The invention discloses a multifunctional super-hydrophobic textile finishing agent, and a preparation method and applications thereof. The preparation method comprises following steps: a precursor of an oxide sol and a graphite oxide aqueous dispersion are dispersed in deionized water, an anionic surfactant is added, a catalyst is added for hydrolysis and condensation reaction after uniform dispersion so as to obtain a mixed reaction system, and the mixed reaction system is heated to 30 to 50 DEG C for 3 to 12h of reaction so as to obtain a hydrosol; a functional agent is added into the hydrosol so as to obtain the multifunctional super-hydrophobic textile finishing agent. The multifunctional super-hydrophobic textile finishing agent is safe, is friendly to the environment, is excellent in effect, is used for super hydrophobic and multifunctional finishing of textile, is capable of providing textile with six functions including super-hydrophobic property, flame resistance, antibacterial property, stain resistance, ultraviolet resistance, and skin protection performance, is capable of eliminating adverse effect of the plurality of functions, improving the synergistic effect; the preparation method is simple and convenient, is easy to control, and is suitable for large scale production.