High-voltage cable insulating material and preparation method and application thereof

A technology of insulating materials and high-voltage cables, which is applied in the field of insulating materials processing, can solve problems such as unexplained dielectric properties and conventional mechanical properties, long-term safety hazards of high-voltage cables, low cross-linking agent content and high cross-linking degree, etc. Achieve low cost, excellent anti-water tree effect, low processing energy consumption

Pending Publication Date: 2020-09-08
ZHEJIANG WANMA MACROMOLECULE MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The temperature resistance level of non-cross-linked polyethylene is low, which cannot meet the long-term use requirements of high-voltage power cables at high temperatures for a long time. By adding a cross-linking agent to change the cross-linking of LDPE into cross-linked polyethylene (XLPE) to improve its Temperature class
[0003] However, the insulation materials of high-voltage power cables commonly used at present have the following problems: the degassing time of cross-linked polyethylene is too long.
At the same time, cross-linked polyethylene has poor water tree resistance, and the long-term service life of the cable is short
[0004] Patent document CN108623877A discloses an insulating material for high-voltage DC cables with low cross-linking agent content and high cross-linking degree. The method of reducing the content of cross-linking agent by adding a cross-linking agent effectively reduces thermal elongation, but it only The thermal elongation performance of the material is analyzed, other dielectric properties and conventional mechanical properties are not described

Method used

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  • High-voltage cable insulating material and preparation method and application thereof
  • High-voltage cable insulating material and preparation method and application thereof
  • High-voltage cable insulating material and preparation method and application thereof

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preparation example Construction

[0067] The present invention also provides a method for preparing the high-voltage cable insulating material according to the present invention, comprising the step of mixing the components of the high-voltage cable insulating material.

[0068] Specifically, the preparation method of the high-voltage cable insulation material includes the following steps:

[0069] Melt and blend low-density polyethylene, antioxidants, polybutadiene additives and polymer material additives, then cool and granulate to obtain granules;

[0070] The particles are mixed with the cross-linking agent and absorbed uniformly to obtain a high-voltage cable insulation material.

[0071] Further, the preparation method of the high-voltage cable insulation material includes the following steps:

[0072] Step 1: Melt and blend low-density polyethylene, antioxidants, polybutadiene additives and polymer material additives, then cool and granulate to obtain granules; wherein, the melt blending equipment incl...

Embodiment 1

[0078] In parts by weight, 100 parts of low-density polyethylene (LDPE), 0.5 parts of liquid polybutadiene (LPB) with a viscosity of 1000mPa·s, 0.5 parts of high-density polyethylene (HDPE), 0.2 parts of 4,4'-sulfur Substituting bis(6-tert-butyl-3-methylphenol) (TBM-6) through a reciprocating single-screw extruder after melt blending, cooling and granulation, and drying to obtain granules;

[0079] Melting temperature process: The temperature of the six zones are: 130, 150, 185, 200, 200, 200°C; the rotating speed is 960RPM; the cooling circulating water is 50°C.

[0080] The particles were mixed with the 1.1 parts of bis(1-methyl-1-phenylethyl)peroxide (DCP) at a constant temperature of 70° C. and absorbed uniformly for more than 16 hours to obtain a high-voltage cable insulation material.

[0081] The air and environment cleanliness meet the necessary conditions for the production of high-voltage cable insulation materials.

Embodiment 2

[0083] In parts by weight, 100 parts of low-density polyethylene (LDPE), 1.0 part of liquid polybutadiene (LPB) with a viscosity of 3000mPa·s, 1.0 part of high-density polyethylene (HDPE), 0.2 part of 4,4'- Thiobis(6-tert-butyl-3-methylphenol) (TBM-6), cooled and granulated after melting and blending by a reciprocating single-screw extruder, and obtained granules after drying;

[0084] Its process and environmental conditions are identical with embodiment 1;

[0085] The particles were mixed with the 1.2 parts of bis(1-methyl-1-phenylethyl)peroxide (DCP) at a temperature of 70° C. and absorbed uniformly at a constant temperature for more than 16 hours to obtain a high-voltage cable insulation material.

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Abstract

The invention provides a high-voltage cable insulating material and a preparation method and application thereof. The high-voltage cable insulating material comprises the components in parts by weight: 100 parts of low density polyethylene; 0.1 to 0.3 part, preferably 0.15 to 0.20 part, of an antioxidant; 1.0 to 2.0 parts, preferably 1.0 to 1.5 parts, of a cross-linking agent; 0.5 to 5.0 parts, preferably 0.5 to 2.0 parts, of a polybutadiene auxiliary agent; and 0.5-10.0 parts, preferably 0.5-5.0 parts, of a high polymer material additive. The high-voltage cable insulating material disclosed by the invention is excellent in comprehensive insulating property; the high-voltage cable insulating material disclosed by the invention has excellent breakdown strength stability, and meanwhile, an excellent water-tree-resistant effect is obtained, so that the long-term use stability of the material can be obviously improved. Furthermore, the preparation method of the high-voltage cable insulating material can greatly reduce the use amount of the cross-linking agent, has lower processing energy consumption, effectively reduces the cost, is suitable for industrial long-time stable production,and indirectly shortens the degassing time.

Description

technical field [0001] The invention relates to a high-voltage cable insulating material and a preparation method and application thereof, belonging to the technical field of insulating material processing. Background technique [0002] Most of the existing domestic insulation materials for power cables use low-density polyethylene (LDPE) as the base material, adding certain antioxidants and crosslinking agents. The temperature resistance level of non-cross-linked polyethylene is low, which cannot meet the long-term use requirements of high-voltage power cables at high temperatures for a long time. By adding a cross-linking agent to change the cross-linking of LDPE into cross-linked polyethylene (XLPE) to improve its Temperature rating. [0003] However, the commonly used insulating materials for high-voltage power cables have the following problems: the degassing time of cross-linked polyethylene is too long, and if the degassing is insufficient, small molecule precipitate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L47/00C08L23/08C08L23/12
CPCC08L23/06C08L2205/03C08L2205/035C08L2205/025C08L2207/066C08L2207/062C08L2203/202C08L47/00C08L23/12C08L23/0815
Inventor 刘敬锐李秀娟张斌刘美兵帅选阳陈文卿
Owner ZHEJIANG WANMA MACROMOLECULE MATERIAL
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