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34 results about "Thianthrene" patented technology

Thianthrene is a sulfur-containing heterocyclic chemical compound. It is a derivative of the parent heterocycle called dithiin. It is notable for its ease of oxidation.

Thianthrene oxide-aromatic amine organic luminescent small molecule as well as preparation and application thereof

The invention belongs to the technical field of organic luminescent materials and discloses a thianthrene oxide-aromatic amine organic luminescent small molecule as well as preparation and an application thereof. The thianthrene oxide-aromatic amine organic luminescent small molecule has a structure formula as shown in the specification, wherein at least one of Ar1, Ar2, Ar3 and Ar4 is a group with an aromatic amine structure, and the rest is hydrogen. The preparation method comprises the following steps: (1) carrying out reaction on thianthrene and liquid bromine to obtain bromo-substituted thianthrene; (2) carrying out reaction on the bromo-substituted thianthrene and hydrogen peroxide to obtain bromo-substituted thianthrene oxide; and (3) carrying out reaction on the bromo-substituted thianthrene oxide and a compound with an aromatic amine structure to obtain the thianthrene oxide-aromatic amine organic luminescent small molecule. The thianthrene oxide-aromatic amine organic luminescent small molecule is good in luminescent property and can be used for preparing organic luminescent devices as a luminescent layer material.
Owner:SOUTH CHINA UNIV OF TECH

Holographic recording medium

A holographic recording medium includes a recording layer. The recording layer includes a framework being expressed with the following general formula (1),In the above formula (1), Ar represents a substituted or unsubstituted group selected from benzothiophene group, naphthothiophene group, dibenzothiophene group, thienothiophene group, dithienobenzene group, benzothiazole group, naphthothiazole group, benzoisothiazole group, naphthoisothiazole group, phenothiazine group, phenoxathiin group, dithianaphthalene group, thianthrene group, thioxanthene group, and bithiophene group. In addition, n is an integer from 1 to 4.
Owner:KK TOSHIBA

Thianthrene compound, display panel and display device

The invention provides a thianthrene compound with a structure represented by the formula (I) in the description. Ar1 and Ar2 are independently selected from any one of a single bond, substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl, substituted or unsubstituted anthryl, substituted or unsubstituted phenanthryl, substituted or unsubstituted acenaphthylene and substitutedor unsubstituted heteroaromatic ring; m is 0 or 1; D1 and D2 are independently selected from aryl or heteroaryl, and Ar2 and Ar3 are independently selected from aryl or heteroaryl. The thianthrene compound contains sulfur element and has high polarizability, and a material with high refractive index is obtained; the sulfur atom has good polarizability and high electron richness, so that the fusedring organic compound material has good charge transport properties and electron donating properties and is quite applicable as a capping layer (cathode cap layer, CPL) material.
Owner:WUHAN TIANMA MICRO ELECTRONICS CO LTD

Compound, display panel and display device

The invention provides a compound, a display panel and a display device. The compound is in a structure shown as a formula (I), wherein R1 and R2 refer to electron-donating groups and independently selected from any one of C1-C20 alkyl groups, C3-C20 cycloalkyl groups, C1-C20 alkoxy groups, a phenyl, a biphenyl, a naphthyl, an anthryl, a phenanthryl, an acenaphthylene group, a pyrenyl, a perylenegrouop, a fluorenyl, a spirobifluorene group, a chrysene group, a benzo-phenanthryl, a benzo-anthryl, a fluoranthene group, a pyrene groupo, a furyl, a benzofuryl, a substituted or unsubstituted dibenzofuran group, a substituted or unsubstituted thienyl, a benzothiophene group, a dibenzothiophene group, a phenoxazine group, a phenazinyl, a phenothiazinyl, a thianthrene group, a carbazolyl, an acridinyl and a diarylamine group, and m is selected from an integer range of 1-4. The compound is a material with AIE characteristics and TADF characteristics, triplet-state excitons are converted into singlet-state excitons through a reverse intersystem conversion process to realize radioluminescence, and the exciton utilization rate of luminescent materials is increased.
Owner:WUHAN TIANMA MICRO ELECTRONICS CO LTD

