61 results about "Gunmetal" patented technology

A metallic material for a connecting part, having a rectangular wire material of copper or a copper alloy as a base material, and formed at an outermost surface thereof, a copper-tin alloy layer substantially composed of copper and tin, wherein the copper-tin alloy layer of the outermost surface further contains at least one selected from the group consisting of zinc, indium, antimony, gallium, lead, bismuth, cadmium, magnesium, silver, gold, and aluminum, in a total amount of 0.01% or more and 1% or less in terms of mass ratio with respect to the content of the tin.

The invention discloses a preparation method of copper-tin alloy with high tin content and high density. The preparation method comprises the following steps of step 1, weighing 83.2-84.3wt% of Cu powder, 15.4-16.5% of Sn powder and 0.3% of Ti powder according to the mass percentage, uniformly mixing the components by a ball grinding mill, and thus obtaining mixed powder; step 2, cold-pressing themixed powder in the step 1 to obtain a cold pressed billet, and putting the cold pressed billet into a spray deposition furnace for spray deposition, and obtaining pre-alloyed powder; and step 3, sieving the pre-alloyed powder in the step 2, conducting secondary cold pressing to obtain a secondary cold pressed billet, then putting the secondary cold pressed billet into an atmosphere sintering furnace, introducing inert gas into the furnace, heating and pressurizing the atmosphere sintering furnace, holding temperature for a while, finally decreasing temperature and reducing pressure of the atmosphere sintering furnace, and thus obtaining the copper-tin alloy. The preparation method increases the content of tin in the copper-tin alloy, the distribution of tin is more uniform, and the density and hardness of the copper-tin alloy are ensured.

The invention discloses a preparation process of low-content copper-tin alloy powder, and relates to the technical field of copper-tin alloy powder processing. The disclosed low-content copper-tin alloy powder is prepared by copper-tin powder mixing, high-energy ball milling and airflow classification processes, and the tin-copper alloy powder obtained by the mechanical alloying preparation process has a microstructure in an irregular scaly shape, a larger specific surface area and a more developed surface, and has the advantages of being higher in chemical catalytic activity, higher in low-temperature sintering activity, good in low-temperature alloying effect and the like. The process is simple and easy and convenient to operate; and by adopting the processes of airflow classification, dispersion treatment and the like, the copper-tin alloy powder product has good dispersity, the average grain diameter D50 and grain fineness distribution can be adjusted and controlled according to user requirements, the application performance of the product is greatly improved, and product quality requirements of customers are met.

The invention belongs to the technical field of grinding materials and grinding tools, and particularly relates to a high-performance metallic bond, a grinding wheel comprising the metallic bond and a preparation method of the grinding wheel. The metallic bond is prepared from the materials in parts by weight: 30-70 parts of copper-tin alloy powder, 5-15 parts of nickel powder, 1-10 parts of silver powder, 5-15 parts of iron powder and 1-5 parts of aluminum oxide powder. The metallic bond further comprises 1-10 wt% of silicon dioxide powder and 10-25 wt% of cobalt powder. The preparation method of the grinding wheel containing the high-performance metallic bond includes the steps that the metallic bond and diamond are mixed for 12-24 h through a high-speed mixing machine; and the mixture of the metal powder and diamond abrasive particles are sintered under the conditions that the temperature is 500-1500 DEG C and the pressure is 1-20 T by using a mold, and demolding is conducted to obtain the grinding wheel containing the high-performance metallic bond. The metallic bond is good in holding performance, the service life of the grinding wheel is long, the bond is good in sharpness, good in heat conductivity and good in heat resistance, and the grinding wheel is uniform in hardness and stable in quality by adopting a heating and pressurizing method.

The invention relates to a composite binding agent grinding wheel for steel rail grinding. The composite binding agent grinding wheel comprises, by weight percent, 28%-45% of modified resin powder, 18%-25% of copper-tin alloy powder, 4%-12% of carbon fibers, 5%-10% of wollastonite, 1%-3% of a wetting agent and the balance grinding materials. The composite binding agent grinding wheel is good in self-sharpening performance, long in service life and high in safety coefficient, the problems happening to grinding under the extreme conditions of high frequency, high pressure and dry grinding duringsteel rail grinding can be solved, and the composite binding agent grinding wheel is used for grinding a steel rail and has the advantages that pressure capable of being borne during grinding is large, the grinding mileage is long, and steel rails are not burnt.

