Anti-ultraviolet glass with small color difference and preparation method thereof

An anti-ultraviolet and chromatic aberration technology, which is applied in the field of anti-ultraviolet glass and its preparation, can solve the problems of uneven thickness of anti-ultraviolet film, poor color and luster, and reduce ultraviolet light, so as to reduce the transmittance of ultraviolet light, small change in chromatic aberration, and color uniform effect

Active Publication Date: 2020-12-11
深圳南玻科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, there are four problems in the above-mentioned anti-ultraviolet glass: first, the cost is high, and the film or coating on the ordinary glass substrate will increase the cost of materials and equipment; The color is poor. Third, the film or coating will change the color of the glass and affect the appearance of the glass. Fourth, it will reduce the intensity of visible light passing through the glass.
[0006] Ordinary transparent glass is green due to iron ions. To make the glass anti-ultraviolet, the existing method is to form a layer of anti-ultraviolet film on the outer surface of the glass by filming or coating, thereby reducing the intensity of ultraviolet rays passing through the glass. , but these methods will first change the color of the glass, from green to brown, gray or even black. In addition, while reducing ultraviolet light, it will also reduce the intensity of visible light passing through the glass.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-5

[0029] Glass samples were prepared according to the weight ratio in Table 1, and the obtained glass samples were tested for optical properties with an ultraviolet-visible spectrophotometer Lambda 950. The test items included visible light transmittance, ultraviolet light transmittance, lightness L, a *value and b*value.

Embodiment 1

[0033] Embodiment 1 is a standard sample, and the raw materials are selected according to the glass weight percentage in the above table embodiment 1. The main raw materials are quartz sand, dolomite, feldspar, limestone, soda ash, Glauber's salt and carbon powder, and the iron oxide content in the main raw materials should be low At 50ppm, add 1% carboxymethyl cellulose sodium aqueous solution as a binder, press to grow * width * height 40 * 40 * 1mm blocks, after aging for 24 hours, heat treatment at 950 ° C for 0.5 hours, and then put into In the melting furnace, the samples were obtained after high-temperature melting, clarification and homogenization, and forming annealing. The optical properties of the samples were tested. The visible light transmittance was 89.65%, the ultraviolet light transmittance was 66.15%, and the lightness L was 95.02. The a* value was -1.06 and the b* value was 0.23.

Embodiment 2

[0035] According to the percentage by weight of glass in Example 2 in the table, select the same raw material as in Example 1, the iron oxide content requirements in the main raw material are the same, and the additives are iron oxide with a purity of 99.99% and cerium oxide with a purity of 99.99%, adding 4% Using water as a binder, pressing a block with a growth*width*height of 45*45*1mm, aging for 28 hours, and then treating it at 920°C for 1 hour, and then putting it into a melting furnace, and going through the same high temperature as in Example 1 The samples were obtained after melting, clarification and homogenization, and forming annealing processes. The optical properties of the samples were tested. The visible light transmittance was 89.97%, the ultraviolet light transmittance was 49.24%, the lightness L was 95.22, and the a* value was - 1.01, the b* value is 0.47. Compared with Example 1, it can be seen that after adding the additive, the visible light transmittanc...

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Abstract

The invention discloses anti-ultraviolet glass with small color difference and a preparation method thereof, and relates to the technical field of anti-ultraviolet glass. According to the anti-ultraviolet glass with the small color difference, the anti-ultraviolet effect can be achieved only by adding a small amount of Fe2O3 (0.1-0.2%) and CeO2 (0.04-0.1%), the color difference change is small, and the cost is low. According to the glass prepared by the preparation method provided by the invention, added materials can be uniformly dispersed in a glass body in the glass melting process, so thatthe effects of uniform color and small color difference change are achieved. Compared with common glass, the anti-ultraviolet glass with the small color difference has the advantages that the color values (including brightness L, a* and b*) of the glass are slightly changed after the anti-ultraviolet glass with small color difference is added with materials, so that the glass can hardly be distinguished by naked eyes, and the appearance of the glass is not influenced. According to the anti-ultraviolet glass with small color difference provided by the invention, the ultraviolet light transmittance can be effectively reduced from 65-75% to 44-50% under the condition that the visible light transmittance of the glass is not greatly reduced.

Description

technical field [0001] The invention relates to the technical field of anti-ultraviolet glass, in particular to an anti-ultraviolet glass with small color difference and a preparation method thereof. Background technique [0002] Although ultraviolet rays have the functions of promoting vitamin D synthesis, sterilization and health care in animals, they will cause aging of facilities and equipment, damage to skin, decline of immune function and cause skin cancer and cataracts. Therefore, resisting ultraviolet radiation has caused people to widespread attention. [0003] Existing anti-ultraviolet glass adopts a film method or a coating method to form a layer of anti-ultraviolet film on the outer surface of the glass. The film method uses multi-layer films such as protective film, adhesive layer, polyester film and anti-ultraviolet coating to stick on the glass substrate On the surface, the coating method is to sandwich a transparent anti-ultraviolet coating between two glass...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/095C03C4/08
CPCC03C3/095C03C4/085
Inventor 邓臻禄陈志鸿刘建党肖子凡戴斌刘攀
Owner 深圳南玻科技有限公司
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