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Super-hydrophobic light polyurethane micro-nano fiber sponge as well as preparation method and application thereof

A micro-nano fiber and super-hydrophobic technology, applied in separation methods, fiber chemical characteristics, chemical instruments and methods, etc., can solve problems such as poor mechanical strength, low efficiency, pollution and clogging, and achieve high porosity and high oil flux performance effect

Active Publication Date: 2020-05-08
HEFEI KETIAN WATERBORNE TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional water treatment methods mainly use membrane separation and adsorption methods, gravity precipitation methods, and thermochemical treatment methods. Although the water body can be purified to a certain extent, these methods generally have high energy consumption, low flux, and The problem of low efficiency and long cycle, some methods still have the problem of secondary pollution to the environment, which can no longer meet the current high-efficiency purification requirements of polluted water bodies. Although membrane materials have certain advantages over other methods, they are easily blocked by pollution. And at the same time, there is poor mechanical strength, which also limits its further application

Method used

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  • Super-hydrophobic light polyurethane micro-nano fiber sponge as well as preparation method and application thereof
  • Super-hydrophobic light polyurethane micro-nano fiber sponge as well as preparation method and application thereof
  • Super-hydrophobic light polyurethane micro-nano fiber sponge as well as preparation method and application thereof

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Experimental program
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preparation example Construction

[0059] The fluorinated polyurethane emulsion with the structure of formula I can be synthesized by an alcohol-soluble method, and the synthesis method can include: reacting polyether polyol with polyisocyanate at 80-95°C after vacuum dehydration treatment at 100-120°C, and testing After the remaining NCO group reaches the theoretical residual value, lower the temperature to 50-70°C, and then add fluorinated small molecule chain extender, fluorinated alcohol monomer, small molecule chain extender, cationic hydrophilic chain extender, and crosslinking agent , The catalyst continued to keep warm for 1 to 5 hours. After testing that the remaining NCO groups reached the theoretical residual value, lower the temperature to 25 to 45°C, add neutralizer and ethanol and emulsify under the action of high-speed shear force, then add emulsifier and Defoaming agent, after emulsification, remove the solvent at 35-55°C for 1-2 hours to obtain the fluorinated polyurethane resin with the structu...

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Abstract

The invention provides a super-hydrophobic light polyurethane micro-nano fiber sponge as well as a preparation method and application thereof. The micro-nano fiber sponge comprises nano-scale fibers with the diameter ranging from 200 nm to 800 nm and micron-scale fibers with the diameter ranging from 5 micrometers to 15 micrometers. The nano-scale fiber comprises fluorinated polyurethane with a structure shown as a formula I; the micro-nano fiber sponge is a three-dimensional light sponge with micron-sized fibers as a frame structure and nano-sized fibers as a main body filling structure. Thepolyurethane light sponge has efficient oil stain water body purification treatment capacity, and has certain application value in the fields of water body cleaning purification and self-protection such as oily water purification treatment, oil-water separation, self-cleaning, water prevention and pollution resistance due to the excellent performance of the polyurethane light sponge.

Description

technical field [0001] The invention belongs to the field of functional fiber materials and polymer synthesis, and more specifically relates to a superhydrophobic lightweight polyurethane micro-nano fiber sponge and its preparation method and application. Background technique [0002] In recent years, with the popularization of the global industrialization process and the rapid development of the economy, there have been frequent accidents of dumping of oil and heavy metal waste liquids mainly polluting marine oil and industrial wastewater to pollute the environment of rivers and marine water bodies, triggering global environmental crisis within. However, the traditional water treatment methods mainly use membrane separation and adsorption methods, gravity precipitation methods, and thermochemical treatment methods. Although the water body can be purified to a certain extent, these methods generally have high energy consumption, low flux, and The problem of low efficiency a...

Claims

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Application Information

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IPC IPC(8): C08L75/08C08L33/26C08L77/10C08L67/02C08L67/00C08J9/28C08G18/66C08G18/48C08G18/32C08G18/10D01F6/94D01F1/10B01D39/04
CPCC08J9/28C08J9/0061C08G18/4833C08G18/4854C08G18/4825C08G18/4808C08G18/10D01F6/94D01F1/10B01D39/04B01D2239/1208B01D2239/1258B01D2239/1291C08J2375/08C08J2433/26C08J2477/10C08J2467/02C08J2467/00C08G18/3812C08G18/3814C08G18/3206C08G18/3275C08G18/3281
Inventor 李维虎闫成成朱保凌赵曦戴家兵
Owner HEFEI KETIAN WATERBORNE TECH CO LTD