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Lithium ion battery electrolyte considering high and low temperature performances and battery

A lithium-ion battery and electrolyte technology, applied in the field of lithium-ion batteries, can solve problems such as inability to take into account high and low temperature performance, and achieve the effects of inhibiting continuous reduction and decomposition, avoiding erosion, and reducing consumption

Active Publication Date: 2020-03-27
GUANGZHOU TINCI MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of this, it is necessary to provide a lithium-ion battery electrolyte additive that takes into account high-temperature cycle performance, high-temperature storage performance, low-temperature cycle performance, and low-temperature storage performance, so as to improve the electrochemical performance of lithium-ion batteries under high-temperature and low-temperature conditions. There is a problem that lithium-ion batteries cannot take into account high and low temperature performance in the technology, so as to expand the application range of lithium-ion batteries

Method used

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  • Lithium ion battery electrolyte considering high and low temperature performances and battery
  • Lithium ion battery electrolyte considering high and low temperature performances and battery
  • Lithium ion battery electrolyte considering high and low temperature performances and battery

Examples

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Embodiment 1

[0029] A lithium-ion battery electrolyte that takes into account both high and low temperature performance, the electrolyte is composed of an organic solvent, a lithium salt and an additive, and the organic solvent is composed of ethylene carbonate (EC) and dicarbonate with a mass ratio of 1:1:1 Methyl ester (EMC) and diethyl carbonate (DEC) form, and described organic solvent weight is 87.5g; Described lithium salt is lithium hexafluorophosphate, and the weight of described lithium hexafluorophosphate is 12.5g; Described additive is chemical formula: The bis-pentafluorophenylphosphino compound A1, said A1 is 0.3% of the total weight of the electrolyte.

[0030] Application: The electrolyte is used to prepare lithium-ion batteries, as follows:

[0031] A lithium ion battery with both high and low temperature performance is composed of a positive electrode, a negative electrode, a separator arranged between the positive and negative electrodes, and the above lithium ion batter...

Embodiment 2

[0033] A lithium-ion battery electrolyte and battery with both high and low temperature performance, wherein the additive has the chemical formula: Bis-pentafluorophenylphosphino-based compound A1, said A1 is 0.5% of the total weight of the electrolyte, and the others are the same as in Example 1.

Embodiment 3

[0035] A lithium-ion battery electrolyte and battery with both high and low temperature performance, wherein the additive has the chemical formula: Bis-pentafluorophenylphosphino-based compound A1, said A1 is 1% of the total weight of the electrolyte, and the others are the same as in Example 1.

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PUM

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Abstract

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a lithium ion battery electrolyte considering high and low temperature performances and a battery. Byadding the bis-pentafluorophenylphosphino compound into the electrolyte, a reduction reaction is performed on a negative electrode material prior to a solvent to form an SEI film with excellent performance, so that the co-intercalation of solvent molecules is prevented, the interface stability of the negative electrode is improved, and the low-temperature performance of a lithium ion battery is improved; and by complexing with HF in the electrolyte at a high temperature, the corrosion of HF in the electrolyte to a positive electrode material under the high-temperature and high-pressure conditions is avoided, and the high-temperature performance of the lithium ion battery is improved.

Description

technical field [0001] The invention belongs to the technical field of lithium-ion batteries, and in particular relates to a lithium-ion battery electrolyte and a battery with both high and low temperature performance. Background technique [0002] Lithium-ion batteries have been widely used in the fields of consumer electronics, electric vehicles and energy storage due to their high energy density, long cycle life, high operating voltage, low self-discharge effect, and no memory effect, and have achieved great commercial success. Especially in the field of electric vehicles, with the popularization of new energy vehicles in the fields of family vehicles, official vehicles, buses, taxis, and logistics vehicles, the proportion of annual sales of new energy vehicles will continue to increase significantly. [0003] With the development of lithium-ion batteries in the field of power battery applications, people have higher and higher requirements for lithium-ion batteries, requ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0567H01M10/0525
CPCH01M10/0567H01M10/0525H01M2300/0025Y02E60/10
Inventor 孙艳光刘蕊周邵云赵经纬
Owner GUANGZHOU TINCI MATERIALS TECH
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