Super-hydrophobic light polyurethane micro-nano fiber sponge as well as preparation method and application thereof
A micro-nano fiber and super-hydrophobic technology, applied in separation methods, fiber chemical characteristics, chemical instruments and methods, etc., can solve problems such as poor mechanical strength, low efficiency, pollution and clogging, and achieve high porosity and high oil flux performance effect
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[0059] The fluorinated polyurethane emulsion with the structure of formula I can be synthesized by an alcohol-soluble method, and the synthesis method can include: reacting polyether polyol with polyisocyanate at 80-95°C after vacuum dehydration treatment at 100-120°C, and testing After the remaining NCO group reaches the theoretical residual value, lower the temperature to 50-70°C, and then add fluorinated small molecule chain extender, fluorinated alcohol monomer, small molecule chain extender, cationic hydrophilic chain extender, and crosslinking agent , The catalyst continued to keep warm for 1 to 5 hours. After testing that the remaining NCO groups reached the theoretical residual value, lower the temperature to 25 to 45°C, add neutralizer and ethanol and emulsify under the action of high-speed shear force, then add emulsifier and Defoaming agent, after emulsification, remove the solvent at 35-55°C for 1-2 hours to obtain the fluorinated polyurethane resin with the structu...
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