Low-VOC sponge as well as preparation method and application thereof

A sponge and nanoparticle technology, applied in chemical instruments and methods, layered products, transportation and packaging, etc., can solve the problems of limiting the use of polyurethane foam, achieve uneven hardness, good recyclable catalytic effect, and reduce VOC content Effect

Inactive Publication Date: 2020-05-15
SAGE AUTOMOTIVE INTERIORS WUHAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This method reduces the VOC produced by polyurethane foam to a certain extent, but the toxic and harmful gas produced by the burning of raw material polyether polyol and foam in the process of automobile interior decoration is still the main source of VOC emissions of polyurethane foam, which seriously limits the production of polyurethane foam. usage of

Method used

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  • Low-VOC sponge as well as preparation method and application thereof
  • Low-VOC sponge as well as preparation method and application thereof
  • Low-VOC sponge as well as preparation method and application thereof

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preparation example Construction

[0031] The preparation method of low VOC sponge, comprises the following steps:

[0032] Ⅰ. Preparation of RGO / TiO 2 Nanoparticles: Add 10 to 50 parts of graphene oxide to the mixed solution of ethanol and deionized water for 30 minutes of ultrasonic vibration, then transfer the mixed solution to a hydrothermal kettle, and divide 50 parts of TiO 2 Pour the powder into a hydrothermal kettle and stir at high speed for 10 minutes; raise the temperature to 120°C and stir for 3 hours; after the reaction, wash the final product with ethanol and deionized water until neutral, and finally dry it at 80°C to obtain RGO / TiO 2 nanoparticles;

[0033] Ⅱ. Mix 30 parts of grafted polyether polyol, 60 parts of high activity polyether polyol, 1 part of catalyst, 1 part of foam stabilizer, 1 part of chain extender, 3 parts of blowing agent, 0.5 part of flame retardant, 0 ~0.6 part RGO / TiO 2 Add nanoparticles and water into the reaction kettle, stir ultrasonically for 30 minutes, and config...

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Abstract

The invention discloses low VOC sponge which comprises the following components: grafted polyether polyol, a highly active polyether polyol, a catalyst, a foam stabilizer, a chain extender, a foamingagent, a flame retardant, RGO/TiO2 nanoparticles, and diphenylmethane diisocyanate. A preparation method comprises the steps: preparing the RGO/TiO2 nanoparticles, preparing finished sponge, preparinga composite fabric, embossing and solarizing. The low VOC sponge is applied to automotive trim. The process is simple, and the VOC content in the composite fabric can be effectively reduced; RGO/TiO2is used as a photoelectron catalyst and does not participate in a chemical reaction, so that a good recyclable catalytic effect is achieved, and the problem of subsequent VOC release of the polyurethane sponge can be continuously and effectively solved; the sponge prepared by the invention is applied to embossing, the embossing forming effect is good, and the pattern appearance is uniform; the problem that a traditional half-ether half-ester polyurethane sponge is uneven in hardness is solved, and the application prospect is wide.

Description

technical field [0001] The invention relates to a sponge, its preparation method and application, in particular to a low-VOC sponge, its preparation method and its application. Background technique [0002] Polyurethane foam is widely used in the automotive interior industry due to its good thermoplasticity, high strength, high elongation, good resilience, wear resistance, oil resistance, solvent resistance, aging resistance and low temperature resistance. The materials used in the synthesis of polyurethane sponge contain a large amount of benzene series and aldehydes. However, due to the production of polyurethane foam and the processing of automobile interiors, a large amount of VOC gas will be generated, which will pollute the environment inside the car and cause great harm to the human body. [0003] At present, the research on VOC reduction of polyurethane foam at home and abroad has not been interrupted, such as using non-volatile or reactive amine catalysts to partia...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/66C08G18/48C08G18/44C08G18/38C08K3/04C08K3/22C08J9/30B32B27/40B32B27/18B32B27/12B32B27/02B32B27/36C08G101/00
CPCB32B5/02B32B5/18B32B5/245B32B2262/0284B32B2266/0278B32B2605/003C08G18/3814C08G18/44C08G18/48C08G18/6618C08G18/7671C08G2101/00C08J9/30C08K3/22C08K2003/2241C08K2201/011C08K3/042
Inventor 张赤兵陶维恩
Owner SAGE AUTOMOTIVE INTERIORS WUHAN
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