Visual radioactive carbon microsphere as well as preparation method and application thereof
A technology of radiocarbon and carbon microspheres, applied in the field of medicine, can solve the problems of inconsistent distribution and metabolic behavior of contrast agents and radioactive microspheres, inconvenient clinical use, and inability to accurately monitor the location of radioactive microspheres for a long time, and achieve visualization. Therapeutic, high-efficiency loading effect
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Embodiment 1
[0063] A visible suspension of radioactive carbon microspheres, each 1ml of the solution contains: carbon microspheres 10-500mg, therapeutic radionuclide activity 5-500mCi, radioactive zirconium[ 89 Zr] activity 0.1-100mCi, small organic molecules 0-100mg, first solution 0.1-1.0ml.
[0064] Specifically, the carbon microspheres are spherical or non-spherical carbon materials rich in micropores and mesopores prepared by any method, with a diameter of 0.05-1000 μm, preferably 20-60 μm. The visualized carbon microsphere products prepared by carbon microspheres with different particle sizes can be used for visual treatment of different solid tumor lesions due to different administration methods and different distributions in tissues, organs and lesions.
[0065] Specifically, the small organic molecule is 5-sulfosalicylic acid, 5-nitrosalicylic acid or a small molecule with a similar structure obtained through simple chemical modification.
[0066] Specifically, the first solutio...
Embodiment 2
[0069] A preparation method of visualized radiocarbon microsphere suspension, the method comprises the following steps:
[0070] Mix the radionuclide solution for treatment with the small molecule aqueous solution and let it stand for 2min-20min;
[0071] Adsorb the therapeutic radionuclide in the above mixed solution with carbon microspheres and let stand for 2min-20min;
[0072] Mix and react the carbon microspheres after absorbing therapeutic radionuclides with sodium phosphate solution, let stand for 2min-20min, wash and separate the solid and liquid to obtain the first intermediate;
[0073] Mix the first intermediate with the organic small molecule aqueous solution with a pH value of 1-14, preferably 3.5-6.5, and then let it stand for 2min-20min to obtain the first intermediate solution;
[0074] Adding the radioactive zirconium with a pH value of 1-14, preferably 3.5-7.5, in the first intermediate solution [ 89 Zr] ion solution, after mixing evenly, let it stand for 2...
Embodiment 3
[0077] A preparation method of visualized radiocarbon microsphere suspension, the method comprises the following steps:
[0078] Use carbon microspheres to adsorb organic small molecules in an organic small molecule aqueous solution with a pH value of 1-14, preferably 3.5-6.5;
[0079] Adsorption of radioactive zirconium by the above-mentioned carbon microspheres after adsorption of small organic molecules[ 89 Zr], obtain the third intermediate;
[0080] Using the third intermediate to adsorb the therapeutic radionuclide in the mixed solution of the therapeutic radionuclide and the organic small molecule aqueous solution;
[0081] Mixing and reacting the third intermediate after absorbing therapeutic radionuclides with sodium phosphate solution, washing and separating solid and liquid to obtain the fourth intermediate; and
[0082] Add the first solution to the fourth intermediate, mix evenly, and carry out moist heat sterilization after sub-packaging. The sterilization cond...
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