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Multipurpose wet rubbing fastness improving agent and preparation method thereof

A technology of wet rubbing fastness and improving agent, which is applied in the field of multi-purpose wet rubbing fastness improving agent and its preparation, can solve problems such as poor persistence of working fluid, unstable working fluid, poor wet rubbing fastness, etc., and achieve No hard feeling, good continuous processability, no drop in strength

Active Publication Date: 2022-07-26
苏州联胜化学有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The poor wet rubbing fastness of fabrics dyed with reactive dyes, direct dyes, sulfur dyes, and disperse dyes has always plagued dyeing and finishing workers. Although various methods have been tried to improve wet rubbing fastness, such as choosing relatively high fastness Dye, fully soaped after dyeing to remove floating color, control the pH value of the dyed fabric surface, and use a finishing agent that has little effect on wet rubbing fastness to reduce the coefficient of friction, etc., but these methods can only improve to a certain extent Wet rubbing fastness of dyed fabrics
[0004] At present, the wet rubbing fastness improvers on the market generally have various problems such as unstable working fluid, easy precipitation, large dosage, and poor persistence of working fluid.

Method used

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  • Multipurpose wet rubbing fastness improving agent and preparation method thereof
  • Multipurpose wet rubbing fastness improving agent and preparation method thereof
  • Multipurpose wet rubbing fastness improving agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The multi-purpose wet rubbing fastness improving agent obtained in Example 1 includes: 35 parts of isocyanate-terminated prepolymers, 20 parts of the above-mentioned (formula 2) structural components, 0.6 parts of dibutyltin dilaurate, 5 parts of glycerin, and formic acid 5 parts, 6 parts of octadecyltrimethyl ammonium chloride, 28 parts of the above-mentioned (formula 7) structural components, 0.8 parts of azodiisobutylamidine hydrochloride, and 40 parts of deionized water.

[0035] The above-mentioned (formula 2) component structural formula is:

[0036]

[0037] Wherein, R2 is a C3-C7 linear or branched alkane, and n is an integer of 10-20.

[0038] The structural formula of the above-mentioned (formula 7) component is:

[0039]

[0040] Wherein, R1 is H or CH3, b is an integer of 1-10, and k is an integer of 10-50.

[0041] The synthetic steps of described multipurpose wet rubbing fastness improving agent are as follows:

[0042] S1. Synthesis steps of isocya...

Embodiment 2

[0047] The multi-purpose wet rubbing fastness improving agent obtained in Example 2 includes: 80 parts of isocyanate-terminated prepolymer, 75 parts of (formula 3) structural components, 0.8 parts of organic bismuth, 6 parts of glycerol, 7 parts of acetic acid, ten parts 6 parts of octaalkyltrimethylammonium chloride, 65 parts of structural components (Formula 8), 1.0 part of azodiisobutylamidine hydrochloride, and 70 parts of deionized water.

[0048] The structural formula of the above-mentioned (formula 3) component is:

[0049]

[0050] Wherein, R1 is H or CH3, and n is an integer of 10-20.

[0051] The structural formula of the above-mentioned (Formula 8) component is:

[0052]

[0053] Wherein, R2 is a C3-C7 straight or branched chain alkane, b is an integer of 1-10, and k is an integer of 10-50.

[0054] The synthetic steps of described multipurpose wet rubbing fastness improving agent are as follows:

[0055] S101, the synthesis step of terminal isocyanate pre...

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PUM

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Abstract

The multi-purpose wet rubbing fastness improving agent provided by the invention has the characteristics of good stability of working fluid, good continuous processability of working fluid, high utilization rate of auxiliary agents, no precipitation and no oil drift. , can be used in the same bath with after-finishing auxiliaries, and can be used to improve the dry and wet rubbing fastness of dyed fabrics such as reactive dyes, direct dyes, sulfur dyes, and disperse dyes. The wet rub fastness improving agent has a highly reactive epoxy group in the polyether segment of the molecule, and the isocyanate group can be re-unblocked after high temperature setting after fabric finishing, and can be reactively combined with fabric and dyes. A dense and tough film is formed on the surface of the fabric. The finished fabric is washable, does not feel hard, does not decrease in strength, and has a certain softness, which can reduce the amount of hand finishing agent in the finishing auxiliaries to a certain extent. .

Description

technical field [0001] The invention relates to the technical field of textile chemicals, in particular to a multipurpose wet rubbing fastness improving agent and a preparation method thereof. Background technique [0002] In recent years, with the development of society and the improvement of people's consumption level, consumers have higher and higher requirements for the quality of clothing performance. As an important performance indicator, wet rubbing color fastness is more and more popular among people. Attention, for domestic brand orders and foreign trade export orders, when encountering dark clothing dyes, it is generally required that the wet rubbing fastness should reach level 3 or above, which puts forward higher requirements for wet rubbing fastness. [0003] The problem of poor wet rubbing fastness of reactive dyes, direct dyes, sulfur dyes, and disperse dyes has always plagued dyeing and finishing workers, although various methods have been tried to improve we...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/67C08G18/66C08G18/48C08G18/34C08G18/12C08G18/32D06P5/08
CPCC08G18/6692C08G18/4825C08G18/348C08G18/12C08G18/6795C08G18/3206D06P5/08
Inventor 陈新华
Owner 苏州联胜化学有限公司
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