The invention discloses a
photopolymer type
holographic recording medium and a preparation method and application thereof.The
photopolymer type
holographic recording medium comprises a writing
monomer, film-forming resin, a photosensitive
initiation combination agent and a catalyst, the writing
monomer comprises nanoparticles and a polymerizable
monomer, and the film-forming resin is prepared from the nanoparticles and the polymerizable monomer; the
refractive index of the polymerizable monomer is smaller than that of the nanoparticles, and the difference between the
refractive index of the nanoparticles and the
refractive index of the polymerizable monomer is larger than 0.5. The film-forming resin includes a
polyol compound and an
isocyanate-based compound. The catalyst is used for catalyzing a
polyol compound and an
isocyanate compound to react to form a film. The photosensitive
initiation combination agent is used for sensing light and inducing
polymerization of the polymerizable monomer. According to the
photopolymer type
holographic recording medium disclosed by the invention, after
exposure, the polymerizable monomers located in the bright area and the nanoparticles extruded to the dark area have relatively large refractive index difference, so that the
refractive index modulation degree of the recording
grating can be improved; the film-forming resin provides effective support for the nanoparticles, and the nanoparticles are not agglomerated.