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Schottky diode based on double-step slope and manufacturing method thereof

A Schottky diode, double-step technology, used in semiconductor/solid-state device manufacturing, electrical components, circuits, etc., can solve the problem of insufficient breakdown voltage, and achieve the effect of reducing electric field strength, simple preparation process, and good repeatability

Inactive Publication Date: 2020-12-04
XIDIAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

It includes from bottom to top: ohmic contact metal Au layer 1, ohmic contact metal Ti layer 2, highly doped n-type Ga 2 o 3 Substrate 3 and low-doped n-type Ga 2 o 3 Thin film 4, low-doped n-type Ga 2 o 3 The film is engraved with a stepped slope 6 and implanted with fluorine ions. The stepped slope 6 is provided with a Schottky electrode Ni layer 7 and a Schottky electrode Au layer 8. Although the diode with this structure has a significant increase in the breakdown voltage , however, this structure can only optimize the electric field intensity distribution of the device at the edge of the Schottky contact on two three-dimensional structures, so that the breakdown voltage is still not high enough, thus limiting the Ga 2 o 3 Application of Schottky Diodes in High Voltage and High Power Devices

Method used

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  • Schottky diode based on double-step slope and manufacturing method thereof
  • Schottky diode based on double-step slope and manufacturing method thereof
  • Schottky diode based on double-step slope and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Embodiment 1, making low-doped n-type Ga 2 o 3 A double-step bevel Schottky diode with a depth of 1 μm and a tilt angle of 40°, a mesa width of the first slope of 900 nm, and a depth of 1.5 μm of the second slope.

[0043] Step 1, pair electron concentration is 5×10 18 cm -3 highly doped n-type Ga 2 o 3 Substrates undergo standard cleaning such as Figure 4 (a).

[0044] 1a) Highly doped n-type Ga 2 o 3 The substrate is cleaned in an organic cleaning solution at 80°C for 20 minutes;

[0045] 1b) Cleaning the organically cleaned substrate with flowing deionized water for 40 seconds;

[0046] 1c) Put the cleaned substrate into HF:H 2 Corrosion in O=1:1 solution for 60s;

[0047] 1d) The etched Ga 2 o 3 The substrate was rinsed with flowing deionized water for 60 s, and dried with high-purity nitrogen gas.

[0048] Step 2, epitaxial growth of low-doped n-type Ga 2 o 3 film, such as Figure 4 (b).

[0049] Put the cleaned substrate into the metal-organic c...

Embodiment 2

[0067] Embodiment 2, making low-doped n-type Ga 2 o 3 A double-step slope Schottky diode with a depth of 1 μm and a slope angle of 50°, a mesa width of the first slope of 600 nm, and a depth of 1 μm of the second slope.

[0068] Step 1, pair electron concentration is 1×10 19 cm-3 highly doped n-type Ga 2 o 3 Substrates undergo standard cleaning such as Figure 4 (a).

[0069] The specific implementation of this step is the same as step 1 of Embodiment 1.

[0070] Step 2, epitaxial growth of low-doped n-type Ga 2 o 3 film, such as Figure 4 (b).

[0071] Put the cleaned substrate into the MOCVD reaction chamber, respectively with TMGa and high-purity O 2 For Ga source and O source, set the reaction chamber temperature to 850°C, growth pressure to 220Pa, TMGa flow rate to 10 sccm, O 2 The flow rate is 350 sccm, the epitaxial growth thickness on the substrate is 3.2 μm, and the carrier concentration is 8×10 16 cm -3 Low-doped n-type Ga 2 o 3 film.

[0072] Step th...

Embodiment A

[0089] Embodiment A, making low-doped n-type Ga 2 o 3 A double-step slope Schottky diode with a depth of 1 μm and a slope angle of 60°, a mesa width of the first slope of 480 nm, and a depth of 800 nm of the second slope.

[0090] A1) The pair electron concentration is 5×10 19 cm -3 highly doped n-type Ga 2 o 3 Substrates undergo standard cleaning such as Figure 4 (a).

[0091] The specific implementation of this step is the same as step 1 of Embodiment 1.

[0092] A2) Epitaxial growth of low-doped n-type Ga 2 o 3 film, such as Figure 4 (b).

[0093] Put the cleaned substrate into the MOCVD reaction chamber, respectively with TMGa and high-purity O 2 For the Ga source and the O source, set the reaction chamber temperature to 900°C, the growth pressure to 220Pa, the TMGa flow rate to 10 sccm, and the O 2 The flow rate is 350sccm, the epitaxial growth thickness on the substrate is 3.5μm, and the carrier concentration is 3×10 17 cm -3 Low-doped n-type Ga 2 o 3 f...

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Abstract

The invention discloses a Schottky diode based on a double-step slope, and mainly solves the problem that an existing Schottky diode device is low in breakdown voltage. The Schottky diode comprises anohmic contact metal Au layer, an ohmic contact metal Ti layer, a highly-doped n-type Ga2O3 substrate and a low-doped n-type Ga2O3 film, wherein two stages of step slopes are respectively engraved onthe two sides of the low-doped n-type Ga2O3 film, a ratio of an inclination angle to height of each stage of step slope is 1:1, and a ratio of the width of the second step slope to the width of the first step slope is 5:3, and fluorine ions are injected into the two stages of step slopes; and a Schottky electrode Ni layer and a Schottky electrode Au layer are sequentially arranged on the second-stage step slope from bottom to top. According to the Schottky diode, the intensity of an electric field at the edge of a Schottky electrode can be uniformly distributed on a plurality of three-dimensional structures, electrons of the low-doped Ga2O3 epitaxial layer below the periphery of the anode can be partially exhausted, the breakdown voltage is effectively improved, and the Schottky diode canbe used as a power device and a high-voltage switching device.

Description

technical field [0001] The invention belongs to the technical field of microelectronic devices, in particular to a Schottky diode, which can be used as a power device and a high-voltage switch device. Background technique [0002] With the rapid development of technological innovation, power electronics, military equipment, communications, motor control, aerospace and other important fields have put forward higher requirements for the performance of semiconductor components. In this case, traditional silicon-based and other narrow-bandgap semiconductor diodes are difficult to meet the growing demand due to their complex fabrication process, high fabrication cost, and breakdown voltage, among which the breakdown voltage has become a key factor affecting the further improvement of device performance. one. To solve these problems, we need to focus on the future and study new semiconductor materials and devices. Compared with other semiconductor materials, Ga 2 o 3 Has many ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L29/872H01L21/329H01L29/06H01L29/24
CPCH01L29/0611H01L29/0615H01L29/24H01L29/66143H01L29/872
Inventor 冯倩胡志国于明扬马红叶徐周蕊张进成张春福张雅超田旭升张涛赵春勇
Owner XIDIAN UNIV