Compound, display panel and display device
A technology for display panels and compounds, applied in the fields of compounds, display panels and display devices, can solve the problems of poor luminescence spectrum overlap, unsatisfactory luminescence wavelength, difficult purification and separation, etc., so as to improve fluorescence quantum efficiency and improve exciton utilization rate. , the effect of improving the luminous efficiency
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Embodiment 1
[0076] Synthesis of Compound M1
[0077] The synthetic route of compound M1 is as follows.
[0078]
[0079] The specific synthesis steps of compound M1 are as follows.
[0080]
[0081] In a 200ml three-necked flask, 8.84g (20mmol) of substrate A (20mmol) and THF (80mL) were added to dissolve, and nitrogen replacement was performed three times. Cool down to -78°C, and when the temperature reaches, control the temperature below -65°C and slowly add n-BuLi 20mL (50mmol) dropwise, and stir for 30min after the dropwise addition is complete. Then 4.35 g (40 mmol) of TMS-Cl was slowly added dropwise, and the temperature was raised to 0° C. for 4 h. After completion, add ice water to quench. DCM (80mL*2) was added for extraction. The collected organic phase was rotary evaporated to obtain a pale yellow oil. Crystallization using Tol / EtOH afforded a pale yellow solid. 6.45 g (15 mmol) of light yellow solid, anhydrous toluene solution (70 mL) and 0.76 mL (8 mmol) of boron ...
Embodiment 2
[0097] Synthesis of compound M2
[0098]
[0099] The specific synthesis steps of compound M2 are as follows.
[0100]
[0101] In a 200ml three-necked flask, 8.84g (20mmol) of substrate A (20mmol) and THF (80mL) were added to dissolve, and nitrogen replacement was performed three times. Cool down to -78°C, and when the temperature reaches, control the temperature below -65°C and slowly add n-BuLi 20mL (50mmol) dropwise, and stir for 30min after the dropwise addition is complete. Then 4.35 g (40 mmol) of TMS-Cl was slowly added dropwise, and the temperature was raised to 0° C. for 4 h. After completion, add ice water to quench. DCM (80mL*2) was added for extraction. The collected organic phase was rotary evaporated to obtain a pale yellow oil. Crystallization using Tol / EtOH afforded a pale yellow solid. 6.45 g (15 mmol) of light yellow solid, anhydrous toluene solution (70 mL) and 0.76 mL (8 mmol) of boron tribromide were successively added into a 200 mL stuffy jar....
Embodiment 3
[0121] Synthesis of Compound M3
[0122]
[0123] The specific synthesis steps of compound M3 are as follows.
[0124]
[0125] In a 200ml three-necked flask, 8.84g (20mmol) of substrate A (20mmol) and THF (80mL) were added to dissolve, and nitrogen replacement was performed three times. Cool down to -78°C, and when the temperature reaches, control the temperature below -65°C and slowly add n-BuLi 20mL (50mmol) dropwise, and stir for 30min after the dropwise addition is complete. Then 4.35 g (40 mmol) of TMS-Cl was slowly added dropwise, and the temperature was raised to 0° C. for 4 h. After completion, add ice water to quench. DCM (80mL*2) was added for extraction. The collected organic phase was rotary evaporated to obtain a pale yellow oil. Crystallization using Tol / EtOH afforded a pale yellow solid. 6.45 g (15 mmol) of light yellow solid, anhydrous toluene solution (70 mL) and 0.76 mL (8 mmol) of boron tribromide were successively added into a 200 mL stuffy jar....
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