Liquid injection formation method of power lithium ion battery
A lithium-ion battery and power technology, applied in secondary batteries, battery electrodes, electrochemical generators, etc., can solve the problems of poor battery positive and negative contact, battery bulging safety, increased resistance, etc., and achieve a good electrolyte solution. The effect of stability, reduction of gas production, and low internal resistance
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Embodiment 1
[0029] 1) The positive and negative electrodes of the power lithium-ion battery are spaced apart and placed in the first electrolytic solution. In the first electrolytic solution, propylene carbonate is used as the organic solvent, containing 2mol / L lithium hexafluorophosphate, and containing 0.03mol / L of sodium hexafluorophosphate, and containing 1-cyclohexyl-2-pyrrolidone and 1,3-propane sultone as additives, the concentration of 1-cyclohexyl-2-pyrrolidone is 3.5% by volume, 1,3- The concentration of propane sultone is 1.5% by volume;
[0030] 2) Charging with a constant current of 0.2C to a first predetermined voltage, said first predetermined voltage=3.86+2.2*0.035=3.94V;
[0031] 3) Constant voltage charging with the first predetermined voltage until the charging current is lower than 0.01C;
[0032] 4) Charging with a constant current of 0.1C to a second predetermined voltage, the second predetermined voltage=4.25V+8.4*0.015=4.38V;
[0033] 5) Constant voltage chargin...
Embodiment 2
[0038] 1) The positive and negative electrodes of the power lithium-ion battery are spaced apart and placed in the first electrolytic solution. In the first electrolytic solution, propylene carbonate is used as an organic solvent, containing 4mol / L lithium hexafluorophosphate, and containing 0.06mol / L of sodium hexafluorophosphate, and containing 1-cyclohexyl-2-pyrrolidone and 1,3-propane sultone as additives, the concentration of 1-cyclohexyl-2-pyrrolidone is 4.5% by volume, 1,3- The concentration of propane sultone is 1.8% by volume;
[0039] 2) Charging with a constant current of 0.5C to a first predetermined voltage, said first predetermined voltage=3.86+2.2*0.045=3.96V;
[0040] 3) Constant voltage charging with the first predetermined voltage until the charging current is lower than 0.01C;
[0041] 4) Charging with a constant current of 0.2C to a second predetermined voltage, the second predetermined voltage=4.25V+8.4*0.018=4.40V;
[0042] 5) Constant voltage charging...
Embodiment 3
[0047]1) The positive and negative electrodes of the power lithium-ion battery are spaced apart and placed in the first electrolytic solution. In the first electrolytic solution, propylene carbonate is used as an organic solvent, containing 3mol / L lithium hexafluorophosphate, and containing 0.045mol / L of sodium hexafluorophosphate, and containing 1-cyclohexyl-2-pyrrolidone and 1,3-propane sultone as additives, the concentration of 1-cyclohexyl-2-pyrrolidone is 4% by volume, 1,3- The concentration of propane sultone is 1.6% by volume;
[0048] 2) Charging with a constant current of 0.3C to a first predetermined voltage, said first predetermined voltage=3.86+2.2*0.04=3.95V;
[0049] 3) Constant voltage charging with the first predetermined voltage until the charging current is lower than 0.01C;
[0050] 4) Charging with a constant current of 0.15C to a second predetermined voltage, said second predetermined voltage=4.25V+8.4*0.016=4.38V;
[0051] 5) Constant voltage charging ...
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