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Antibacterial molecular sieve coating aluminum foil and preparation method thereof

A molecular sieve and aluminum foil technology, which is applied in coatings, antifouling/underwater coatings, devices for coating liquids on surfaces, etc., can solve the problems that antibacterial properties cannot be effectively maintained for a long time, and the bonding force between coatings and aluminum foils is not strong. , to achieve good self-healing ability, avoid adhesion, and widen the distance between layers

Inactive Publication Date: 2020-11-13
ZHENJIANG WANYUAN ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The object of the present invention is to provide an antibacterial molecular sieve coated aluminum foil and a preparation method thereof, to solve the weak bonding force between the coating and the aluminum foil in the prior art, and in the actual use process, the antibacterial performance of the product cannot be obtained for a long time Disadvantages of effective retention

Method used

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  • Antibacterial molecular sieve coating aluminum foil and preparation method thereof
  • Antibacterial molecular sieve coating aluminum foil and preparation method thereof

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preparation example Construction

[0025] A preparation method of an antibacterial molecular sieve coated aluminum foil, the specific preparation steps comprising:

[0026] Modification of graphene oxide:

[0027] In parts by weight, successively take 10-20 parts of graphene oxide, 200-500 parts of water, and 8-10 parts of octadecylamine, first disperse graphene oxide in water, then add octadecylamine, and heat After stirring and reacting, filter, wash and dry to obtain modified graphene oxide;

[0028] Preparation of aluminum foil products:

[0029] In parts by weight, sequentially take 10-20 parts of modified graphene oxide, 4-8 parts of water-based binder, and 100-200 parts of water, stir and mix, apply on the surface of aluminum foil, and then dry to obtain antibacterial Molecular sieve coated aluminum foil.

[0030] Further, the specific preparation steps also include:

[0031] Modification of graphene oxide:

[0032] In parts by weight, successively take 10-20 parts of graphene oxide, 200-500 parts o...

Embodiment 1

[0039] Pretreatment of aluminum foil:

[0040] Mix and dissolve the silane coupling agent and absolute ethanol at a mass ratio of 1:5 to obtain the ethanol solution of the silane coupling agent; firstly dip the aluminum foil in the ethanol solution of the silane coupling agent, at a temperature of 45°C, After soaking for 4 hours, take it out, soak the aluminum foil in absolute ethanol, then add aluminum isopropoxide with 1% mass of absolute ethanol, and fatty acid with 10% mass of absolute ethanol, and heat for 3 hours at a temperature of 75°C , take out the aluminum foil, dry it, and get the pretreated aluminum foil;

[0041] Modification of graphene oxide:

[0042] In parts by weight, successively take 10 parts of graphene oxide, 200 parts of water, 8 parts of octadecylamine, 8 parts of tetrabutyl titanate, 100 parts of absolute ethanol, and 8 parts of fatty acid, and first disperse the graphene oxide Add octadecylamine to water, heat and stir for 24 hours at a temperature...

Embodiment 2

[0047] Pretreatment of aluminum foil:

[0048] Mix and dissolve the silane coupling agent and absolute ethanol at a mass ratio of 1:10 to obtain the ethanol solution of the silane coupling agent; firstly, soak the aluminum foil in the ethanol solution of the silane coupling agent, at a temperature of 55°C, After soaking for 6 hours, take it out, soak the aluminum foil in absolute ethanol, then add aluminum isopropoxide with 10% of the mass of absolute ethanol, and fatty acid with 15% of the mass of absolute ethanol, and heat the reaction for 5 hours at a temperature of 85°C , take out the aluminum foil, dry it, and get the pretreated aluminum foil;

[0049] Modification of graphene oxide:

[0050]In parts by weight, successively take 20 parts of graphene oxide, 500 parts of water, 10 parts of octadecylamine, 10 parts of tetrabutyl titanate, 120 parts of absolute ethanol, and 10 parts of fatty acid, and first disperse the graphene oxide Add octadecylamine to water, heat and s...

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Abstract

The invention discloses an antibacterial molecular sieve coating aluminum foil and a preparation method thereof. The antibacterial molecular sieve coating aluminum foil comprises an antibacterial molecular sieve coating and an aluminum foil body; at least one side of the aluminum foil is provided with the antibacterial molecular sieve coating; the antibacterial molecular sieve coating comprises modified graphene oxide; epoxy groups between the modified graphene oxide layers are at least partially modified by octadecylamine; antibacterial nanoparticles are embedded between the modified grapheneoxide layers; the D50 of the antibacterial nano particles is 100 to 200 nm; a middle layer is also arranged between the antibacterial molecular sieve and the modified graphene oxide; the middle layercomprises a silane coupling agent and Nano gamma-AlOOH; and the silane coupling agent is arranged on the surface of the aluminum foil so as to connect the nano gamma-AlOOH with the aluminum foil. Theobtained product has excellent antibacterial performance, and even if the molecular sieve layer on the surface layer falls off, the excellent antibacterial performance can still be kept.

Description

technical field [0001] The invention relates to the technical field of aluminum foil materials, in particular to an antibacterial molecular sieve coated aluminum foil and a preparation method thereof. Background technique [0002] Aluminum foil paper refers to the paper made of aluminum foil backing paper and aluminum foil paper. It is soft and easy to deform, like paper, and does not rebound after deformation, guarantees shading, no falling, no light transmission, no pollution, and cheap price. As a raw and auxiliary material for industrial manufacturing, aluminum foil paper is mainly used in packaging protection, daily necessities, construction, etc. Aluminum foil paper is widely used, including aviation food packaging, ordinary meat packaging, cigarette packaging, etc.; although the development of aluminum foil packaging is relatively late , but the market is growing rapidly, and the prospects are attracting attention. Aluminum foil paper will replace more single materia...

Claims

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Application Information

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IPC IPC(8): C09D5/14C09D201/00B05D7/14B05D7/24B05D3/10
CPCB05D3/102B05D7/14B05D7/24B05D2202/25B05D2252/00C08K2003/2241C08K2201/011C09D5/14C09D201/00C08K9/04C08K3/042C08K3/22
Inventor 张君钱本强
Owner ZHENJIANG WANYUAN ELECTRONICS