Detection reagent for fluorescently labeling amino compounds and application of detection reagent in protein fluorescence labeling
An amino compound and protein fluorescence technology, which is applied in the field of detection reagents for fluorescently labeled amino compounds, can solve the problems of protein fluorescent labeling time increase, poor stability of labeled products, low fluorescence quantum yield, etc., and achieve high labeling efficiency and fast labeling speed , The effect of simple synthetic route
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Embodiment 1
[0039] A detection reagent for fluorescently labeled amino compounds, the structural formula of which is as follows:
[0040]
[0041] The preparation method of above-mentioned detection reagent is:
[0042] (1) Synthesis of fluorescein methyl ester:
[0043] (1.1) Dissolve fluorescein (3.32g, 10mmol) in 10ml of methanol, drop into 2.5ml of concentrated sulfuric acid, heat to reflux for 14 hours, and use Molecular sieve drying. After the above reaction stopped, add 1g ice, 10g NaHCO3 powder, filter, wash with a small amount of water, the red solid obtained is put into 50ml NaHCO3 aqueous solution with a mass fraction of 2%, filter again, and wash with water again. The water washing process was repeated three times.
[0044] (1.2) After washing with water, add 1% acetic acid solution, filter, and wash with water.
[0045] (1.3) The solid (red solid) obtained by the reaction was washed with water and then dried to obtain 3.4 g (98%) of fluorescein methyl ester as a red s...
Embodiment 2
[0052] A detection reagent for fluorescently labeled amino compounds, the structural formula of which is as follows:
[0053]
[0054]Its preparation method is basically the same as the preparation method of the detection reagent in Example 1, except that step (1) is not carried out, and it is directly synthesized from step (2).
Embodiment 3
[0056] A detection reagent for fluorescently labeled amino compounds, the structural formula of which is as follows:
[0057]
[0058] Its preparation method is the same as that of the detection reagent in Example 1, except that ethanol is selected as the solvent in step (1.1).
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