Electroconductive polymer active medical catheter and preparation method thereof
A conductive polymer and polymer technology, applied in the direction of catheters, etc., can solve the problems of hysteresis and time delay, complex structure, large size, etc., and achieve the effects of low cost, broad application prospects, and simple preparation methods
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[0018] As an aspect of the technical solution of the present invention, it relates to a method for preparing a conductive polymer active medical catheter, including:
[0019] making a conductive polymer / carbon nanotube composite electrode film from the mixed dispersion liquid comprising conductive polymer, carbon nanotube, first ionic liquid and water;
[0020] making a hollow cylinder with a polymer carrying an ionic liquid, and thermally swelling the hollow cylinder to absorb a second ionic liquid to obtain a hollow cylinder electrolyte layer;
[0021] The obtained hollow columnar electrolyte layer is placed between at least two conductive polymer / carbon nanotube composite electrode films to form a sandwich structure, and then the sandwich structure is hot-pressed to form a conductive polymer active medical catheter.
[0022] see figure 1 , in a more typical embodiment of the present invention, the preparation method may include the following steps:
[0023] Adding carbon ...
Embodiment 1
[0047]Configure the conductive polymer / carbon nanotube mixed dispersion, wherein the conductive polymer consumption is 55wt%, the carboxylated carbon nanotube consumption is 15wt%, and the 1-ethyl-3-methylimidazolium tetrafluoroborate consumption is 30wt%. . The above mixed dispersion liquid was casted on a polytetrafluoroethylene substrate, and dried on a heating platform at 40° C. to obtain a conductive polymer / carbon nanotube composite electrode film.
[0048] Poly(vinylidene fluoride-co-hexafluoropropylene) is dissolved in N,N-dimethylformamide to obtain a polymer solution with a concentration of 10 wt%, and the above solution is injected into a grooved polytetrafluoroethylene mould, using The method of phase inversion obtains hollow poly(vinylidene fluoride-co-hexafluoropropylene) square column, and then the hollow poly(vinylidene fluoride-co-hexafluoropropylene) square column is thermally swelled at 50 ° C to absorb 1-ethyl- 3-Methylimidazolium tetrafluoroborate, obtain...
Embodiment 2
[0052] Configure the conductive polymer / carbon nanotube mixed dispersion, wherein the conductive polymer consumption is 70wt%, the carboxylated carbon nanotube consumption is 10wt%, and the 1-ethyl-3-methylimidazolium tetrafluoroborate consumption is 20wt%. . The above mixed dispersion liquid was casted on a polytetrafluoroethylene substrate, and dried on a heating platform at 40° C. to obtain a conductive polymer / carbon nanotube composite electrode film.
[0053] Poly(vinylidene fluoride-co-hexafluoropropylene) was dissolved in N,N-dimethylformamide to obtain a polymer solution with a concentration of 15 wt%, and the above solution was injected into a grooved polytetrafluoroethylene mould, and utilized The method of phase inversion obtains hollow poly(vinylidene fluoride-co-hexafluoropropylene) square column, and then the hollow poly(vinylidene fluoride-co-hexafluoropropylene) square column is thermally swelled at 50 ° C to absorb 1-ethyl- 3-methylimidazolium tetrafluorobora...
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