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TPU film and preparation method thereof

A thin film and film layer technology, applied in chemical instruments and methods, lamination, coating, etc., can solve problems such as poor customer experience, limitations, and poor durability

Inactive Publication Date: 2020-08-11
湖南中天碧水膜科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Whether it is the application of curved screen protective film or the self-healing protective film of the top paint in the automotive industry, the raw materials require a large amount of TPU film substrates, and most of these film substrates rely on imports and are expensive
At present, the TPU substrates used in electronic curved surface protective films and automotive self-repairing protective films on the market are basically made by high-temperature extrusion molding, so the thickness uniformity is relatively poor, which affects its optical effect; and this type of TPU In order to improve its mechanical properties (breaking strength), the film mostly uses raw materials containing benzene rings. The protective film made of TPU synthesized by such raw materials has excellent mechanical properties, but it has a fatal flaw: under the action of ultraviolet rays, it will Initiate the decomposition of urethane bonds to generate aromatic amines. After the benzene nuclei on the aromatic amines are oxidized and rearranged, they generate chromophoric groups such as quinone structures, so that the produced TPU film products are easy to yellow and have poor durability. It limits its application on electronic protective film and car coating film, and the customer experience is poor

Method used

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  • TPU film and preparation method thereof
  • TPU film and preparation method thereof
  • TPU film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment example 1

[0020] Select solid content 50wt%, number average molecular weight 180000, viscosity 40000cps, aliphatic hydrocarbon polyurethane resin, its transmittance is more than 90%, use solvent MEK to dilute the viscosity of this TPU solution to within 20000cps, dilute the TPU solution after dilution with Coating on a 70μm PET heavy-release film with a release force of 600g at a speed of 5m / min, and then passing through temperatures of 50°C, 80°C, 130°C, 150°C, 140°C and wind frequencies of 400Hz, 600Hz, 1000Hz, 1500Hz , 1800Hz 5-section oven drying, and finally on-line lamination on a 40μm PET light release film with a release force of 350g to obtain a TPU film.

Embodiment 2

[0022] Different from Example 1, an aliphatic hydrocarbon polyurethane resin with a solid content of 50 wt%, a number average molecular weight of 210,000, and a viscosity of 40,000 cps was selected.

Embodiment 3

[0024] Different from Example 1, an aliphatic hydrocarbon polyurethane resin with a solid content of 50 wt%, a number average molecular weight of 130,000, and a viscosity of 40,000 cps was selected.

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Abstract

The invention provides a TPU film comprising a resin layer. A heavy release film layer is arranged on one side of the TPU resin layer; a light release film layer is arranged on the other side far awayfrom the heavy release film layer of TPU resin layer; the release force of the heavy release film layer ranges from 500 g / 25 mm to 700 g / 25 mm, and the release force of the light release film layer ranges from 300 g / 25 mm to 500 g / 25 mm. By means of the TPU film, when the light release film layer on one side of the TPU resin layer is uncovered, the heavy release film layer is uncovered and separated, and bubbles are generated.

Description

technical field [0001] The present invention relates to films, in particular to TPU films. Background technique [0002] Thermoplastic polyurethane (TPU) not only has the rubber characteristics of high strength and high wear resistance of cross-linked polyurethane, but also has the thermoplastic properties of linear polymer materials, so that its application can be extended to the field of plastics. Especially in recent decades, TPU has become one of the fastest growing polymer materials. TPU film is an important application form of TPU material. In recent years, it has been more and more widely used with the development and progress of high technology. [0003] It is precisely because TPU has excellent wear resistance, tear resistance, and flexion strength; high tensile strength, high elongation, and low long-term compression set rate. At the same time, it has good resistance to oils (mineral oil, animal and vegetable oils and lubricating oils) and many solvents; TPU also...

Claims

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Application Information

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IPC IPC(8): B32B27/40B32B27/08B32B33/00B32B37/00B32B38/16C08J7/04C09D175/04C08L67/02
CPCB32B27/08B32B27/40B32B33/00B32B37/00B32B38/164B32B2038/168C08J2367/02C08J2475/04C08J7/0427
Inventor 葛建峰徐金龙孔祥永耿龙飞
Owner 湖南中天碧水膜科技有限公司
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