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59results about How to "Increase the allocation ratio" patented technology

Method for quickly screening and detecting azo dyes forbidden in textile materials, leathers and dyes using gas chromatography mass spectrometry

ActiveCN102798677AReduce processing timeHigh consumption of reagents and materialsComponent separationChemistryMass spectrum analysis
The invention discloses a method for quickly screening and detecting azo dyes forbidden in textile materials, leathers and dyes using gas chromatography mass spectrometry, which comprises the following steps: 1) preparing a sample, 2) subjecting the sample to reduction reaction, 3) extracting the sample, 4) performing the gas chromatography mass spectrometry on the sample, 5) screening decision: compared with the GC-MS analysis result of a standard solution, if the retention time and the mass spectrum of the aromatic amine in the sample keep with standards, the sample is judged as a suspicious positive sample, otherwise it is a negative sample and directly judged as a qualified sample. The sample pre-treatment time is shortened, the cost is reduced, the detection time is shortened, the operation step is simple, the operation is convenient, the operation time is short, the operation cost is low, the detection efficiency is improved; the aromatic amine in the sample is detected by a gas chromatography mass spectrometer, color interference problem is not existed, the sample matrix is effectively prevented from being infected, and the judgment accuracy is high, thus the method is not only suitable for textile materials, but also suitable for other products such as leathers and dyes.
Owner:南京海关工业产品检测中心

Method for recovering rhenium from molybdenum smelting waste acid

The invention discloses a method for recovering rhenium from molybdenum smelting waste acid and belongs to the technical field of metal rhenium recovery and recycle. The method comprises 1, filtering molybdenum smelting waste acid, and treating the filtrate by a composite aminoethylene weak basic anion exchange resin column for adsorption until adsorption is saturated, and 2, carrying out desorption on the saturated anion exchange resin column, collecting the desorption liquid and carrying out evaporation crystallization to obtain ammonium perrhenate. The composite aminoethylene weak basic anion exchange resin has large saturation adsorption quantity. The desorption liquid has rhenium content 100 times or more that of waste acid. Compared with the existing extraction method and ion exchange method, the method provided by the invention has a high rhenium recovery rate of 98% or more. Through use of solubility difference of ammonium perrhenate, ammonium molybdate and ammonium sulfate, ammonium perrhenate is purified by evaporation crystallization and ammonium perrhenate purity is 99.9% or more. The method has a simple rhenium recovery process, is environmentally friendly, is convenient for operation and is suitable for large scale production.
Owner:ZHENGZHOU MINERALS COMPOSITIVE UTILIZATION RES INST CHINESE GEOLOGICAL ACAD +1

Low-titanium-content double-layer covering agent for silicon steel and use method of low-titanium-content double-layer covering agent

ActiveCN106890961AReduce Ti sourceLower thermodynamic conditionsMolten siliconTitanium
The invention provides a low-titanium-content double-layer covering agent for silicon steel and a use method of the low-titanium-content double-layer covering agent. The low-titanium-content double-layer covering agent comprises an upper layer covering agent part and a lower layer covering agent part; the lower layer covering agent part is contacted with molten steel; the upper layer covering agent part is located above the lower layer covering agent part; the upper layer covering agent part comprises the following raw materials, by weight percentage, 44-62% of SiO2, 2-10% of MgO, 1-10% of CaO, greater than 0 and less than or equal to 7% of Fe2O3, 20-38% of Al2O3, greater than 0 and less than or equal to 1% of C (all), greater than 0 and less than or equal to 0.5% of TiO2, and the balance ignition lost; and the lower layer covering agent part comprises the following raw materials, by weight percentage, 15-25% of SiO2, 3-8% of MgO, 48-68% of CaO, 2-10% of Fe2O3, greater than 0 and less than or equal to 1% of Al2O3, greater than 0 and less than or equal to 1% of C (all), greater than 0 and less than or equal to 0.2% of TiO2, and the balance ignition loss. With the use of the low-titanium-content double-layer covering agent, the content of titanium in molten silicon steel can be reduced effectively.
Owner:BEIJING SHOUGANG CO LTD