Heterocyclic compounds and their use in electro-optical or opto-electronic devices

Compounds exhibiting high hole mobility and / or high glass transition temperatures are provided which are of the formula [Ar1]m[Ar2]n wherein:m is an integer from 1-3 and n is an integer and may be 1 or 2;Ar1 represents a thianthrene residue having a linkage to Ar2 at one or two positions selected from ring positions 1-4 and 5-8 and optionally mono-, bi- or poly-substituted with C1-C4-alkyl-, C1-C4-alkoxy-, fluoro, phenyl or biphenyl which in the case of phenyl or biphenyl may be further substituted with C1-C4-alkyl-, C1-C4-alkoxy- or fluoro;Ar2 represents a residue derived from an arylamine in which the aryl rings are phenyl, naphthyl or anthracenyl optionally substituted with C1-C4-alkyl-, C1-C4-alkoxy- or fluoro, a polycyclic fused or chain aromatic ring system optionally containing nitrogen or sulphur and in a chain aromatic ring system optionally containing one or more chain oxygen or sulphur atoms, a triarylphosphine oxide or an arylsilane the rings of any of which are optionally substituted with C1-C4-alkyl-, C1-C4-alkoxy- or fluoro.Certain of the compounds may be used in electron transport layers and may be doped with p-type dopants. They may be incorporated into OLEDs, organic photovoltaic devices, imaging members and thin film transistors.In further embodiments there are provided OLEDs or other devices e.g. electrostatic latent image forming members in which improved efficiency is obtained by using as electron transport layers, electron injectors, hosts and emitters (dopants) ambipolar or electron-transmitting compounds in which thianthrene is bonded to aryl e.g. 1-anthracenyl-9-yl-thianthrene, 1-biphenyl-4-yl-thianthrene and 9,10-Bis(1-thianthrenyl) anthracene.
Owner:POWER OLEDS

9, 9, 10, 10-tetraoxygen-thianthrene-contained water/alcohol-soluble polymer as well as preparation method and application thereof

The invention belongs to the technical field of organic photoelectricity, and discloses a 9, 9, 10, 10-tetraoxygen-thianthrene-contained water / alcohol-soluble polymer as well as a preparation method and application thereof. The structure of the polymer is as shown in formula (1), where x is greater than 0 and less than or equal to 0.5, n is a repeated unit and is equal to 10 to 1,000, and R1 is apolar group-containing water / alcohol-soluble side chain. According to the 9, 9, 10, 10-tetraoxygen-thianthrene-contained water / alcohol-soluble polymer, through the introduction of a polar side chain-contained 9, 9, 10, 10-tetraoxygen-thianthrene unit into the polymer, the LUMO energy level of the polymer can be reduced, the electron mobility can be increased, injection and transmission of electrons are facilitated, and the HOMO energy level of the polymer can be reduced at the same time to prevent hole transportation; a strong polar group on a side chain enables the polymer to be dissolved with a strong polar solvent such as water and alcohol, and a uniform thin film is prepared through a solution processing mode, so that solvent orthogonal processing can be realized. The polymer is applied to an electron transmission layer of an organic light emitting diode, and the device efficiency can be improved.
Owner:SOUTH CHINA INST OF COLLABORATIVE INNOVATION

Use of thianthrene-containing polymers as a charge store

The present invention relates to the use of a thianthrene-containing polymer as redox-active electrode material, for example as an electrode slurry, for electrical charge storage means, especially secondary batteries, It additionally also relates to the electrode material comprising the polymer, and to an electrode and an electrical charge storage means comprising the polymer,
Owner:INNOVATIONLAB

Organometallic monomers and high refractive index polymers derived therefrom

Synthesis of thianthrene moiety containing silane and germane monomers and their polymerization is presented. The polymers show high refractive index, high transparency and excellent thermal stability. They are useful as dielectric films for semiconductor industry and for optical applications, including high-RI materials in CMOS image sensors.
Owner:SILECS OY

