Styrene-acrylic emulsion, preparation method and application thereof, and latex paint
A styrene-acrylic emulsion and coating technology, applied in latex paints, coatings, etc., can solve problems such as low viscosity and poor emulsion polymerization stability
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[0034] The present invention also provides a kind of preparation method of styrene-acrylic emulsion, it comprises the steps:
[0035] S1. Preparation according to the ratio of each raw material component of the styrene-acrylic emulsion described in any embodiment of the present invention.
[0036] Specifically, prepare materials according to the following raw material components in the following mass percentages:
[0037]
[0038] Among them, commercially available styrene, butyl acrylate and acrylic acid monomers mostly contain polymerization inhibitors to prevent self-polymerization, requiring monomer purification. Among them, the polymerization inhibitor in styrene and acrylic acid is hydroquinone, which is removed by alkali washing, and hydroquinone is reacted with sodium hydroxide to generate sodium hydroquinone. The polymerization inhibitor of butyl acrylate is p-hydroxyanisole, which is removed with a sodium hydroxide solution with a concentration of 4%-6%.
[0039...
Embodiment 1
[0061] A kind of preparation method of styrene-acrylic emulsion, it comprises the steps:
[0062] Monomer pre-emulsion preparation:
[0063] In a three-necked flask equipped with a stirrer, 80 g of distilled water was added at a constant temperature, and 4 g (3% equivalent) of a composite emulsifier was added, wherein the mass ratio of SDS and OP-10 was 1:1. Stir rapidly for 20 minutes; add 25 g of styrene, 25 g of butyl acrylate and 0.8 g of acrylic acid in sequence, and continue to stir for 30 minutes to make the emulsification uniform to obtain a milky white monomer pre-emulsion, which is taken out for use.
[0064] Seed Emulsion Polymerization:
[0065] A four-necked flask equipped with an electric stirrer, a spherical reflux condenser, a thermometer and a constant-pressure dropping funnel was placed in a constant temperature water bath, 20 g of distilled water was added, the speed of the stirrer was adjusted to 350 r / min, and the temperature was gradually increased by st...
Embodiment 2
[0070] A preparation method of a styrene-acrylic emulsion, the preparation method is generally the same as that of Example 1, the difference is: in the preparation process of the monomer pre-emulsion, the additions of styrene and butyl acrylate are respectively 20g and 30g.
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