Converter later-stage low-temperature tapping efficient dephosphorization method

The invention discloses a converter later-stage low-temperature tapping efficient dephosphorization method. The method comprises the following steps that Si, Mn and part of iron in slag are oxidized by adopting high lance position and large oxygen flow in the early stage of blowing; with the continuation of oxygen blowing, CO gas generated by chemical reaction of carbon and oxygen enables the early-stage slag to be prone to emerge, the lance position is raised, and the oxygen flow is reduced; the lance position is lowered in the middle stage of blowing; in the middle and later stages of smelting, the lance position is increased for slag adjustment, a part of sinter is added in multiple batches, the dephosphorization effect of the slag is good, and meanwhile good thermodynamic and dynamic conditions are achieved; and then a sublance is put down for TSC, and in the later stage of smelting, the final TSO temperature is controlled to be 1590-1620 DEG C . According to the method, an in-furnace efficient dephosphorization production process under a converter end-point low-temperature tapping condition is provided, and by reducing tapping end-point temperature, the distribution ratio of phosphorus in slag and steel in the later stage of smelting of a converter is increased, and therefore the dephosphorization efficiency in the later stage of smelting is improved.
Owner:LIUZHOU IRON & STEEL

Method for producing low-sulfur and low-phosphorus steel by utilizing semi-molten steel

The invention relates to a method for producing low-sulfur and low-phosphorus steel by utilizing semi-molten steel. The method comprises the following steps: acquiring low-sulfur and low-phosphorus molten steel by the semi-molten steel through pre-deoxidation, KR desulfurization, converter steelmaking, LF refining and VD vacuum smelting in sequence, and acquiring the low-sulfur and low-phosphorussteel by pouring the low-sulfur and low-phosphorus molten steel, wherein the sulfur content of the molten steel subjected to KR desulfurization is lower than or equal to 0.005%, the rate of slagging-off after KR desulfurization is higher than or equal to 90%, the phosphorus content of the molten steel subjected to converter steelmaking is lower than or equal to 0.004%, 10-30 kg of slagging balls are added into the molten steel per ton during converter steelmaking, the included angle of oxygen gun holes during converter steelmaking is larger than or equal to 13 degrees, and the final temperature of converter steelmaking is lower than or equal to 1620 DEG C. According to the method provided by the invention, the off-site sulfur content is lower than or equal to 0.005% and the rate of dephosphorization during the converter steelmaking of the semi-molten steel reaches 96% or higher. Meanwhile, hydrogen-sulfide-corrosion-resistant continuous-casting round billet non-metallic inclusions produced through the method reach the following levels: class A is lower than or equal to level 0.5; class C is equal to level 0; class B and class C are lower than or equal to level 1.0; and the total thickness of class A, class B, class C and class D is lower than or equal to level 3.0.
Owner:CHENGDE JIANLONG SPECIAL STEEL

Environment-friendly high-purity cerium dioxide extraction method

The invention belongs to the technical field of separation and purification of rare earth, and particularly relates to an environment-friendly high-purity cerium dioxide extraction method. The methodcomprises the following steps: (1) extracting: mixing a cerium chloride material liquid and an extracting agent at the volume ratio of 1:(1.2-1.5), extracting, separating, adding hydrotalcite whose weight is 4-6% of the weight of the extracting agent at the same time, conducting ultrasonic dispersion for 20-30 minutes, leaving to stand, then separating, recycling a solid phase, inputting an organic phase into a reextraction procedure; (2) reextracting: taking an oxalic acid solution, wherein the volume of the oxalic acid solution is 1.5-2.0 times the volume of the organic phase, reextracting at the temperature of 50-60 DEG C, conducting ultrasonic dispersion for 20-30 minutes, filtering to obtain a precipitate; (3) oxidizing: firing and oxidizing the obtained precipitate at the temperatureof 1000-1100 DEG C for 12-15 hours, and obtaining the high-purity cerium dioxide. The method abandons the traditional alkaline saponification causing serious ammonia nitrogen pollution, and the artificial hydrotalcite is used to implement ion exchange in the extraction process, so that the balanced acidity of the system is maintained, and the environmental pollution is reduced.
Owner:DEQING XINGBANG RARE EARTH NEW MATERIALS

