Composition for hologram recording medium, and hologram recording medium
A technology of holographic recording medium and composition, which is applied in holographic recording materials, recording information storage, holographic technology, etc., and can solve problems that have not yet been made
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Embodiment 1
[0586]
[0587] Dissolve 3-HO-ABNO: 0.15g in DURANATE(TM) TSS-100: 2.85g. After dissolving the caprylic acid solution: 0.002 g of bismuth tris(2-ethylhexanoate) there, it stirred at 45 degreeC under reduced pressure, and it was made to react for 2 hours. 3450 cm from the hydroxyl group of 3-HO-ABNO observed by FT-IR -1 The disappearance of the peak was used to confirm the reaction between the hydroxyl group of 3-HO-ABNO and the isocyanate group. Further add and mix DURANATE(TM)TSS-100: 12g to prepare 3-HO-ABNO masterbatch.
[0588]
[0589] Polymerizable monomer HLM101: 0.362 g, photopolymerization initiator HLI02: 0.0145 g were dissolved in DURANATE (TM) TSS-100: 3.69 g, and it was made A liquid.
[0590] In addition, PRAXCELL PCL-205U (polycaprolactone diol (molecular weight 530)): 2.42g and PRAXCELL PCL-305 (polycaprolactone triol (molecular weight 550)): 1.04g were mixed (PRAXCELL PCL-205U: PRAXCELL PCL -305=70:30 (weight ratio)), octanoic acid solution in which bis...
Embodiment 2~4
[0595] Except that the 3-HO-ABNO masterbatch was mixed so that the content molar ratio of 3-HO-ABNO and the photopolymerization initiator of component (d) was the value shown in Table 1, it was carried out in the same manner as in Example 1. The composition for holographic recording media and the sample for evaluation of the composition for holographic recording media were produced.
Embodiment 5~8
[0597] Use 5-HO-AZADO instead of 3-HO-ABNO, and make the 5-HO-AZADO masterbatch so that the content molar ratio of 5-HO-AZADO and the photopolymerization initiator of component (d) is the value shown in Table 1. The composition for holographic recording media and the sample for evaluation of the composition for holographic recording media were produced similarly to Example 1 except having mixed it.
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