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A kind of high-strength, high-toughness, oxidation-resistant iron-nickel-based superalloy and preparation method thereof

A nickel-based superalloy, high-strength and high-toughness technology, applied in the field of high-strength, high-toughness and anti-oxidation iron-nickel-based superalloy and its preparation, can solve the problem of limited increase in material cost, and achieve improved resistance to steam oxidation and flue gas corrosion , Improve the effect of durable performance, excellent structural stability and steam oxidation resistance

Active Publication Date: 2021-03-30
HUANENG POWER INT INC +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The new iron-nickel-based superalloy has a higher temperature bearing capacity than austenitic heat-resistant steel, and has good high-temperature performance, and the material cost is limited compared with high-grade austenitic heat-resistant steel (such as HR3C). The overall cost performance is high, and it is expected Applied to the key high-temperature components of 650°C ultra-supercritical units, but there is no mature iron-nickel-based superalloy system in the existing technology that can meet the requirements of 650°C units

Method used

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  • A kind of high-strength, high-toughness, oxidation-resistant iron-nickel-based superalloy and preparation method thereof
  • A kind of high-strength, high-toughness, oxidation-resistant iron-nickel-based superalloy and preparation method thereof
  • A kind of high-strength, high-toughness, oxidation-resistant iron-nickel-based superalloy and preparation method thereof

Examples

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Effect test

Embodiment 1

[0028] 1. Alloy composition

[0029] Table 1 provided the chemical composition of Example 1 of the present invention. Test alloy 1# is the iron-nickel base superalloy of embodiment 1 of the present invention, in order to compare with the highest austenitic heat-resistant steel Sanicro25 alloy (Sweden Sandvik company development) with the present temperature bearing capacity, also listed Sanicro25 in the table ingredients.

[0030] Table 1 Chemical composition (% by weight, balance being Ni) of embodiment 1 of the present invention and comparative example (Sanicro25)

[0031]

[0032]

[0033] 2. Alloy melting and thermal deformation

[0034] By weight percentage, Fe 35-45%, Cr 15-21%, Mo 0.5-1.4%, W 0.1-0.8%, Ti 1.8-2.5%, Al 0.8-2.5%, Mn≤1.0%, Nb≤0.1%, Co≤2%, Si≤0.05%, C0.03-0.10%, B0.001-0.005%, P≤0.01%, the balance is Ni, the weight percentage of Cr+Ni is more than 50%, the weight percentage of W+Mo It is 0.6-1.5%, added to the vacuum induction furnace for melting,...

Embodiment 2-9

[0055] The chemical compositions of the alloys described in Examples 2-9 of the present invention are shown in Table 5.

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Abstract

The invention discloses a high-strength, high-toughness anti-oxidation iron-nickel-based superalloy and a preparation method thereof, wherein the composition of the iron-nickel-based superalloy includes, by weight percentage, Fe 35-45%, Cr 15-21%, Mo 0.5‑1.4%, W 0.1‑0.8%, Ti 1.8‑2.5%, Al 0.8‑2.5%, Mn≤1.0%, Nb≤0.1%, Co≤2%, Si≤0.05%, C 0.03‑0.10%, B 0.001‑0.005%, P≤0.01%, the balance is Ni. The weight percentage of Cr+Ni is greater than 50%, and the weight percentage of W+Mo is 0.6-1.5%. The iron-nickel-based superalloy of the present invention has high durable strength, high impact toughness and good steam oxidation resistance; γ' phase and M 23 C 6 It is the main strengthening phase; compared with the existing technology, its processing performance is equivalent and the material cost is low, but it has better structural stability, high temperature strength and impact toughness, and can be used to manufacture ultra-supercritical thermal power units at 650 °C and above High-temperature components such as main steam pipes, headers and high-temperature section rotors.

Description

technical field [0001] The invention relates to the technical field of high-temperature metal structural materials, in particular to a high-strength, high-toughness, oxidation-resistant iron-nickel-based superalloy and a preparation method thereof. Background technique [0002] Coal-fired thermal power units provide more than 70% of domestic electricity, but domestic thermal power units have low average power generation efficiency and high energy consumption, and are the main emission sources of sulfur dioxide, nitride NOx, carbon dioxide and mercury. With the improvement of environmental protection requirements, it is necessary to significantly reduce and reduce the carbon dioxide emissions per unit of GDP. In the field of coal power, adopting high-parameter and large-capacity thermal power units is one of the most direct, economical and effective measures to realize the clean and efficient utilization of coal. At present, all developed countries in the world, China and In...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C30/00C22F1/00
CPCC22C19/055C22C19/056C22C30/00C22C38/02C22C38/04C22C38/06C22C38/44C22C38/48C22C38/50C22C38/52C22C38/54C22F1/00
Inventor 袁勇张鹏严靖博周永莉尹宏飞党莹樱杨珍黄锦阳鲁金涛谷月峰
Owner HUANENG POWER INT INC
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