The present invention relates to the technical field of
sodium ion batteries, and in particular to a
sodium ion battery
composite electrolyte and a
sodium ion battery. The
composite electrolyte comprises
electrolyte A and
electrolyte B, wherein
electrolyte A comprises
sodium salt,
ether solvent and ester
solvent, and electrolyte B comprises
sodium salt and ester
solvent, wherein electrolyte A accounts for 70-95% of the total
mass of the
composite electrolyte, and electrolyte B accounts for 5-30% of the total
mass of the composite electrolyte.
Ether solvents are conducive to realizing the
wetting effect of the composite electrolyte on the
sodium ion battery, and the products completely decomposed in the first charge are used as part of the SEI film on the surface of the negative
electrode, thereby improving the first effect of the negative
electrode, and at the same time improving the battery cycle performance and the
oxidation resistance of the electrolyte, reducing the cycle gas production, and further improving the
oxidation resistance of the composite electrolyte and the working performance of the
sodium ion battery. Ester solvents can provide
high voltage stability, fully activate the
sodium ion battery, and synergize with
ether solvents to enhance the various working performances of the sodium ion battery.