In-situ reinforced wooden product UV-3D printing coating and preparation method thereof
A UV-3D, wood product technology, applied in manufacturing, additive processing, etc., can solve problems such as low strength and weak interface bonding, achieve low preparation cost, improve efficiency and diversity, and promote high value-added utilization. Effect
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[0030] A method for preparing an in-situ enhanced wood product UV-3D printing coating, comprising the following steps:
[0031] Step 1: Mixing the nanocellulose with acrylic resin monomer and catalyst according to a certain ratio to prepare modified nanocellulose through atom transfer radical polymerization;
[0032] Step 2: Mixing the modified nanocellulose prepared in Step 1 with printing raw materials and catalysts according to a certain ratio to prepare printing composite resin;
[0033] Step 3: Print the printed composite resin prepared in Step 2 on the surface of the wood product by UV-3D printer for coating printing, and the modified nanocellulose and the printing raw material undergo in-situ polymerization chemical reaction during the printing process, thereby preparing the wood product UV-3D printing coating;
[0034] Step 4: Post-curing the wood product UV-3D printing coating prepared in step 3 to obtain an in-situ enhanced wood product UV-3D printing coating.
[0...
Embodiment 1
[0043] An embodiment of the in-situ reinforced wood product UV-3D printing coating comprises the following preparation raw materials in percentage by weight: in the modified nanocellulose, 1% of nanocellulose, 98% of acrylic resin monomer %, catalyst 1%, wherein the nanocellulose is extracted from poplar, the acrylic resin monomer is tert-butyl acrylate, and the catalyst is cuprous bromide. The reaction temperature of the atom transfer radical polymerization reaction is 25° C., and the reaction time is 2 hours. In the printing composite resin, 3% of modified nanocellulose, 96% of printing raw material, and 1% of catalyst, wherein the printing raw material is acrylic resin, and the catalyst is triphenylphosphine.
[0044] The preparation method of the in-situ enhanced wood product UV-3D printing coating described in this embodiment comprises the following steps:
[0045] (1) Preparation of modified nanocellulose: prepare modified nanocellulose A by mixing nanocellulose with ac...
Embodiment 2
[0050] An example of the UV-3D printing coating for in-situ reinforcement of wood products includes the following preparation raw materials in weight percent: in the modified nanocellulose, 3% of nanocellulose, 95.5% of acrylic resin monomer %, catalyst 1.5%, wherein the nanocellulose is extracted from poplar, the acrylic resin monomer is tert-butyl acrylate, and the catalyst is cuprous bromide. The reaction temperature of the atom transfer radical polymerization reaction is 40° C., and the reaction time is 1 hour. In the printing composite resin, 3% of modified nanocellulose, 96% of printing raw material, and 1% of catalyst, wherein the printing raw material is acrylic resin, and the catalyst is triphenylphosphine.
[0051] The preparation method of the in-situ enhanced wood product UV-3D printing coating described in this embodiment comprises the following steps:
[0052] (1) Preparation of modified nanocellulose: prepare modified nanocellulose A by mixing nanocellulose wit...
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