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Leaching process of magnesium ions in serpentine

A technology of serpentine and magnesium ions, which is applied in the field of hydrometallurgy, can solve the problems of high energy consumption, low extraction efficiency, equipment corrosion, etc., and achieve the goal of reducing the degree of corrosion, reducing economic and environmental costs, and prolonging the service life Effect

Pending Publication Date: 2020-04-24
NORTHEASTERN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical task of the present invention is to propose a high-efficiency and economical leaching process for magnesium ions in serpentine, aiming at the problems of low efficiency in extracting magnesium ions in serpentine, high energy consumption in the process, and serious equipment corrosion.

Method used

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  • Leaching process of magnesium ions in serpentine
  • Leaching process of magnesium ions in serpentine

Examples

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Comparison scheme
Effect test

Embodiment 1

[0033] A kind of leaching process of magnesium ion in serpentine, operation such as figure 1 shown, including the following steps:

[0034] (1) Under normal pressure, weigh 15g of the serpentine ore sample to be treated and put it into a beaker, add a leaching agent at a liquid-solid ratio of 4:1 by mass, pour it into a three-necked flask after mixing, and add the leaching agent sulfuric acid The amount is 1.1 times of the theoretical amount; place the three-neck flask in a water bath at 90°C, and stir continuously at a speed of 300r / min;

[0035] (2) After stirring for 3min, add leaching aid fluorite ore powder, the fluorite ore powder add-on is 1% of the serpentine ore sample quality; keep stirring, after the ore sample is leached for 2h, it is filtered and rinsed, The leaching solution was recovered, and then the leaching residue was dried, weighed, sample-prepared, tested, and the leaching rate was calculated; the leaching rate of magnesium oxide was 88.10%.

Embodiment 2

[0037] A process for leaching magnesium ions in serpentine, comprising the steps:

[0038] (1) is identical with step (1) reaction condition among the embodiment 1;

[0039] (2) After stirring for 3min, add leaching aid fluorite ore powder, the fluorite ore powder add-on is 3% of the serpentine ore sample quality; keep stirring, after the ore sample is leached for 2h, it is filtered, rinsed, The leaching solution was recovered, and then the leaching residue was dried, weighed, sample-prepared, tested, and the leaching rate was calculated; the leaching rate of magnesium oxide was 90.46%.

Embodiment 3

[0041] A process for leaching magnesium ions in serpentine, comprising the steps:

[0042] (1) is identical with step (1) reaction condition among the embodiment 1;

[0043] (2) After stirring for 3min, add leaching aid fluorite ore powder, the fluorite ore powder add-on is 5% of the serpentine ore sample quality; keep stirring, after the ore sample is leached for 2h, it is filtered, rinsed, The leaching solution was recovered, and then the leaching residue was dried, weighed, sample-prepared, tested, and the leaching rate was calculated; the leaching rate of magnesium oxide was 94.88%.

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Abstract

The invention relates to a leaching process of magnesium ions in serpentine. The process includes the steps of: mixing serpentine with a leaching agent, carrying out normal-pressure water bath reaction at a stirring rate of 200-600r / min, adding fluorite mineral powder serving as a leaching aid when stirring is carried out for 1-3min, and after continuous reaction and leaching for 1-4h, performingfiltering to obtain magnesium ion leachate. The leaching aid adopted in the process is relatively small in dosage, cheap and easily available, safe and non-toxic, and free of environmental pollution,thus providing a more suitable leaching aid for improving the serpentine acid leaching efficiency. Besides, the leaching process can realize efficient acid leaching of serpentine under normal pressure, increases the pH value of leaching liquid, and alleviates the corrosion to leaching equipment. Also the leaching method is simple to operate and easily controllable, and is easy to realize industrialization.

Description

technical field [0001] The invention relates to the field of hydrometallurgy, in particular to a process for leaching magnesium ions in serpentine. Background technique [0002] At present, in the development and utilization process of serpentine, due to the nature of the ore, the mining process, and the dressing and smelting technology, a large number of serpentine tailings will be produced, accounting for about one-third to two-thirds of the mining volume. The discharge and accumulation of a large number of serpentine tailings not only occupy land, but also cause serious environmental pollution and natural ecological damage, affecting the normal production order. In addition, serpentine tailings contain about 40% magnesium and a small amount of other metal elements. If these valuable metal elements are not recycled, it will cause a great waste of metal mineral resources and bring huge losses to the national economy. Therefore, effectively solving the problem of comprehens...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B26/22C22B3/08
CPCC22B26/22C22B3/08Y02P10/20
Inventor 刘文刚彭祥玉刘文宝陈旭东王本英翟菊彬
Owner NORTHEASTERN UNIV