The invention discloses an acidic cyanide-free copper-tin alloy electroplating bath. The electroplating bath is an acidic system and adopts inorganic salt as the main salt, a dispersing agent and a gloss agent are added and used in the electroplating bath, and the system can be used for effectively increasing the current efficiency of a process, thus the deposition velocity of an electroplating layer is increased, and the defect that an alkali cyanide-free copper-tin alloy electroplating layer is thinner is overcome. The electroplating bath disclosed by the invention is simple in operation, low in cost and wide in current density range; and the prepared electroplating layer is uniform and bright in appearance, good in binding force and high in corrosion resistance. The electroplating bath disclosed by the invention contains no cyanide and lead and no other heavy metal additives and organic complexing agents, so that the electroplating bath is safe and environment-friendly, the damage of the electroplating bath to the ecological environment is effectively avoided, and the wastewater treatment cost is effectively reduced.

The invention relates to a method for white copper-tin electroplating on a permanent magnetic material, wherein the method comprises the following steps: (1) chamfering and polishing; (2) degreasing and removing oil; (3) pickling and derusting; (4) carrying out acid liquid activation; (5) electronickelling to form a nickel-plated layer; (6) electrocoppering to form a copper-plated layer; and (7) electroplating with a Cu-Sn alloy to form a Cu-Sn alloy-plated layer: adopting a Cu-Sn alloy electroplating solution, electroplating the permanent magnetic material formed with the copper-plated layer to form the Cu-Sn alloy-plated layer. After the treatment, the electroplating binding force of the plated layer is the same as that of electronickelling; the anticorrosion ability of the plated layer is the same as that of multilayer nickel electroplating; and 20% of electroplating costs can be saved, and using problems of a crowd allergic to nickel is avoided.

The invention discloses a preparation method for reducing apparent density of copper-tin alloy powder. The preparation method comprises the following steps that a high-purity copper plate and pure tin powder are selected as raw materials, and water at 0 DEG C-5 DEG C are taken as an atomized water source during atomization; charcoal is added in the smelting process, the steel casting temperature is 1200 DEG C-1300 DEG C, and powder is dehydrated and dried after atomization; hydrogen is introduced by using a boat pushing type reduction furnace for reduction; alloy powder obtained after reduction is screened; and mixing and blending are conducted to obtain the finished copper-tin alloy powder. The apparent density of the prepared alloy powder ranges from 3.0 g/cm < 3 > to 3.5 g/cm < 3 >, and compared with the apparent density of finished alloy powder prepared through a traditional atomization method ranges from 3.5 g/cm < 3 > to 4.0 g/cm < 3 >, the apparent density of the alloy powder is greatly reduced, and the shape maintaining performance of the pressed powder is facilitated; and a high-quality raw material is provided for a high-end diamond tool, and the sharpness and the wear resistance of the diamond tool are effectively improved. In addition, due to the fact that the atomized water temperature is low, the powder cooling speed is increased after the molten steel is crushed, the oxidation time in the powder flying process is shortened, and therefore powder with the low oxygen content is obtained.

The invention discloses a directional solidification preparation method of a high-tin-content and high-plasticity copper-tin alloy, which comprises the following steps of: 1, weighing a Cu block, Sn and Ti, and pretreating; 2, materials obtained in the step 1 are sequentially put into a magnesia crucible, Ti is put into a feeding hopper for standby application, and a furnace door of a directional solidification furnace is closed; 3, the furnace is vacuumized, then induction melting heating is adopted, molten copper-tin alloy is obtained, a trace titanium element is added into a melt, and heat preservation is conducted to achieve melt homogenization; 4, the molten metal is poured into a constant-temperature cylindrical graphite crucible below for drawing, and a directionally solidified copper-tin alloy cast ingot is obtained after drawing is finished; the problems of low tin solid solubility caused by solute segregation in the existing copper-tin alloy preparation process and poor material plasticity and toughness caused by high intermetallic compound content are solved, meanwhile, the alloy structure is improved, and fine orientation lt is obtained; 001gt, 001gt; and the growing crystal grains synchronously realize directional solidification preparation of the high-solid-solubility and high-plasticity copper-tin alloy.