Method for separating and preparing alpha-terthienyl, thianthrene and p-terphenyl

The invention relates to a method for separating and preparing high-purity monomers of alpha-terthienyl, thianthrene and p-terphenyl from plant flaveria bidentis extracts, obtained by petroleum ether refluxing, with high-speed countercurrent chromatography. In the method, the countercurrent chromatography is adopted to separate and prepare the high-purity alpha-terthienyl, thianthrene and p-terphenyl from the plant flaveria bidentis extracts, obtained by petroleum ether refluxing, a solvent comprises three components including petroleum ether or n-alkane, dichloromethane and acetonitrile or fatty alcohol in the volume ratio of 10:(0-3):(12-7); and the method is suitable for separation and preparation of the monomers of alpha-terthienyl, thianthrene and p-terphenyl through various models of countercurrent chromatographs, so that a large amount of crude products or synthetic mixtures can be directly fed, the purity of separated alpha-terthienyl is over 99%, and the purity of thianthrene and p-terphenyl can reach more than 90%.
Owner:BEIJING UNIV OF CHEM TECH

Environment-friendly preservative and preparation method thereof

The invention discloses an environment-friendly preservative which is characterized by being prepared from the following components in parts by weight: 3-6 parts of salicylaldehyde norbornadiene ionization co-modified methoxy poly (ethylene glycol) amine, 2-4 parts of lignosulfonate diazonium alkyl urea, 1-2 parts of 1-thianthrene boric acid, 0.5-1.5 parts of 1-ethyl 3guanidyl thiourea hydrochloride, 5-8 parts of antibacterial Chinese herbal medicine extracts, 15-25 parts of ethanol and 120-150 parts of deionized water. The invention further provides a preparation method thereof. The environment-friendly preservative disclosed by the invention is good in preservative effect, good in environment-friendly performance, broad in antibacterial spectrum and excellent in performance stability.
Owner:何述安

Carbazole compound containing thianthrene and diphenylethlene structures and preparation of carbazole compound

The invention provides a carbazole compound containing thianthrene and diphenylethlene structures. The carbazole compound is particularly 9-ethyl-3-(1,2-diphenylvinyl)-6-(5,5,10,10-thianthrene)carbazole. The preparation method comprises the following steps: firstly, preparing 9-ethyl-3-(1,2-diphenylvinyl)-6-carbazole boric acid and 2-bromine-5,5,10,10-thianthrene; and then enabling reaction between 9-ethyl-3-(1,2-diphenylvinyl)-6-carbazole boric acid and 2-bromine-5,5,10,10-thianthrene to obtain 9-ethyl-3-(1,2-diphenylvinyl)-6-(5,5,10,10-thianthrene)carbazole. The carbazole compound has favorable heat stability, electrochemical stability, charge transfer performance and luminescence property and can serve as a blue-green organic electroluminescence material.
Owner:SHANXI UNIV

Sample method for synthesis of thianthrene based on sulfur powder

A sample method for synthesis of thianthrene based on a sulfur powder comprises the steps: weighing 0.5 mmol of 1,2-diiodobenzene, 0.5 mmol of the sulfur powder, 0.05 mmol of cuprous iodide, 0.1 mmol of 1,10-phenanthroline and 1.0 mmol of potassium carbonate into a 25 mL round-bottom flask, adding a magnetic stirring bar and 2 mL of dimethyl sulfoxide, drying the obtained organic phase with anhydrous Na2SO4, filtering, evaporating to remove a solvent of the obtained filtrate, and separating and purifying the residue by silica gel column chromatography to obtain the thianthrene product. The method has the advantages: 1, raw materials are simple, and thiophenol or a derivative thereof having pungent smell has no need to be used; 2, the operation is simple, and any anhydrous and anaerobic operations and other special operations are not needed; and 3, reaction conditions are mild, the reaction can be completed by heating at 90 DEG C, and the thianthrene is suitable for magnified synthesis.
Owner:JIANGXI NORMAL UNIV

