Anti-glare film with high wear resistance and low flash point

An anti-glare film and anti-glare technology, applied in optics, optical components, instruments, etc., can solve the problems of wear resistance and flash point, the lack of essential improvement in wear resistance, poor wear resistance of anti-glare film, etc. problems, to achieve the effect of being conducive to stress absorption, improving the overall hardness, and good flash point

Active Publication Date: 2021-02-05
NUOVO FILM SUZHOU CHINA INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these methods can all realize the anti-glare effect, there are defects: some methods are complicated in technology, high in cost, and the wear resistance of the obtained anti-glare film is not good, or can not take into account both wear resistance and flash point problems; To improve the sharpness and visual effects of display devices, the problem of flash point must also be taken seriously
[0004] The patent with the publication number CN109810555A discloses a high-hardness, anti-glare hardened layer coating solution and a hardened film, which are prepared by adding silica particles to the combination system of acrylic resin and acrylic monomer to prepare high wear-resistant anti-glare film, but the flash point of the prepared anti-glare film is poor
The patent with the publication number CN104817951A discloses an anti-glare coating and an anti-glare hardened film. By adding two kinds of inorganic particles with different particle sizes to the combination system of acrylic resin and acrylic monomer, an anti-glare coating with excellent flash point is prepared. film, but the prepared anti-glare film has poor abrasion resistance
The patent publication No. CN102762644A discloses a coating for an anti-glare film and an anti-glare film comprising the coating, the coating for an anti-glare film includes a binder resin, organic particles and inorganic particles, and the The difference in the refractive index of the binder resin and the organic particles and the difference in the refractive index of the binder resin and the inorganic particles are each 0.3 or less, and the prepared anti-glare film has excellent anti-glare properties , image clarity and contrast, but there is no essential improvement in wear resistance
[0005] For this reason, it is necessary to design a low-flash point, high wear-resistant anti-glare film, which can overcome the problem that the existing wear-resistant and flash point cannot be taken into account.

Method used

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  • Anti-glare film with high wear resistance and low flash point
  • Anti-glare film with high wear resistance and low flash point
  • Anti-glare film with high wear resistance and low flash point

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preparation example Construction

[0047] In the present invention, the preparation method of the anti-glare film comprises the following steps:

[0048] (1) Mix the raw materials of the anti-glare coating solution according to the proportion, and stir evenly to obtain coating solution 1, coating solution 2 and coating solution 3.

[0049] (2) Coating the first coating solution, the second coating solution and the third coating solution on the substrate in sequence, and then using ultraviolet light to obtain the anti-glare film.

[0050] The preferred solution in the present invention is that when preparing the coating solution, firstly add the acrylate prepolymer and acrylate monomer to the solvent, stir and dissolve at a high speed, then add the photoinitiator, anti-glare particles and leveling agent , dispersant, fluorine-containing additives, fully stirred evenly.

[0051] The preferred solution in the present invention is that, when coating, the surface of the coating is dried by heating and baking every ...

Embodiment 1

[0054] 1. Preparation of coating solution

[0055] Add 40 parts of hexafunctional urethane acrylic resin oligomer CN9010NS (manufactured by Sartomer, refractive index 1.49) and 20 parts of pentafunctional acrylate monomer SR399NS (manufactured by Sartomer, refractive index 1.49) in 200 parts of propylene glycol methyl ether ), after high-speed stirring and dissolving, add 4 parts of photoinitiator 184 (manufactured by Tianjin Tianjiao Chemical Co., Ltd.) and 1 part of photoinitiator TPO (manufactured by Tianjin Tianjiao Chemical Co., Ltd.), then add 1 part of antiglare particle PMMA particle MX- 80H3WT (Nippon Soken Chemical, particle size 0.7μm, refractive index 1.48), then add 1 part of leveling agent BYK-333 (Byke Chemicals), 1 part of dispersant DISPERBYK-110 (Byke Chemicals), fully stir evenly, Obtain coating solution 1;

[0056] Add 50 parts of hexafunctional urethane acrylic resin oligomer CN9010NS (manufactured by Sartomer, refractive index 1.49) and 20 parts of penta...

Embodiment 2

[0061] 1. Preparation of coating solution

[0062] Add 70 parts of hexafunctional urethane acrylic resin oligomer CN9010NS (manufactured by Sartomer, refractive index 1.49) and 20 parts of pentafunctional acrylate monomer SR399NS (manufactured by Sartomer, refractive index 1.49) in 200 parts of propylene glycol methyl ether ), after high-speed stirring and dissolving, add 4 parts of photoinitiator 184 (manufactured by Tianjin Tianjiao Chemical Co., Ltd.) and 1 part of photoinitiator TPO (manufactured by Tianjin Tianjiao Chemical Co., Ltd.), then add 1 part of antiglare particle PMMA particle MX- 80H3WT (Nippon Soken Chemical, particle size 0.7μm, refractive index 1.48), then add 1 part of leveling agent BYK-333 (Byke Chemicals), 1 part of dispersant DISPERBYK-110 (Byke Chemicals), fully stir evenly, Obtain coating solution 1;

[0063] Add 70 parts of hexafunctional urethane acrylic resin oligomer CN9010NS (manufactured by Sartomer, refractive index 1.49) and 20 parts of penta...

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Abstract

The invention discloses an anti-glare film with high wear resistance and a low flash point. The anti-glare film comprises a base material, and a first anti-glare coating, a second anti-glare coating and a third anti-glare coating which are sequentially coated on the base material; the first anti-glare coating, the second anti-glare coating and the third anti-glare coating respectively contain first anti-glare particles, second anti-glare particles and third anti-glare particles, the particle sizes of the first anti-glare particles, the second anti-glare particles and the third anti-glare particles are sequentially increased, the particle size difference of the first anti-glare particles and the second anti-glare particles is 0.5-5 [mu]m, the particle size difference between the second anti-glare particles and the third anti-glare particles is 1-7 [mu]m; and the first anti-glare particles, the second anti-glare particles and the third anti-glare particles are all organic particles, andthe refractive index difference between the first anti-glare particles, the second anti-glare particles and the resin in the corresponding coatings is less than 0.1. The anti-glare film provided by the invention has excellent properties of low flash point and high definition, and also has excellent wear resistance.

Description

technical field [0001] The invention relates to the technical field of anti-glare films, in particular to an anti-glare film with high wear resistance and low flash point. Background technique [0002] With the rapid development of the electronic information industry, various portable electronic terminals and electronic products, such as mobile phones, computers, conference electronic tablets, etc., have become extremely popular, bringing great convenience to people's work and life. But in the process of actually using electronic products, people are often affected by "glare". "Glare" refers to the visual condition that causes visual discomfort and reduces the visibility of objects due to unsuitable brightness distribution or extreme brightness contrast in space or time in the field of vision. Strong glare can also cause problems such as vision loss, depression, and irritability. "Anti-glare" means that when light passes through the screen or the surface of an object, a ce...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/02G02B1/14C08J7/04C09D175/14C09D7/65C08L67/02
CPCG02B5/0226G02B5/0268G02B1/14C08J7/042C09D175/14C09D7/65C08J2367/02C08J2475/14C08J2433/12C08L33/12
Inventor 王恒王新媛朱玲李增成杨裕倩潘克菲姜锴
Owner NUOVO FILM SUZHOU CHINA INC
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