Temperature gradient liquid-liquid-liquid microextraction method

The invention relates to a temperature gradient liquid-liquid-liquid microextraction method. The temperature gradient refers to that a temperature difference exists between a receiving phase and a supplying phase (sample) of the liquid-liquid-liquid microextraction, wherein the receiving phase is a hot end and the supplying phase is a cold end. The site of the liquid-liquid-liquid microextraction is a coaxial tube-shell-type channel. Liquid layer segregation is supplied by a hollow fiber pipe, wherein the lateral wall of the fiber pipe is provided with micropores or is free from pores. Liquid which is neither immiscible with the liquid of the supplying phase nor the receiving phase is arranged on the surface of the hollow fiber pipe in a loaded mode. An outer shell body is sleeved outside the hollow fiber pipe, wherein the inner diameter of the outer shell body is larger than the outer diameter of the hollow fiber pipe. The supplying phase passes through the interior of the hollow fiber pipe, and the receiving phase is filled in a cavity between the hollow fiber pipe and the outer shell body. The outer shell body is heated so that the receiving phase is heated, thus the temperature gradient between the receiving phase and the supplying phase is achieved and used as mass transfer power, and an extraction recovery rate is improved.
Owner:重庆南派克仪表科技有限公司

Rice seedling culture solution added with exogenous salicylic acid and application of rice seedling culture solution

The invention discloses a rice seedling culture solution added with exogenous salicylic acid and application of the rice seedling culture solution. According to the rice seedling culture solution added with the exogenous salicylic acid, the exogenous salicylic acid is added on the basis of a rice nutrient solution formula, and the addition amount is 100 [mu]mol/L<-1>. The cadmium content of root systems and overground parts of rice seedlings is reduced; the rice seedling culture solution is used for regulating pectin synthesis, deesterification and lignin synthesis to reduce cadmium accumulation of rice plants and relieve poison of cadmium stress to rice seedlings; the rice seedlings are cultured in the rice seedling culture solution for 10 days, the pectin content and deesterification degree of roots are increased, free carboxyl in pectin is increased, and the adsorption and combination capacity of cell walls to cadmium is enhanced; meanwhile, root lignin content is increased, the cell walls are thickened, and cadmium ions are prevented from entering cells. The invention discloses and verifies an important rice Cd regulation mechanism, and provides theoretical guidance and a feasible scheme for safe production of cadmium-polluted rice field soil.
Owner:CHINA NAT RICE RES INST

Method for measuring concentration of phenylephrine in plasma by LC-MS/MS, and pretreatment method of sample

The invention relates to the technical field of medical detection, and specifically relates to a method for measuring the concentration of phenylephrine in plasma by LC-MS / MS. The method comprises thefollowing steps: primary extraction: adding an internal standard working solution and an extracting solution into a sample, centrifugally layering the solution after mixing the solutions uniformly, and collecting the supernatant to obtain first supernatant; derivatization reaction: concentrating and drying the first supernatant, adding a NaHCO3 buffer salt for dissolution, and then adding an acetonitrile solution of dansyl chloride to perform a derivatization reaction; and secondary extraction: adding the extracting solution into the reaction solution after the derivatization reaction for secondary extraction, centrifuging to obtain second supernatant, concentrating and drying the second supernatant, and redissolving the product to obtain a sample solution. By adoption of the pretreatment method of the sample provided by the invention, the extraction rate of low-level phenylephrine can be maximally improved, the interference of a plasma matrix is effectively removed, the specificityis improved, the minimum detection limit is reduced to 0.02ng / ml, and the sensitivity is increased to 0.1nM to adapt to the detection requirements of the concentration of the low-concentration phenylephrine in drug clinical studies.
Owner:CHINA RESOURCES SANJIU MEDICAL & PHARMA

Efficient extraction method for high-purity lanthanum oxide

The invention relates to an efficient extraction method for high-purity lanthanum oxide. The efficient extraction method comprises the following steps of (1) extraction: mixing a lanthanum oxide feedliquid with an extraction agent at a volume ratio of 1:(2.5-3.5) for extraction separation, carrying out ultrasonic dispersion for 10-15 min, and carrying out separation after standing, wherein the extraction agent comprises the following raw materials including, by volume, 20%-24% of P507, 10%-15% of 1,2,5-thiadiazole-3,4-dithiol and the balance kerosene; (2) back extraction: carrying out back extraction on an oxalic acid solution with the organic-phase volume being 3.0-4.0 times at 50-60 DEG C, carrying out ultrasonic dispersion for 20-30 min, carrying out precipitation, and carrying out filtration to obtain a precipitate; and (3) oxidation: carrying out burning oxidation on the obtained precipitate at 800-900 DEG C for 12-15 h so as to obtain lanthanum oxide. According to the efficientextraction method provided by the invention, a specific amount of 1,2,5-thiadiazole-3,4-dithiol is added into an extraction system; through cooperation between the 1,2,5-thiadiazole-3,4-dithiol and the P507, the hydrophobicity of a lanthanum extraction complex can be higher; and accordingly, the entry into an organic phase can be easier, and the extraction efficiency and the distribution ratio canbe improved.
Owner:DEQING XINGBANG RARE EARTH NEW MATERIALS

