Preparation method of three-dimensional graphene-nanowire hybrid aerogel
A technology of graphene and airgel, which is applied in the field of preparation of three-dimensional graphene composite airgel, can solve the problems of large contact thermal resistance, poor thermal conductivity, and inapplicability, and achieve low contact resistance, low contact thermal resistance, tight connection effect
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Embodiment 1
[0039] A preparation method of a three-dimensional graphene-nanowire hybrid airgel, specifically:
[0040] 1) Ultrasonic dispersion of graphene oxide (GO) and silicon dioxide nanopowder (300nm particle size) in an aqueous solution to obtain a mixed and dispersed aqueous solution of graphene oxide. The mass concentration of graphene oxide is 6g / L, and graphene oxide (GO ), the mass ratio of silica nanopowder is 1:6;
[0041] 2) Then add ammonia water with a concentration of 25% to the prepared graphene oxide / silicon dioxide mixed dispersion solution, and the volume ratio of the added ammonia water to the graphene oxide mixed dispersion solution volume ratio is 1:60.
[0042] 3) Pour the mixed solution formed in 2) into a container, inject ethanol into the container, make it fully mix with the mixed solution formed in 2), and let it stand for 5 hours to obtain graphene oxide hydrogel and organic solvent mixture. Ethanol is removed by evaporation to obtain graphene oxide hydrog...
Embodiment 2
[0050] A preparation method of a three-dimensional graphene-nanowire hybrid airgel, specifically:
[0051] 1) Ultrasonic disperse graphene oxide (GO), carbon nanotubes, and silica nanopowder (300nm particle size) in an aqueous solution to obtain a mixed and dispersed aqueous solution of graphene oxide. The mass concentration of graphene oxide is 6g / L. The mass ratio of graphene (GO) to silica nanopowder is 1:4, and the mass ratio of carbon nanotubes to graphene oxide is 1:100;
[0052] 2) Then add ammonia water with a concentration of 25% to the prepared graphene oxide / silicon dioxide mixed dispersion solution, and the volume ratio of the added ammonia water to the graphene oxide mixed dispersion solution volume ratio is 1:60.
[0053] 3) Pour the mixed solution formed in 2) into a container, inject ethanol into the container, make it fully mix with the mixed solution formed in 2), and let it stand for 5 hours to obtain graphene oxide hydrogel and organic solvent mixture. Et...
Embodiment 3
[0061] A preparation method of a three-dimensional graphene-nanowire hybrid airgel, specifically:
[0062] 1) Ultrasonic dispersion of graphene oxide (GO), carbon nanotubes, and silicon dioxide nanopowder (300nm particle size) in an aqueous solution to obtain a mixed and dispersed aqueous solution of graphene oxide. The mass concentration of graphene oxide is 6g / L, two The mass ratio of silicon oxide nanopowder is 1:20, and the mass ratio of carbon inner nanotubes to graphene oxide is 1:10;
[0063] 2) Then add ammonia water with a concentration of 25% to the prepared graphene oxide / carbon nanotube / silicon dioxide mixed dispersion aqueous solution, the volume ratio of the added ammonia water to the graphene oxide mixed dispersion aqueous solution is 1:60.
[0064] 3) Pour the mixed solution formed in 2) into a container, inject ethanol into the container, make it fully mix with the mixed solution formed in 2), and let it stand for 5 hours to obtain the graphene oxide-carbon na...
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