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A high-voltage electrospinning method for liquid polymer materials

A technology of high-voltage electrospinning and polymer materials, which is applied in the field of textile fibers to achieve the effects of small specific mass, reduced surface tension, and expanded molding process

Active Publication Date: 2021-10-08
HARBIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The invention provides a spinning method using liquid polymer materials combined with high-voltage electrospinning technology. The method uses liquid epoxy resin (epoxy value greater than 12), liquid phenolic resin, liquid silicone resin and liquid silicone rubber. A liquid polymer material is combined with electrospinning technology to prepare a nanofiber membrane. This method overcomes the technical problem that the liquid polymer material cannot be electrospun in the existing process. The technical scheme adopted is as follows:

Method used

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  • A high-voltage electrospinning method for liquid polymer materials
  • A high-voltage electrospinning method for liquid polymer materials
  • A high-voltage electrospinning method for liquid polymer materials

Examples

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Embodiment 1

[0029] This embodiment provides a high-voltage electrospinning method for liquid polymer materials, which is performed according to the following steps:

[0030] Step 1: Add 2g of liquid epoxy resin with epoxy value greater than 12, 2g of polylactic acid (polymer surfactant), 2g of oligomeric silane (curing agent) and 14mL of N,N-dimethylformamide (organic solvent) Put it into a stirring vessel with magnetic stirring, and after fully stirring and dissolving on the magnetic stirrer, the spinning precursor solution is obtained;

[0031] Step 2: place the spinning precursor solution prepared in step 1 in a spinning device for high-voltage electrospinning, and in the process of high-voltage electrostatic spinning, the spinning precursor solution after being ejected by the spinning needle of the spinning device Under the heating action of the energy input device (or called the curing heating device), the evaporation of the organic solvent and the curing of the liquid polymer materi...

Embodiment 2

[0035] In this example, on the basis of Example 1, liquid phenolic resin is used to replace liquid epoxy resin with epoxy value greater than 12.

[0036] In this example, a liquid phenolic resin is used instead of a liquid epoxy resin with an epoxy value greater than 12. According to the method of the present invention, a fiber membrane can also be prepared. The interior can absorb more substances and can be prepared in large quantities.

Embodiment 3

[0038] In this example, on the basis of Example 1 and Example 2, polyamine is used instead of oligomeric silane.

[0039] In this embodiment, polyamines are used instead of oligomeric silanes, which can also better enhance the fiber-forming ability of the liquid polymer material, make it cure faster, and obtain better curing effects.

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Abstract

The invention discloses a high-voltage electrostatic spinning method for liquid polymer materials, which belongs to the technical field of textile fibers. The method is to dissolve materials such as liquid polymer materials, polymer surfactants and curing agents into organic solvents, configure them as spinning precursors, and place the prepared spinning precursors in spinning devices for high-voltage electrospinning , and in the high-voltage electrospinning process, the spinning precursor liquid sprayed out from the spinning needle of the spinning device is heated by the curing heating device to evaporate the organic solvent and solidify the liquid polymer material to obtain a fiber film . The invention successfully prepares the liquid polymer material that cannot be spun into a fiber membrane in the prior art, realizes a technological breakthrough, and overcomes the technical problem that the liquid polymer material cannot be spun. The fiber membrane prepared by the invention has a porous structure, small specific mass and good heat insulation performance, and can be applied to the fields of flexible electronic devices, sensors and the like.

Description

technical field [0001] The invention relates to a high-voltage electrostatic spinning method of liquid polymer materials, belonging to the technical field of textile fibers. Background technique [0002] When the epoxy value of epoxy resin is less than or equal to 12, it is solid, and when the epoxy value is greater than 12, it is liquid. In the existing spinning technology, only solid epoxy resin can be used for spinning, and liquid ring with epoxy value greater than 12. Oxygen resin cannot be spun. In addition, liquid phenolic resin, liquid silicone resin and liquid silicone rubber, the three liquid polymer materials, cannot be spun because they are all in liquid state. So far, no example of spinning liquid substances has been found. SUMMARY OF THE INVENTION [0003] The invention provides a spinning method using liquid polymer material combined with high-voltage electrostatic spinning technology. A kind of liquid polymer material is combined with electrospinning techn...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D5/00D04H1/728
CPCD01D5/003D04H1/728
Inventor 巩桂芬邹明贵罗艳梅
Owner HARBIN UNIV OF SCI & TECH
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