The invention provides a method for plating tin-copper alloys on surfaces of TC4 titanium alloys and a TC4 titanium alloy module. The method comprises the steps that the surfaces of TC4 titanium alloytarget modules are treated to remove oil stains on the surfaces of the target modules; a first electroplating process is adopted to preplate tin on the surface-treated target modules to form nickel pre-plated layers on the surfaces of the target modules; the target modules are heated after the nickel preplating treatment; a second electroplating process is adopted to perform the nickel impact treatment on the heated target modules to form nickel impacted layers; and a third electroplating process is adopted to plate the copper-tin alloys on the surfaces of the nickel impacted layers to form copper-tin alloy layers. The method can be adopted to prepare the uniform and compact copper-tin alloy layers with excellent wear resistance on the surfaces of the TC4 titanium alloy target modules; and the process is stable in process and convenient to operate, so that the application field of the TC4 titanium alloy target modules can be greatly widened.

The invention discloses a preparation method of CuSn10 powder with low bulk density. The method is characterized by comprising the following steps: selecting pure copper powder prepared by a water atomization method, wherein the granularity of the water atomization pure copper powder is -200 meshes; selecting copper-tin alloy powder prepared by a water atomization method, wherein the granularity of the copper-tin alloy powder is -200 meshes, and the tin content is greater than 10-30%; mixing the pure copper powder and the copper-tin alloy powder according to a proportion, wherein the proportion of the copper to the copper-tin alloy powder is selected to be larger than 0-2.0 times according to the tin content of the copper-tin alloy powder; putting the mixed powder into a reduction furnaceat a reduction temperature of 400-700 DEG C; and crushing and screening the sintered powder, and adjusting the particle size distribution to obtain finished powder. The formed product is stable in performance and good in compressibility and flowability, a pressed green part is high in strength, the shrinkage rate of the powder after sintering is stable, and the structure is fine and uniform.

The invention provides a slotted wheel. Manufacturing material components of the slotted wheel comprise copper-tin alloyed powder, sliver powder and polyimide resin powder, and the components comprise, by weight, 70%-95% of the copper-tin alloyed powder, 3%-10% of the silver powder and 1%-6% of the polyimide resin powder. The slotted wheel is good in heat resistance, long in service life, high in sharpness, great in cutting capacity and high in material removal rate, the processing work cycle can be shortened, the quality of the workpiece surface is good, and no burn or crack occurs.

The invention discloses a high-tin copper-tin alloy electroplating solution for barrel plating. The solution is characterized by comprising pyrophosphate which is used as a complexing agent, monopotassium phosphate which is used as conducting salt, soluble copper salt and soluble tin salt which are used as main salts, phosphoric acid and potassium hydroxide which are used as a pH regulator of the electroplating solution, a stabilizer of the electroplating solution, and an appropriate amount of compound additives, wherein the concentration of pyrophosphate is 100-350g/L, the concentration of monopotassium phosphate is 40-120g/L, the concentration of the copper salt is 3-20g/L, the concentration of the tin salt is 3-20g/L, the concentration of the stabilizer is 1-12g/L, and the concentration of the compound additives is 1-20ml/L. The electroplating solution disclosed by the invention is simple in component, easy to maintain and applicable to a wide current density range; a plating is bright; a bright high-tin copper-tin alloy plating with a good matrix bonding force can be obtained in a manner of barrel plating.

The invention discloses an ultrathin permanent magnet with a coating deposited on the surface. The permanent magnet is a thin sheet with the thickness of less than or equal to 1mm, and the permanent magnet comprises the following components in percentage by mass: 26.0-35.0% of Pr-Nd, 0-8.0% of Dy, 0-8.0% of Tb, 0-5.0% of Nd, 0.5-2.5% of B, 0-2.8% of Al, 0-1.0% of Cu and the balance of Fe. A Cu-Ni combined coating is deposited on the surface of the permanent magnet thin sheet, the Cu-Ni combined coating comprises a copper-tin alloy sputtering layer deposited on the surface of the permanent magnet thin sheet through sputtering and a nickel-based protective layer deposited on the surface of the copper-tin alloy sputtering layer through electroplating or chemical plating, the tin content in the copper-tin alloy sputtering layer is gradually decreased to zero from the bottom layer to the surface, the surface layer is a pure copper layer, and the copper-tin alloy sputtering layer is a gradient coating. According to the ultrathin permanent magnet, advantages that a magnetron sputtering process does not need acid pickling pretreatment, and a prepared film layer is deposited firmly and is compact and corrosion-resistant are combined, and the problem that in the surface treatment process of the permanent magnet, an acid pickling solution and an electroplating solution erode a matrix structure so that the magnetic performance is reduced is solved.