Converter low-alkalinity residue high-efficiency dephosphorization method

The invention discloses a converter low-alkalinity residue high-efficiency dephosphorization method. A residue remaining method is adopted, so that the FeO content in the residue is improved; a low-lance position operation is adopted in an early blowing stage, so that the temperature of a molten bath is improved, melting of lime is accelerated, primary residues are rapidly formed, and phosphorus is rapidly removed by utilizing high FeO content and low furnace temperature in the early stage. When the Si and Mn oxidizing period is basically ended and a C-O2 reaction begins, the oxygen supply strength is reduced, and soft blow is properly caused, so that the number of reflection streams is increased, the impact area is enlarged, the C-O2 reaction speed is reduced, the FeO content in the residue is increased, the generation of C2s on the lime surface is reduced, and a terminal dephosphorization rate is guaranteed under the conditions that the slag alkalinity and lime addition amount are low by adopting low alkalinity R of less than 2.0. According to a method for adjusting the lance position and controlling the oxygen supply strength, the smelting temperature is controlled, a phosphorus distribution ratio is increased, and the dephosphorization efficiency is improved; the method has the advantages of simple process, simplicity in operation and good dephosphorization effect and can be widely applied to serving as a dephosphorization method in a steel plant.
Owner:XI LIN IRON & STEEL GRP

Method for quickly screening and detecting azo dyes forbidden in textile materials, leathers and dyes using gas chromatography mass spectrometry

The invention discloses a method for quickly screening and detecting azo dyes forbidden in textile materials, leathers and dyes using gas chromatography mass spectrometry, which comprises the following steps: 1) preparing a sample, 2) subjecting the sample to reduction reaction, 3) extracting the sample, 4) performing the gas chromatography mass spectrometry on the sample, 5) screening decision: compared with the GC-MS analysis result of a standard solution, if the retention time and the mass spectrum of the aromatic amine in the sample keep with standards, the sample is judged as a suspicious positive sample, otherwise it is a negative sample and directly judged as a qualified sample. The sample pre-treatment time is shortened, the cost is reduced, the detection time is shortened, the operation step is simple, the operation is convenient, the operation time is short, the operation cost is low, the detection efficiency is improved; the aromatic amine in the sample is detected by a gas chromatography mass spectrometer, color interference problem is not existed, the sample matrix is effectively prevented from being infected, and the judgment accuracy is high, thus the method is not only suitable for textile materials, but also suitable for other products such as leathers and dyes.
Owner:南京海关工业产品检测中心

Heavy rare earth and light rare earth separation method and extraction agent

InactiveCN103451427BAvoid the limitations of low solubilityLess quantityProcess efficiency improvementRare-earth elementNitrate
The invention discloses a heavy rare earth and light rare earth separation method and a heavy rare earth and light rare earth separation extraction agent. The method includes the step of conducting extraction on a rare earth element and nitrate mixed aqueous solution through imidazolyl ionic liquid where the extraction agent is dissolved or chloroform where the extraction agent is dissolved or a 1-pentanol diluent where the extraction agent is dissolved so that heavy rare earth elements can be extracted and yttrium and light rare earth elements can be kept in the aqueous phase, wherein the extraction agent which is used is 1-methylimidazole shown in the chemical formula 1 or 2-methylimidazole shown in the chemical formula 2 when the diluent is the imidazolyl ionic liquid or the chloroform, and the extraction agent which is used is 2-methylimidazole shown in the chemical formula 2 when the diluent is the 1-pentanol diluent. The heavy rare earth and light rare earth separation method and the heavy rare earth and light rare earth separation extraction agent have the advantages that the extraction agent is low in price and can be easily obtained, the extraction system is simple, the extraction efficiency is high, the amount of the extraction agent which is used is small, and the specificity is strong.
Owner:LANZHOU UNIVERSITY
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