Method for producing low-sulfur and low-phosphorus steel by utilizing semi-molten steel

A technology for molten steel and steel products, which is applied in the field of producing low-sulfur and low-phosphorus steel products, and can solve the problems of increased consumption of S-corroded line pipes, etc.

Inactive Publication Date: 2020-11-13
CHENGDE JIANLONG SPECIAL STEEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, according to statistics, about 1 / 3 of the world's proven oil and gas fields contain H 2 S gas, containing H 2 The exploitation of S oil and gas fields is increasing day by day, thus making the anti-H 2 Substantial increase in consumption of S corrosion line pipe

Method used

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  • Method for producing low-sulfur and low-phosphorus steel by utilizing semi-molten steel
  • Method for producing low-sulfur and low-phosphorus steel by utilizing semi-molten steel

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Experimental program
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Embodiment 1

[0061] This embodiment provides a method for producing low-sulfur and low-phosphorus steel using semi-liquid steel. The method includes: semi-liquid steel is sequentially subjected to pre-deoxidation, KR desulfurization, converter steelmaking, LF refining and VD vacuum smelting to obtain low-sulfur and low-phosphorus molten steel. The low-sulfur and low-phosphorus molten steel is poured to obtain the low-sulfur and low-phosphorus steel;

[0062] Wherein, the sulfur content in molten steel after KR desulfurization is 0.005%; the slag removal rate after KR desulfurization treatment is 90%; the phosphorus content in molten steel after converter steelmaking is 0.004%; Add 20kg of slag balls per ton of molten steel in the steel; the included angle of the oxygen lance hole in the converter steelmaking is 13°; the end temperature of the converter steelmaking is 1620°C; Deoxidation; Calcium oxide and calcium fluoride are added in the KR desulfurization; the addition amount of the calc...

Embodiment 2

[0065] This embodiment provides a method for producing low-sulfur and low-phosphorus steel using semi-liquid steel. The method includes: semi-liquid steel is sequentially subjected to pre-deoxidation, KR desulfurization, converter steelmaking, LF refining and VD vacuum smelting to obtain low-sulfur and low-phosphorus molten steel. The low-sulfur and low-phosphorus molten steel is poured to obtain the low-sulfur and low-phosphorus steel;

[0066] Wherein, the sulfur content in molten steel after KR desulfurization is 0.002%; the slag removal rate after KR desulfurization treatment is 95%; the phosphorus content in molten steel after converter steelmaking is 0.002%; Add 10kg of slag balls per ton of molten steel in the steel; the included angle of the oxygen lance hole in the converter steelmaking is 15°; the end temperature of the converter steelmaking is 1520°C; Deoxidation; calcium oxide and calcium fluoride are added in the KR desulfurization; the addition of the calcium oxi...

Embodiment 3

[0069] This embodiment provides a method for producing low-sulfur and low-phosphorus steel using semi-liquid steel. The method includes: semi-liquid steel is sequentially subjected to pre-deoxidation, KR desulfurization, converter steelmaking, LF refining and VD vacuum smelting to obtain low-sulfur and low-phosphorus molten steel. The low-sulfur and low-phosphorus molten steel is poured to obtain the low-sulfur and low-phosphorus steel;

[0070] Wherein, the sulfur content in the molten steel after the KR desulfurization is 0.0037%; the slag removal rate after the KR desulfurization treatment is 98%; the phosphorus content in the molten steel after the converter steelmaking is 0.001%; ​​the converter smelting Add 30kg of slag balls per ton of molten steel in the steel; the included angle of the oxygen lance hole in the converter steelmaking is 20°; the end point temperature of the converter steelmaking is ≤1570°C; Deoxidation; Calcium oxide and calcium fluoride are added in th...

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Abstract

The invention relates to a method for producing low-sulfur and low-phosphorus steel by utilizing semi-molten steel. The method comprises the following steps: acquiring low-sulfur and low-phosphorus molten steel by the semi-molten steel through pre-deoxidation, KR desulfurization, converter steelmaking, LF refining and VD vacuum smelting in sequence, and acquiring the low-sulfur and low-phosphorussteel by pouring the low-sulfur and low-phosphorus molten steel, wherein the sulfur content of the molten steel subjected to KR desulfurization is lower than or equal to 0.005%, the rate of slagging-off after KR desulfurization is higher than or equal to 90%, the phosphorus content of the molten steel subjected to converter steelmaking is lower than or equal to 0.004%, 10-30 kg of slagging balls are added into the molten steel per ton during converter steelmaking, the included angle of oxygen gun holes during converter steelmaking is larger than or equal to 13 degrees, and the final temperature of converter steelmaking is lower than or equal to 1620 DEG C. According to the method provided by the invention, the off-site sulfur content is lower than or equal to 0.005% and the rate of dephosphorization during the converter steelmaking of the semi-molten steel reaches 96% or higher. Meanwhile, hydrogen-sulfide-corrosion-resistant continuous-casting round billet non-metallic inclusions produced through the method reach the following levels: class A is lower than or equal to level 0.5; class C is equal to level 0; class B and class C are lower than or equal to level 1.0; and the total thickness of class A, class B, class C and class D is lower than or equal to level 3.0.

Description

technical field [0001] The invention relates to the field of steelmaking, in particular to a method for producing low-sulfur and low-phosphorus steel by utilizing semi-steel. Background technique [0002] At present, according to statistics, about 1 / 3 of the world's proven oil and gas fields contain H 2 S gas, containing H 2 The exploitation of S oil and gas fields is increasing day by day, thus making the anti-H 2 The consumption of S corroded line pipe has increased significantly. Anti-H 2 S corrosion line pipe is mainly used to transport 2 S oil and gas, its service environment is extremely harsh, and its corrosion resistance has extremely high requirements. If the line pipe is severely perforated or cracked during the transportation of oil and gas, it will lead to major safety accidents such as fuel leakage and explosion and social and economic losses. Therefore, the line pipe is required to have high strength, toughness, good welding performance and better Corrosi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/06C21C7/064C21C7/072C21C7/10C21C5/28
CPCC21C5/28C21C7/06C21C7/064C21C7/072C21C7/10
Inventor 王雪原李澍曹娜姚忠尹修刚董诗朋周胜刚冯晓明张国东李刚李军龙
Owner CHENGDE JIANLONG SPECIAL STEEL
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