9,9,10,10-tetroxide-thianthrene seven-member fused ring unit containing polymer as well as preparation method and application thereof

The invention discloses a 9,9,10,10-tetroxide-thianthrene seven-member fused ring unit containing polymer as well as a preparation method and application thereof. A structural formula of the 9,9,10,10-tetroxide-thianthrene seven-member fused ring unit containing polymer is as follows; and in the formula, x1 and x2 are molar fractions of component unit component and satisfy the following relationships that x1 is larger than or equal to 0 and smaller than 1, x2 is larger than 0 and smaller than or equal to 1, and x1+x2 is equal to 1, and n is a repeated unit and is equal to 10-1000. The polymerhas very good thermal stability and relatively high fluorescence quantum yield; and with existence of a sulfuryl group unit, the electronic transmission performance of the polymer can also be improved. By regulating a ratio of comonomer units, the luminescence spectra of the polymer can be regulated to obtain the polymers with light emitting in different colors. The 9,9,10,10-tetroxide-thianthreneseven-member fused ring unit containing polymer can be used as an organic luminescent material and is prepared into a polymer light-emitting diode with a solution processing method. A chemical structural formula is described in the description.
Owner:东莞伏安光电科技有限公司

Thianthrene-containing pentabasic condensed nucleus unit derivative and its synthetic method and application

The invention discloses a thianthrene-containing pentabasic condensed nucleus unit derivative and its synthetic method and an application. The thianthrene-containing pentabasic condensed nucleus unitis obtained by performing ring closure on a ternary condensed nucleus unit and benzene derivative after coupling. In the invention, the thianthrene-containing pentabasic condensed nucleus unit is a pentabasic ring combination structure, and is good for improving the output and thermal stability of molecular fluorescence quantum. The thianthrene IN THE thianthrene-containing pentabasic condensed nucleus unit derivative can improve the molecular hole transport performance; besides, the thianthrene has a non-planer structure and can maintain the molecular singlet state and three-line state gradewhile inhibit the molecule piling. The thianthrene-containing pentabasic condensed nucleus unit derivative can be used as an organic lighting or main body material; through evaporation and solution process, the organic lighting diode is prepared.
Owner:SOUTH CHINA INST OF COLLABORATIVE INNOVATION

Allylation coupling reaction method and application thereof

The invention discloses a novel allylation coupling reaction method. The method comprises the following steps: with alkenyl thianthrene salt as an allylation reagent, respectively with a carboxylic acid compound and organic amine as substrates, in the presence of alkali, or directly with a carboxylate compound and aromatic hydrocarbon / heterocyclic hydrocarbon as substrates, reacting in an organic solvent at room temperature to obtain an allylation coupling product. The preparation method has the advantages of mild conditions and no transition metal participation, can efficiently realize the preparation of various allyl esters, allyl substituted amines and allyl substituted aromatic hydrocarbon / heterocyclic hydrocarbon compounds, and has ideal application prospects in the fields of fine chemical engineering, material science and pharmacy.
Owner:SOUTH UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA

Protein labeling method for acetenyl sulfosalt click reaction

The invention provides a protein labeling method for an ethynyl sulfosalt click reaction, and particularly relates to a method for carrying out a copper-free catalytic click reaction of cycloaddition of ethynyl sulfosalt and azide in a water-soluble medium at room temperature, and carrying out a click reaction on a sample to be detected and ethynyl sulfosalt after the sample to be detected is modified by an azide reagent. The ethynyl sulfur salt is synthesized by dimethyl sulfoxide, and the structural formula is as follows: R1 is selected from one of hydrogen, alkyl, phenyl, benzyl or substituted benzyl, and R2 and R3 are selected from one of alkyl, phenyl, phenoxathiane, thianthrene or phenyl phenothiazine. The method does not need catalysis of copper, can be rapidly carried out at room temperature, and solves the problems that in the prior art, a probe is too large in size, difficult to synthesize, poor in solubility and cell penetrability and the like.
Owner:PEKING UNIV SHENZHEN GRADUATE SCHOOL +1

