Bactericidal emulsion pressure-sensitive adhesive, dust-sticking pad and preparation method of dust-sticking pad

A sterilizing milk and hydraulic technology, applied in adhesives, pressure-sensitive films/sheets, cleaning equipment, etc., can solve the problem of no bactericidal and antibacterial effects, achieve stable bactericidal and antibacterial effects, improve bactericidal effects, and good reaction stability

Active Publication Date: 2020-11-10
临沂天勤塑业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the relatively mature antibacterial and antibacterial sticky mats on the market use conventional anionic or anionic nonion

Method used

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  • Bactericidal emulsion pressure-sensitive adhesive, dust-sticking pad and preparation method of dust-sticking pad
  • Bactericidal emulsion pressure-sensitive adhesive, dust-sticking pad and preparation method of dust-sticking pad

Examples

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preparation example Construction

[0079] In one embodiment, the preparation method of the sterilizing emulsion pressure-sensitive adhesive comprises the steps:

[0080] (1) uniformly mixing acrylate monomer, N methylol acrylamide, molecular weight regulator, surfactant and deionized water to obtain emulsion;

[0081] (2) heating the reactor to 80°C, taking 6wt% of the emulsion described in step (1) and adding it to the reactor, then adding an initiator, polymerizing for half an hour as a seed, then adding the remaining step (1) described The emulsification is added dropwise to the reaction kettle for 4 hours, the temperature is kept for 1 hour, and the temperature is lowered to 45 ° C. The treatment agent is added, stirred, and then glacial acetic acid is added to adjust the pH to 5-6. The bactericidal emulsion pressure-sensitive adhesive.

[0082] A second aspect of the present invention provides a sticky dust pad containing the above-mentioned sterilizing emulsion pressure-sensitive adhesive.

[0083] A th...

Embodiment 1

[0104] Embodiment 1 provides a kind of sterilizing emulsion pressure-sensitive adhesive, in parts by weight, the components of the sterilizing emulsion pressure-sensitive adhesive are: 900 parts of acrylate monomers, 0.5 parts of molecular weight regulator, 20 parts of surfactant, 0.02 parts of initiator, 2 parts of N-methylol acrylamide, 6 parts of treatment agent, 1200 parts of deionized water;

[0105] The acrylate monomer is a mixture of hydroxyethyl acrylate, dimethylaminoethyl methacrylate, glycidyl methacrylate, methyl methacrylate, isooctyl acrylate, and butyl acrylate; The mass ratio of ethyl ester, dimethylaminoethyl methacrylate, glycidyl methacrylate, methyl methacrylate, isooctyl acrylate and butyl acrylate is 1.5:2:1:5:65:15;

[0106] Described molecular weight regulator is n-dodecyl mercaptan;

[0107] The surfactant is a mixture of quaternary ammonium salt surfactant 1227 and AEO-9; the mass ratio of the quaternary ammonium salt surfactant 1227 and AEO-9 is 2....

Embodiment 2

[0121] Embodiment 2 provides a kind of sterilizing emulsion pressure-sensitive adhesive, in parts by weight, the components of the sterilizing emulsion pressure-sensitive adhesive are: 1000 parts of acrylate monomers, 1 part of molecular weight regulator, 40 parts of surfactant, 0.04 parts of initiator, 4 parts of N-methylol acrylamide, 10 parts of treatment agent, 1400 parts of deionized water;

[0122] The acrylate monomers are the same as those in Example 1, except that the hydroxyethyl acrylate, dimethylaminoethyl methacrylate, glycidyl methacrylate, methyl methacrylate, and isooctyl acrylate are different. , The mass ratio of butyl acrylate is 2.5:3:1:8:75:25;

[0123] Described molecular weight regulator is n-dodecyl mercaptan;

[0124]The surfactant is the same as in Example 1, except that the mass ratio of the quaternary ammonium salt surfactant 1227 and AEO-9 is 2.5:1;

[0125] The initiator is dimethyl azobisisobutyrate;

[0126] The treatment agent is the same as...

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Abstract

The invention relates to the technical field of dust-sticking pads, in particular to a bactericidal emulsion pressure-sensitive adhesive, a dust-sticking pad and a preparation method of the dust-sticking pad. The bactericidal emulsion pressure-sensitive adhesive at least comprises the following components in parts by weight: 900 to 1100 parts of acrylate monomers, 0.2 to 2 parts of molecular weight regulators, 10 to 80 parts of surfactants, 0.01 to 0.05 parts of an initiator and 1200 to 1400 parts of deionized water, wherein each surface active agent comprises a quaternary ammonium salt surface active agent. The dust-sticking pad provided by the invention is good in sterilization and antibacterial effect and excellent in dust-sticking effect, a quaternary ammonium salt surfactant is addedas an emulsifier, so that sterilization effect is improved, reaction stability is better, comprehensive performance of a formed pressure-sensitive adhesive is very good, the interface adhesive force and peel strength of the pressure-sensitive adhesive are increased, and the adhesive force and peel strength of the pressure-sensitive adhesive are improved so that unwinding force of the dust-stickingpad is 0.8 to 1.3 N, and the 180 degree stripping force of the dust-sticking pad is 1.5 to 5.5 N.

Description

technical field [0001] The invention relates to the technical field of sticky dust pads, and more particularly, to a sterilizing emulsion pressure-sensitive adhesive, a dust sticky pad and a preparation method thereof. Background technique [0002] The sticky mat, also known as the sticky floor glue, is mainly suitable for sticking at the entrance of the clean space and between the buffer zones. It can effectively remove the dust on the soles and wheels, and minimize the impact of dust on the quality of the clean environment. In this way, the effect of simple dust removal is achieved, and the problem that the dust removal of other floor mats is not completely can not ensure that the dust does not spread is solved. [0003] At present, the relatively mature antibacterial and antibacterial dust sticky pads on the market use conventional anionic or anionic nonionic acrylate emulsions as dust sticky pressure-sensitive adhesives, and such acrylate emulsions do not have any bacter...

Claims

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Application Information

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IPC IPC(8): C09J7/38C09J7/24C09J133/08C08J5/18C08L23/06C08L23/08A47L25/00C08F2/28C08F220/18C08F220/14C08F220/32C08F220/34C08F220/20
CPCC09J7/385C09J7/243C09J133/14C08J5/18A47L25/005C08F2/28C08F220/1808C09J2433/00C09J2423/046C08J2323/06C08J2423/06C08J2423/08C08F220/1804C08F220/14C08F220/325C08F220/34C08F220/20
Inventor 陈伟刘华山李海伟
Owner 临沂天勤塑业有限公司
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