Application of amomum maximum extract in preparation of alpha-glucosidase inhibitor drug
A technology of glucosidase and cardamom, which is applied in the field of medicinal chemistry to improve the occurrence and development, reduce production and absorption, and protect the function of the pancreas
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Embodiment 1
[0031] Preparation and identification of embodiment 1 formula I compound
[0032] Take 2 kg of dry cardamom rhizomes and crush them, heat and reflux them with 5L of 95% ethanol for three times, combine the three extracts and concentrate under reduced pressure until there is no alcohol smell, add pure water until the total volume is 1L, and use an equal volume of ethyl acetate The ester was extracted three times, and the combined ethyl acetate extracts were concentrated to dryness under reduced pressure.
[0033] The ethyl acetate extract was subjected to silica gel column chromatography with petroleum ether-acetone gradient elution. Collect petroleum ether-acetone 95:5 eluted fractions and recover to dryness under reduced pressure. After silica gel column chromatography, dichloromethane-methanol gradient elution, collect 99:1 elution fraction, this fraction utilizes Sephadex LH-20 gel column chromatography, dichloromethane-methanol 1:1 elution, obtain formula I compound.
Embodiment 2
[0034] Preparation and identification of embodiment 2 formula I compound
[0035] Take 2 kilograms of dried cardamom rhizomes and grind them, extract by percolation with 20L 95% ethanol, combine the alcohol extracts, concentrate under reduced pressure to about 2L, add 500 grams of pretreated macroporous resin (resin model can be D101, AB -8, HPD-100 and HP20, etc.). After fully volatilizing to remove ethanol, pack the column, ethanol-water gradient elution (0, 30%, 60%, 80% and 95% ethanol), 80% ethanol eluted fraction is the target fraction, and concentrate to dryness under reduced pressure. Through silica gel column chromatography, petroleum ether-acetone gradient elution. Collect petroleum ether-acetone 95:5 eluted fractions and recover to dryness under reduced pressure. After silica gel column chromatography, dichloromethane-methanol gradient elution, collect 99:1 elution fraction, this fraction utilizes Sephadex LH-20 gel column chromatography, dichloromethane-methanol ...
Embodiment 3
[0036] Preparation and identification of embodiment 3 formula I compound
[0037]Take 2 kilograms of dried cardamom rhizomes and grind them, heat and reflux them with 5L of methanol to extract three times, combine the three extracts and combine the alcohol extracts, concentrate under reduced pressure to about 2L, add 500 grams of pretreated macroporous resin (resin type can be for D101, AB-8, HPD-100 and HP20, etc.). After fully volatilizing to remove methanol, pack the column, ethanol-water gradient elution (0, 30%, 60%, 80% and 95% ethanol), the fraction eluted with 80% ethanol is the target fraction, and concentrate to dryness under reduced pressure. Through silica gel column chromatography, petroleum ether-acetone gradient elution. Collect petroleum ether-acetone 95:5 eluted fractions, and recover to dryness under reduced pressure. After silica gel column chromatography, dichloromethane-methanol gradient elution, collect 99:1 elution fraction, this fraction utilizes Seph...
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