The invention provides a method for preparing copper-tin alloy powder through diffusion. The method comprises the following steps that 1, weighing and mixing 49%-95% of copper powder, 4%-50% of tin powder and 0.1%-1% of copper-gadolinium alloy powder; 2, carrying out ball milling, wherein the mass ratio of milling balls to the mixed powder is 7: 3-3: 2, the ball milling time is 3-8 h, and the ball milling rotating speed is 50-80 r/min; 3, carrying out diffusion, wherein the protective atmosphere is hydrogen and nitrogen mixed gas, and the diffusion temperature of a reduction furnace is 200-500 DEG C; 4, crushing; and 5, after screening and anti-oxidation treatment, obtaining diffused copper-tin alloy powder. The obtained copper-tin alloy powder is uniform and stable in particle size, wide in sintering process window, fine and smooth in structure and good in cold press formability, the use proportion of the copper-tin alloy powder in diamond tools is increased, the problem of composition segregation of the copper-tin alloy powder is solved, the problem can be effectively solved, and the copper-tin alloy powder is widely applied to the diamond tools.

The invention discloses a method for simultaneously improving intensity, ductility and abrasion resistance of copper-tin alloys, and belongs to the technical field of material preparation. The methodcomprises the steps of preparing raw materials of 8-15% of Sn,1-8% of Fe, 0.8-1.2% of P, and the balance Cu, placing the raw materials in a medium frequency induction heating furnace, performing heating for melting, then treating molten mass by a quick cooling method, controlling the cooling rate and the supercooling degree of the molten mass, and adjusting and controlling the proportion of nanoscale iron enriched phases and intercrystalline micron order iron enriched phases in a primary phase. The intensity and the ductility of the alloys are reinforced by using the nanoscale iron enriched phase, the abrasion resistance of the alloys is improved by an intercrystalline micron order iron enriched phase, and through controlling the proportion of the nanoscale iron enriched phase to the micron order iron enriched phase, high-strength high-ductility high-wear-resistance copper-tin alloys are obtained. The alloys are simple in components, the preparation technology is short in technologicalprocesses, the method is low in cost, castings are good in properties, and the method is suitable for fields of high speed rails, heavy trucks, aerospace and the like, and has favorable application prospects.

The invention relates to a welding method of a high-bonding-strength copper-steel bimetallic antifriction wear-resistant composite material, and belongs to the technical field of dissimilar connection of bimetallic composite materials. The method comprises the following operation steps that (1) a steel sheet and a copper alloy sheet which are the same in area size are taken and subjected to surface sand blasting and rough polishing treatment correspondingly; (2) copper-tin alloy powder is pressed into a sheet-shaped green body; (3) the sheet-shaped green body is placed on a steel sheet, sintering and cladding are conducted in a mesh belt furnace, and a steel sheet cladding piece with a cladding layer is obtained; (4) the cladding layer surface of the steel sheet cladding piece and the copper alloy sheet are folded, diffusion welding is conducted in a vacuum sintering furnace, and a welding piece is obtained; and (5) the welding piece is subjected to low-temperature annealing treatment and water quenching, the copper-steel bimetallic composite material is obtained, and the shear strength of a welding interface is 240-280 MPa. According to the method, the bonding strength of the cladding layer and the steel layer is greatly improved, and due to the fact that the cladding layer is very thin, the defects of shrinkage porosity, shrinkage cavity, cracking and the like in common fusion welding are overcome.