Polymer containing 9,9,10,10-tetraoxy-thianthrene five-element fused-ring unit as well as preparation method and application thereof

The invention belongs to the technical field of organic photoelectric and discloses a polymer containing 9,9,10,10-tetraoxy-thianthrene five-element fused-ring unit as well as a preparation method andapplication thereof. The 9,9,10,10-tetraoxy-thianthrene five-element fused-ring unit is a unit with strong electrical absorption and can improve the electron transmission property of the polymer. Through adjusting the copolymer unit proportion, a luminescent spectrum and a band gap can be well adjusted to obtain the polymers with different functions. The five-element parallel-ring structure can further improve the carrier mobility and stability of the polymer. The polymer containing 9,9,10,10-tetraoxy-thianthrene five-element fused-ring unit provided by the invention can be used as the organic photoelectric materials or polymer solar cell materials to prepare into polymer light-emitting diodes and polymer solar cells through a solution processing method.
Owner:东莞伏安光电科技有限公司

Thianthrene oxide-based yttrium complex phosphorescent luminescent materials and preparation methods thereof

The invention discloses thianthrene oxide-based yttrium complex phosphorescent luminescent materials and preparation methods thereof. The thianthrene oxide-based yttrium complex phosphorescent luminescent materials have general structural formulas shown in the description. The preparation methods comprise that an organic ligand containing a strong electron-withdrawing thianthrene oxide functionalgroup or other organic ligands and antimony trichloride undergo a reaction to produce a high electron injection transmission iridium complex phosphorescent material with phosphorescence quantum efficiency of 95% or more. The yttrium complex phosphorescent luminescent materials solve the problem that the traditional luminescent material has low phosphorescence quantum efficiency and weak electron injection transmission ability, and have an important application value in preparation of high performance organic light emitting diodes.
Owner:山西绿普光电新材料科技有限公司

Heterocyclic compounds and their use in electro-optical or opto-electronic devices

ActiveUS20180323378A9Favourable combination of hole mobilityHigh pointGroup 4/14 element organic compoundsIndium organic compoundsThianthreneLatent image
Compounds exhibiting high hole mobility and / or high glass transition temperatures are provided which are of the formula [Ar1]m[Ar2]n wherein:m is an integer from 1-3 and n is an integer and may be 1 or 2;Ar1 represents a thianthrene residue having a linkage to Ar2 at one or two positions selected from ring positions 1-4 and 5-8 and optionally mono-, bi- or poly-substituted with C1-C4-alkyl-, C1-C4-alkoxy-, fluoro, phenyl or biphenyl which in the case of phenyl or biphenyl may be further substituted with C1-C4-alkyl-, C1-C4-alkoxy- or fluoro;Ar2 represents a residue derived from an arylamine in which the aryl rings are phenyl, naphthyl or anthracenyl optionally substituted with C1-C4-alkyl-, C1-C4-alkoxy- or fluoro, a polycyclic fused or chain aromatic ring system optionally containing nitrogen or sulphur and in a chain aromatic ring system optionally containing one or more chain oxygen or sulphur atoms, a triarylphosphine oxide or an arylsilane the rings of any of which are optionally substituted with C1-C4-alkyl-, C1-C4-alkoxy- or fluoro.Certain of the compounds may be used in electron transport layers and may be doped with p-type dopants. They may be incorporated into OLEDs, organic photovoltaic devices, imaging members and thin film transistors.In further embodiments there are provided OLEDs or other devices e.g. electrostatic latent image forming members in which improved efficiency is obtained by using as electron transport layers, electron injectors, hosts and emitters (dopants) ambipolar or electron-transmitting compounds in which thianthrene is bonded to aryl e.g. 1-anthracenyl-9-yl-thianthrene, 1-biphenyl-4-yl-thianthrene and 9,10-Bis(1-thianthrenyl) anthracene.
Owner:POWER OLEDS

