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Corrosion inhibitor for reinforced concrete and preparation method thereof

A technology of reinforced concrete and rust inhibitor, which is applied in the field of building materials, can solve problems such as improving concrete and aggravating corrosion, and achieves the effects of low equipment dependence, inhibition of steel corrosion, and good adaptability

Inactive Publication Date: 2020-03-27
庄明磊
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The concrete reinforcement rust inhibitor of the present invention has no negative influence on concrete properties, and has high-efficiency reinforcement corrosion resistance, and can be widely used in newly mixed reinforced concrete structures such as harbor projects, coastal buildings, and civil buildings. The combined use of these materials has excellent anti-corrosion properties, but it has not been considered to improve other properties of concrete, such as compactness, impermeability, etc., from the concrete anti-corrosion agent itself.
If the concrete mix design is unreasonable, it may aggravate the occurrence of corrosion

Method used

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  • Corrosion inhibitor for reinforced concrete and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A rust inhibitor for reinforced concrete, consisting of the following components by weight: 10 parts of surface modified Mo-Zn-Dy-O-B, (1R,2R,3S,4R,6S)-4,6-diamino- 2,3-dihydroxycyclohexyl 6-amino-6-deoxy-alpha-D-glucopyranoside 10 parts, epoxy glycoside modified {(2S)-2-{bis[3,5-bis(tri Fluoromethyl)phenyl]hydroxymethyl}-1-pyrrolidinyl[4-(1-pyrrolidinyl)-3-pyridyl]methanone 15 parts, water 60 parts, alkylbenzenesulfonate primer Air agent 0.01 part.

[0031]The epoxy glycoside modified {(2S)-2-{bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}-1-pyrrolidinyl[4-(1-pyrrolidine base)-3-pyridyl]methanone preparation method, comprising the steps of: {(2S)-2-{bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}-1- Add 17g of pyrrolidinyl[4-(1-pyrrolidinyl)-3-pyridyl]methanone, 10g of 3,4-epoxybutyl-beta-cellobioside, and 3g of sodium carbonate into 100g of dimethyl sulfoxide , stirred and reacted at 90°C for 4 hours, then filtered to remove insoluble salts, and then rotary ev...

Embodiment 2

[0037] A rust inhibitor for reinforced concrete, consisting of the following components by weight: 11 parts of surface modified Mo-Zn-Dy-O-B, (1R,2R,3S,4R,6S)-4,6-diamino- 2,3-dihydroxycyclohexyl 6-amino-6-deoxy-alpha-D-glucopyranoside 11 parts, epoxy glycoside modified {(2S)-2-{bis[3,5-bis(tri Fluoromethyl)phenyl]hydroxymethyl}-1-pyrrolidinyl[4-(1-pyrrolidinyl)-3-pyridyl]methanone 16 parts, water 63 parts, ferric saponin air-entraining agent 0.02 share.

[0038] The epoxy glycoside modified {(2S)-2-{bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}-1-pyrrolidinyl[4-(1-pyrrolidine base)-3-pyridyl]methanone preparation method, comprising the steps of: {(2S)-2-{bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}-1- Pyrrolidinyl[4-(1-pyrrolidinyl)-3-pyridyl]methanone 17g, 3,4-epoxybutyl-beta-cellobioside 10g, potassium carbonate 3.5g were added to N,N-di In 110 g of methylformamide, the reaction was stirred at 93° C. for 4.5 hours, then the insoluble salt was removed by filtrati...

Embodiment 3

[0044] A rust inhibitor for reinforced concrete, consisting of the following components by weight: 13 parts of surface modified Mo-Zn-Dy-O-B, (1R,2R,3S,4R,6S)-4,6-diamino- 2,3-dihydroxycyclohexyl 6-amino-6-deoxy-alpha-D-glucopyranoside 13 parts, epoxy glycoside modified {(2S)-2-{bis[3,5-bis(tri Fluoromethyl)phenyl]hydroxymethyl}-1-pyrrolidinyl[4-(1-pyrrolidinyl)-3-pyridyl]methanone 18 parts, water 65 parts, alkylbenzenesulfonate primer Air agent 0.03 parts.

[0045] The epoxy glycoside modified {(2S)-2-{bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}-1-pyrrolidinyl[4-(1-pyrrolidine base)-3-pyridyl]methanone preparation method, comprising the steps of: {(2S)-2-{bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}-1- Pyrrolidinyl[4-(1-pyrrolidinyl)-3-pyridyl]methanone 17g, 3,4-epoxybutyl-beta-cellobioside 10g, sodium hydroxide 4g were added to N-methylpyrrolidone 130g, stirred and reacted at 95°C for 5 hours, then filtered to remove insoluble salts, and then rotary evaporated ...

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Abstract

The invention discloses a corrosion inhibitor for reinforced concrete. The corrosion inhibitor for reinforced concrete is prepared from the following components in parts by weight: 10-15 parts of surface modified Mo-Zn-Dy-O-B, 10-15 parts of (1R, 2R, 3S, 4R, 6S)-4, 5-diamino-2, 3- dihydroxy cyclohexyl-6-amino-6-deoxy-alpha-D-glucopyranoside, 15 to 20 parts of epoxy glycoside modified {(2S)-2-{bis[3, 5-bis (trifluoromethyl) phenyl] hydroxymethyl}-1-pyrrolidinyl [4-(1-pyrrolidinyl)-3-pyridyl] ketone, 60 to 70 parts of water and 0.01 to 0.05 part of an air entraining agent. The invention also discloses a preparation method of the corrosion inhibitor for reinforced concrete. The corrosion inhibitor for reinforced concrete has the advantages of being low in preparation cost, environmentally friendly, remarkable in corrosion inhibition effect, low in dosage, good in adaptability to cement, capable of properly improving the performance of concrete and the like.

Description

technical field [0001] The invention relates to the technical field of building materials, in particular to a rust inhibitor for reinforced concrete and a preparation method thereof. Background technique [0002] In recent years, with the expansion of the scale of national large-scale engineering construction and the deterioration of natural conditions, the corrosion of steel bars in concrete has become increasingly apparent, which has brought serious harm to the normal use of concrete structures and brought serious harm to the national economy or the safety of people's lives and properties. The immeasurable loss has become a worldwide concern of the concrete industry and even the entire engineering field. Preventing and controlling the corrosion of steel bars is the guarantee to ensure the safety of concrete structures and the key to improving the quality of projects. [0003] There are many technical measures to prevent the corrosion of steel bars. On the basis of improvi...

Claims

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Application Information

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IPC IPC(8): C04B24/20C04B103/61
CPCC04B40/0039C04B2103/0004C04B2103/0017C04B2103/0025C04B2103/61C04B22/0013C04B24/121C04B24/128C04B24/20
Inventor 庄明磊
Owner 庄明磊
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