The invention relates to a production method of a copper-tin alloy strip. The production method comprises the following steps: S1, smelting raw materials; s2, horizontal continuous casting; s3, surface milling; s4, rough rolling and edge cutting; s5, cleaning for the first time; s6, performing first intermediate annealing; s7, intermediate rolling; s8, intermediate annealing for the second time; s9, finish rolling; s10, cleaning for the second time; the production method provided by the invention is based on the fact that domestic copper strip enterprises widely have horizontal continuous casting units and cold rolling mills, hot processing such as hot rolling and hot extrusion is not involved, the technological process is controllable, the equipment investment cost is low, large-scale production is easy, and the comprehensive performance of the prepared copper-tin alloy strip is excellent.

The invention discloses a multi-set-gear-shaped diamond saw blade self-formed by orderly positioning and weakening of carcasses and a manufacturing process of the saw blade. The saw blade is composedof segments and a base body, and the segments are formed by compounding working layer sheets and middle separation layer sheets, wherein the thicknesses of the working layer sheets and the middle separation layer sheets are 0.2-2.0 mm. Segment working layers are made of metal powder and diamond, separation layers are made of graphite powder, ceramic powder and copper-tin alloy powder, organic solvents are added to the working layers and the separation layers, and the working layers and the separation layers are manufactured into working layer sheet blanks and middle separation layer sheet blanks separately; weakened carcass particles are embedded in predetermined positions with pit structures of the working layer sheet blanks, and then the working layer sheets and the middle separation layer sheets are alternately assembled at intervals and sintered into the segments of the saw blade; and the segments are welded to the base body to manufacture the saw blade with a diameter of 100-2500mm. In the cutting working process, the weakened carcass particles fall off automatically, the middle separation layers are worn in advance, pits and grooves are formed in working lip planes of the segments, so that the working plane of the saw blade is of a multi-set-gear-shaped structure, and the saw blade has the advantages such as high efficiency, long life and low energy consumption.

The invention relates to a high-strength and high-conductivity copper-tin alloy contact wire and a preparation process thereof. The high-strength and high-conductivity copper-tin alloy contact wire comprises the following chemical components: 0.01wt%-0.8wt% of Sn, 0.01wt%-0.3wt% of Ca, 0.005wt%-0.05wt% of Zr and the balance Cu and inevitable impurities, wherein the chemical components of the copper-tin alloy contact wire are sequentially added in batches according to the sequence of Cu, Sn, Ca and Zr. The preparation process comprises the steps of smelting, upward continuous casting, solutiontreatment, aging treatment, continuous extrusion and drawing forming. The copper-tin alloy contact wire prepared by the method has higher strength and conductivity, and the application range of the copper-tin alloy contact wire is widened.

The invention relates to the technical field of powder metallurgy, and provides a powder metallurgy composite material with high compounding ratio. The powder metallurgy composite material comprises,by weight, 80-95 parts of copper-tin alloy powder, 5-10 parts of phosphor copper powder, 5-15 parts of micro wax powder, 1-10 parts of calcium carbonate powder and 5-15 parts of nano graphite carbon tubes. A manufacturing method comprises the steps of blank manufacturing, presintering quenching, oil immersion, deoiling, re-pressing and sintering shaping, and the strength and wear resistance of thematerial can be effectively improved.

The invention relates to a sharp type diamond drill bit for dry-drilling of granite, and relates to the field of processing of hard and brittle stone materials. Ultrafine tungsten-copper alloy powder,copper-tin alloy powder, ultrafine iron powder, carbonyl nickel powder, phosphorus-copper powder, silver powder and diamond are adopted as raw materials of the drill bit. The drill bit is prepared from, by weight, 30-45% of ultrafine tungsten-copper alloy powder, 30-40% of carbonyl copper-tin prealloy powder, 10-20% of ultrafine iron powder, 10-25% of carbonyl nickel powder, 5-10% of phosphorus-copper powder and 1-5% of silver powder, the weight percentage of tin in the copper-tin prealloy powder is 20%, the weight percentage of phosphorus in the phosphorus-copper powder is 20%, the weight percentage of copper in the tungsten-copper prealloy powder is 30%, the concentration of the diamond is 15-50% (in preparation according to 400%), and the granularity is 300-550 [mu]m. Rapid and continuous dry-drilling machining can be performed on hard granite with the thickness larger than 50 mm through the diamond drill bit.