Organometallic Monomers and high Refractive index Polymers derived therefrom

Synthesis of thianthrene moiety containing silane and germane monomers and their polymerization is presented. The polymers show high refractive index, high transparency and excellent thermal stability. They are useful as dielectric films for semiconductor industry and for optical applications, including high-RI materials in CMOS image sensors.
Owner:SILECS OY

Three-membered ring preparation method without metal catalysis

The invention discloses a novel preparation method of a three-membered ring, which comprises the following step: reacting an amino derivative or an alkyl derivative containing an electron withdrawing group as a substrate with olefin thianthrene salt in an organic solvent in the presence of alkali at room temperature to obtain a three-membered ring product. The preparation method has the characteristics of mild conditions, no transition metal participation, small environmental pollution and high yield.
Owner:SOUTH UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA

A method for preparing sulfur-doped graphene film

The invention discloses a method for preparing a sulfur-doped graphene film, and relates to the field of preparation of novel two-dimensional nanometer materials. The invention comprises the following steps: respectively placing the metal substrate and thianthrene in a heat-insulated heating zone of a reaction chamber of a chemical vapor deposition system; feeding mixed gas into the reaction chamber under vacuum conditions; annealing the metal substrate at high temperature After treatment, keep warm at the preparation temperature of the graphene film, then heat the thianthrene to vaporize it, and transport the thianthrene gas to the metal substrate through the mixed gas to react, and finally prepare the sulfur-doped graphene film on the metal substrate . The preparation process of the present invention is simple, the cost is low, large-scale industrial production can be realized, and the raw materials are green and pollution-free; the number of layers, doping content and area of ​​the sulfur-doped graphene film prepared by the present invention can be flexibly adjusted by controlling related parameters, thereby The preparation of sulfur-doped graphene films with different properties is of great value in the field of basic scientific research and practical applications such as sensors.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Preparation method of flexible triboluminescent composite film

The invention belongs to the technical field of thin films, and relates to a method for preparing a flexible triboluminescence composite film; the method proposed by the invention is to sequentially vapor-deposit N2, N7-bis(1-naphthyl) on a polyethylene terephthalate substrate )‑N2, N7‑diphenylthianthracene‑2,7‑diamine layer, copper phthalocyanine layer, lithium fluoride layer, tris(4‑(N‑phenyl‑N‑(1‑naphthyl)amine group ) phenylphosphine layer, and then use ethylene-vinyl acetate copolymer plastics to obtain a flexible triboluminescence composite film, utilize the synergistic effect between each component in the composite structure, triboluminescence.Advantage of the present invention is: (1) triboluminescence The brightness reaches 90cd / m2, which is blue light; (2) After repeated rubbing for 50,000 times, the triboluminescent brightness only drops by 10%, which greatly improves the reliability of the triboluminescent composite film.
Owner:TAICANG BIQI NEW MATERIAL RES & DEV

A kind of protein labeling method of ethynyl sulfate click reaction

The invention provides a protein labeling method for acetylene sulfur salt click reaction, especially a copper-free catalyzed "click" reaction in which acetylene sulfur salt and azide undergo cycloaddition in a water-soluble medium at room temperature. After the sample is modified with an azide reagent, a click reaction occurs with ethynyl sulfate. Ethynyl sulfur salt is synthesized from dimethyl sulfoxide, the structural formula is: R 1 One selected from hydrogen, alkyl, phenyl, benzyl or substituted benzyl, R 2 with R 3 One selected from alkyl, phenyl, phenothiazine, thianthrene or phenylphenothiazine. The invention does not need the catalysis of copper, can be rapidly carried out at room temperature, and solves the problems of the probes in the prior art that are too large in size, difficult to synthesize, and have poor solubility and cell penetration.
Owner:PEKING UNIV SHENZHEN GRADUATE SCHOOL +1
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