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A lithium-ion battery electrolyte and battery with both high and low temperature performance

A lithium-ion battery and electrolyte technology, applied in the field of lithium-ion batteries, can solve the problem of inability to take into account high and low temperature performance, and achieve the effects of inhibiting continuous reduction and decomposition, reducing consumption, and avoiding structural degradation.

Active Publication Date: 2022-05-27
GUANGZHOU TINCI MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of this, it is necessary to provide a lithium-ion battery electrolyte additive that takes into account high-temperature cycle performance, high-temperature storage performance, low-temperature cycle performance, and low-temperature storage performance, so as to improve the electrochemical performance of lithium-ion batteries under high-temperature and low-temperature conditions. There is a problem that lithium-ion batteries cannot take into account high and low temperature performance in the technology, so as to expand the application range of lithium-ion batteries

Method used

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  • A lithium-ion battery electrolyte and battery with both high and low temperature performance
  • A lithium-ion battery electrolyte and battery with both high and low temperature performance
  • A lithium-ion battery electrolyte and battery with both high and low temperature performance

Examples

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Embodiment 1

[0029] A lithium-ion battery electrolyte that takes into account high and low temperature performance, the electrolyte is composed of an organic solvent, a lithium salt and an additive, and the organic solvent is composed of ethylene carbonate (EC), dicarbonate and ethylene carbonate in a mass ratio of 1:1:1. Methyl ester (EMC) and diethyl carbonate (DEC) are composed, the weight of the organic solvent is 87.5g; the lithium salt is lithium hexafluorophosphate, and the weight of the lithium hexafluorophosphate is 12.5g; the chemical formula of the additive is The bis-pentafluorophenylphosphino-based compound A1, the A1 is 0.3% of the total weight of the electrolyte.

[0030] Application: Lithium-ion batteries are prepared with this electrolyte, as follows:

[0031] A lithium ion battery that takes into account high and low temperature performance is composed of a positive electrode, a negative electrode, a separator arranged between the positive electrode and the negative elec...

Embodiment 2

[0033] A lithium ion battery electrolyte and battery with both high and low temperature performance, wherein the additive is the chemical formula of The bis-pentafluorophenylphosphino-based compound A1, the A1 is 0.5% of the total weight of the electrolyte, and the others are the same as in Example 1.

Embodiment 3

[0035] A lithium ion battery electrolyte and battery with both high and low temperature performance, wherein the additive is the chemical formula of The bis-pentafluorophenylphosphino-based compound A1, the A1 is 1% of the total weight of the electrolyte, and the others are the same as in Example 1.

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Abstract

The invention belongs to the technical field of lithium-ion batteries, and in particular relates to a lithium-ion battery electrolyte and a battery with both high and low temperature performance. By adding bis-pentafluorophenylphosphino-based compounds in the electrolyte, the reduction reaction occurs on the negative electrode material in preference to the solvent to form an SEI film with excellent performance, prevent the co-intercalation of solvent molecules, improve the interface stability of the negative electrode, and improve lithium Low-temperature performance of ion batteries; complexation with HF in the electrolyte at high temperatures, avoiding the erosion of positive electrode materials by HF in the electrolyte under high temperature and high pressure conditions, and improving the high-temperature performance of lithium-ion batteries.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a lithium ion battery electrolyte and a battery with both high and low temperature performance. Background technique [0002] Lithium-ion batteries are widely used in consumer electronics, electric vehicles and energy storage due to their high energy density, long cycle life, high operating voltage, low self-discharge effect, and no memory effect, and have achieved great commercial success. Especially in the field of electric vehicles, with the widespread popularity of new energy vehicles in the fields of family vehicles, official vehicles, buses, taxis, and logistics vehicles, the proportion of annual sales of new energy vehicles will continue to increase significantly. [0003] With the development of lithium-ion batteries in the field of power battery applications, people have higher and higher requirements for lithium-ion batteries, requiring both hi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/0567H01M10/0525
CPCH01M10/0567H01M10/0525H01M2300/0025Y02E60/10
Inventor 孙艳光刘蕊周邵云赵经纬
Owner GUANGZHOU TINCI MATERIALS TECH
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