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A kind of preparation technology of copper-tin alloy powder with low tin content

A copper-tin alloy and powder preparation technology, which is applied in the field of copper-tin alloy powder processing, can solve the problems of low activity, uneven distribution of Sn content, discounted application effect, etc.

Active Publication Date: 2021-05-18
湖南省天心博力科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the copper-tin powder with low tin content (tin content 5% and below) prepared by the traditional high-temperature smelting-atomization process has large tin burning loss, unstable content, large fluctuations, uneven distribution of Sn content, and Sn in the copper matrix. It is in the disadvantages of complete alloying, low activity, low catalytic activity, low temperature sintering and low alloying activity, so its application effect is greatly reduced

Method used

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  • A kind of preparation technology of copper-tin alloy powder with low tin content

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028]A low tin content copper tin alloy powder preparation process, the specific method is as follows:

[0029](1) Copper tin powder mixing: It is used to use a precision weighing technique to weigh tin powder from 99.9%, adding 95 wt% purity of no less than 99.9% water atomized copper powder for mixing, mixing ,spare. Among them, the particle size of tin powder is less than 100 μm, and the particle diameter of the copper powder is less than 150 μm.

[0030]It is worth noting that the accuracy of the precision weighing technique of tin powder is controlled between 0.145 to 0.155%.

[0031](2) High energy ball milling: The above mixed uniform copper tin powder and stearic acid are added to the high energy ball mill, and the ball mill is carried out at normal temperature under nitrogen or inert gas, wherein the medium is a cast steel ball for DB5mm, and the material ball ratio is 1:25, the filling coefficient is 0.4, the ball mill is 100 min, and after the ball milling for 40 min, the SDBS-EB...

Embodiment 2

[0037]A low tin content copper tin alloy powder preparation process, the specific method is as follows:

[0038](1) Copper tin powder mixing: It is used to weigh 5% by weight of the purity of no less than 99.9%, adding 95 wt% purity, no less than 99.9% of water atomized copper powder, then joined Polyethylene glycol, added amount of copper tin alloy powder 0.4% by weight, mix well, spare. Among them, the particle size of tin powder is less than 100 μm, and the particle diameter of the copper powder is less than 150 μm. Precision weighing techniques of tin powder are controlled between 0.145 to 0.155%.

[0039](2) High energy ball milling: The preparation process is the same as in the first embodiment, and is specifically referred to in Example 1.

[0040](3) Airflow classification: The preparation process is the same as in the first embodiment, and is specifically referred to in Example 1.

Embodiment 3

[0042]A low tin content copper tin alloy powder preparation process, the specific method is as follows:

[0043](1) Copper tin powder mixed: It is used to weigh tin powder from 0.1% by weight of 0.9% purity, adding 99.9% by weight of water atomized copper powder to 99.9% by weight. Polyethylene glycol was added, and the added amount was 0.2% by weight of the copper tin alloy powder, and the mixture was mixed. Among them, the particle size of tin powder is less than 100 μm, and the particle diameter of the copper powder is less than 150 μm. Precision weighing techniques of tin powder are controlled between 0.145 to 0.155%.

[0044](2) High energy ball milling: The above-mentioned mixed uniform copper tin powder and stearic acid are added to the high energy ball mill, and the ball mill is performed at normal temperature under nitrogen or inert gas, wherein the medium is a cast steel ball of DB10mm, and the material ball ratio is 1:20, the filling coefficient is 0.3, the ball milling time is...

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Abstract

The invention discloses a process for preparing copper-tin alloy powder with low tin content, and relates to the technical field of copper-tin alloy powder processing. The copper-tin alloy powder with low tin content disclosed by the present invention is prepared by copper-tin powder mixing-high-energy ball mill-airflow classification process, and the tin-copper alloy powder obtained by mechanical alloying preparation process has irregular and scale-like microscopic appearance , the specific surface area is larger, the surface is more developed, and it has the advantages of high chemical catalytic activity, high low-temperature sintering activity and good low-temperature alloying effect. The invention is simple in process and easy to operate, adopts processes such as airflow classification and dispersion treatment, so that the copper-tin alloy powder product has good dispersibility, and the average particle diameter D50 and particle size distribution can be adjusted and controlled according to user requirements, greatly improving product application performance and meeting customer requirements. Product quality requirements.

Description

Technical field[0001]The present invention belongs to the technical field of copper tin alloy powder processing, and more particularly to a low tin content copper tin alloy powder preparation process.Background technique[0002]As the earliest alloy in human application, Copper Tin Alloy has been used in the history of 4,000 years. The smelting and production of copper-tin alloy is easier than pure copper, and the strength is significantly improved by pure copper, and wear resistant, chemical resistance is stable. When the tin content is less than 5%, the α solid solution is mainly formed in the copper tin alloy, exhibiting excellent plastic properties; when the amount of tin containing is close to 7%, Cu Tin alloy appears in Cu31SN8The base solid solution, the plastic deformation ability, the high temperature environment, Cu31SN8The base solid solution is decomposed and diffused, and recrystallization, there is a good thermal processability; when the amount of tin containing is more ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F9/04B22F1/00
CPCB22F1/0003B22F9/04B22F2009/042B22F2009/043
Inventor 李钢黄雄辉张拥军杨丛红
Owner 湖南省天心博力科技有限公司