Dry Homogenization Process of Lithium Iron Phosphate Start-Stop Battery Cathode Slurry and Prepared Slurry

A technology of lithium iron phosphate and battery cathode, which is applied in the field of dry homogenization of cathode slurry of lithium iron phosphate start-stop battery, can solve the problems of affecting the safety performance of the battery, prolonging the stirring time in the high-speed dispersing stage, and having many particles, and achieves a high level of improvement. Rate charge-discharge performance and service life, avoid the stirring paddle rubbing against the cylinder, and increase the effect of the contact area

Active Publication Date: 2022-03-18
CAMEL GRP NEW ENERGY BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the case of using a conventional mixer and ensuring the amount of feeding, the current dry pulping process of lithium iron phosphate cathode slurry has the following problems in the manufacturing process: 1. Kneading with high solid content causes scratches between the stirring paddle and the cylinder wall; 2. Low solid content Content kneading causes uneven dispersion of materials, many particles, and cannot be coated in the subsequent process; 3. Low solid content kneading takes a long time and the effect is not good, resulting in prolonged stirring time in the high-speed dispersion stage
The above problems will lead to the following results: 1. Metal impurities are introduced into the slurry, which affects the safety performance of the battery; 2. The material is not uniformly dispersed, and particle agglomeration will affect the coating production efficiency, and in severe cases, affect the charge and discharge performance of the battery rate; 3. Stirring Long time seriously affects production efficiency and increases manufacturing cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A dry homogenization process for positive electrode slurry of lithium iron phosphate start-stop battery. The dry powder feeding amount accounts for 60% of the effective volume of the mixer. The specific process is as follows:

[0023] S1. Dry mixing stage: according to the formula requirements of lithium iron phosphate start-stop battery, put the dry powder (lithium iron phosphate, PVDF, conductive agent) into the mixing tank with circulating water cooling function at one time, the revolution speed is 10rpm, the dispersion speed is 100rpm, and stir The time is 15 minutes, set the mixer alarm shutdown current 110A, delay time 1″ before starting the mixing, and control the temperature of the mixing process at 40-50°C;

[0024] S2. Wetting stage: add conductive paste to the dry powder mixed in the above step S1, add the conductive paste in 4 times, the revolution speed is 15rpm, the dispersion speed is 300rpm, the stirring time is 5min each time, and the temperature during ...

Embodiment 2

[0029] A dry homogenization process for the positive electrode slurry of lithium iron phosphate start-stop battery. The dry powder feeding amount accounts for 75% of the effective volume of the mixer. The specific mixing process is as follows:

[0030] S1. Dry mixing stage: According to the formula requirements of lithium iron phosphate start-stop battery, put the dry powder into the mixing tank with circulating water cooling function at one time, the revolution speed is 15rpm, the dispersion speed is 200rpm, and the mixing time is 15min. Before starting the mixing, set the mixer to alarm and stop The current is 100A, the delay time is 1", and the temperature during the stirring process is controlled at 40-50°C;

[0031] S2. Wetting stage: Add the conductive paste to the dry powder mixed in the above step S1, add the conductive paste in 5 times, the revolution speed is 20rpm, the dispersion speed is 400rpm, the stirring time is 5min each time, and the temperature during the sti...

Embodiment 3

[0036] A dry homogenization process for positive electrode slurry of lithium iron phosphate start-stop battery. The dry powder feeding amount accounts for 90% of the effective volume of the mixer. The specific mixing process is as follows:

[0037] S1. Dry mixing stage: According to the formula requirements of lithium iron phosphate start-stop battery, put the dry powder into the mixing tank with circulating water cooling function at one time, the revolution speed is 15rpm, the dispersion speed is 300rpm, and the mixing time is 15min. Before starting the mixing, set the mixer to alarm and stop The current is 90A, the delay time is 1", and the temperature during the stirring process is controlled at 40-50°C;

[0038] S2. Wetting stage: add conductive paste to the dry powder mixed in the above step S1, add the conductive paste in 6 times, the revolution speed is 25rpm, the dispersion speed is 500rpm, the stirring time is 5min each time, and the temperature during the stirring pro...

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PUM

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Abstract

A dry homogenization process for positive electrode slurry of lithium iron phosphate start-stop battery and the prepared slurry, including: S1) putting the dry powder into the mixing tank, and controlling the temperature during the stirring process; S2) wetting stage: mixing to step S1) Add conductive paste to the dry powder, put the conductive paste in 4-6 times; S3) kneading stage: after the last feeding of the conductive paste, add solvent to adjust the solid content of the paste in the mixing tank to 66%-68% Carry out kneading, and gradually increase the revolution speed and dispersion speed; S4) The solvent is added to the mixing tank at one time, and the stirring is continued. The invention improves the particle agglomeration of the slurry and reduces the fineness of the slurry; the slurry kneaded under the condition of high solid content is beneficial to disperse the material evenly under the action of high shear force, so that the high-rate battery can be charged and discharged More uniform, thereby greatly improving the rate charge and discharge performance and service life of the battery. In addition, the invention shortens the homogenization cycle to 4.5-5.5h.

Description

technical field [0001] The invention relates to the technical field of lithium batteries, in particular to a dry homogenization process for positive electrode slurry of lithium iron phosphate start-stop batteries. Background technique [0002] Although lithium batteries have defects such as cost, grouping, and safety performance in the field of starting batteries, as the start-stop technology has gradually become popular, lithium start-stop batteries are an important component of automobiles, and lithium iron phosphate system start-stop batteries are becoming more and more popular in light weight, It has outstanding advantages in service life, charging and discharging, and safety performance. [0003] As the first process of lithium battery manufacturing, the pulping process of battery positive electrode slurry is the top priority of the entire lithium battery manufacturing process. In the case of using a conventional mixer and ensuring the amount of feeding, the current dr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/04H01M4/58H01M4/62H01M10/052B01F33/82B01F23/53
CPCH01M4/04H01M4/625H01M4/5825H01M10/052B01F23/51B01F23/59B01F23/53B01F33/82Y02E60/10
Inventor 齐明阳刘琳张宝华王海强
Owner CAMEL GRP NEW ENERGY BATTERY CO LTD
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