe, applicable and cost-effective thickener. [0003] In the process of preparing ethoxylated bisphenol A diacrylate by using raw materials such as acrylic acid and ethoxylated bisphenol A, waste liquid containin...

Claims

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Application Information

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IPC IPC(8): C08F220/06C08F212/08C08F220/56C08F220/40C08F222/20D06P1/52
CPCC08F220/06D06P1/5257
Inventor 陈金辉方玉琦杨晓凤钱莉陈秋坤刘长海吴玉春
Owner DUPLUS CHEM OF ZHANGJIAGANG CITY
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