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Heteropolyacid air bactericide as well as preparation method and application thereof

A technology of heteropolyacid and bactericide, which is applied in the field of heteropolyacid air bactericide and its preparation, can solve the problems of negative ion air sterilizing effect not obvious, human respiratory system damage, large amount of ozone, etc., and achieve high catalytic ability and selectivity Good stability, guaranteed stability, and good thermal stability

Inactive Publication Date: 2021-04-20
安徽稞馨环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Existing air sterilization technologies have certain deficiencies in use: for example, [China Invention] CN201810776498.9 discloses an air sterilization device for intensive care units, which uses negative ions to sterilize air, but the effect of negative ion air sterilization is not obvious, and negative ions are The residence time in the air is short, and it only stays for a few seconds in places with a lot of dust, and negative ions are generated by high-voltage discharge, which often produces a large amount of ozone at the same time, causing damage to the human respiratory system; [Chinese Invention] CN202010382776.X discloses a A photocatalyst air sterilization disinfectant and its application, the photocatalyst air sterilization mainly uses ultraviolet light to irradiate the photocatalyst to produce effects, and ultraviolet rays are harmful to the human body; [Chinese invention] CN201910329921.5 discloses an air sterilization purifier, which uses activated carbon The adsorption principle carries out the sterilization process, but the activated carbon can only adsorb temporarily, and as the temperature and wind speed increase, the adsorbed pollutants may be freed, so the filter material should be replaced frequently to avoid adsorption saturation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A heteropoly acid air bactericide, comprising the following raw materials in parts by weight: 1 part of N,N-dimethylformamide, 1.5 parts of propionic acid, 2.5 parts of phosphotungstic acid, 3 parts of silane coupling agent, 10 parts of di Chlorine oxide, 30 parts of water.

[0029] A preparation method of heteropolyacid air bactericide, comprising the following steps:

[0030] (A) After mixing N,N-dimethylformamide and propionic acid in proportion, add water in proportion and stir to dissolve it completely to obtain a mixed solution; the stirring time is 30min, the stirring speed is 800rpm, and the temperature is 45- 65°C.

[0031] (B) Under the protection of inert gas, add phosphotungstic acid and silane coupling agent in proportion to the mixed solution obtained in step (A), then pour it into the reaction tank for reaction, and stir; the reaction time is 0.5h, and the reaction temperature is 100°C, during the reaction process, a pH regulator should be used to contr...

Embodiment 2

[0034] A kind of heteropolyacid air sterilizer, comprises the raw material of following parts by weight: 5 parts of N,N-dimethylformamide, 5 parts of propionic acid, 3 parts of phosphomolybdic acid, 10 parts of silane coupling agent, 30 parts of di Chlorine oxide, 45 parts of water.

[0035] A preparation method of heteropolyacid air bactericide, comprising the following steps:

[0036] (A) After mixing N,N-dimethylformamide and propionic acid in proportion, add water in proportion, stir to dissolve it completely, and obtain a mixed solution; the stirring time is 60min, the stirring speed is 2000rpm, and the temperature is 45- 65°C.

[0037] (B) Under the protection of an inert gas, add phosphomolybdic acid and a silane coupling agent in proportion to the mixed solution obtained in step (A), then pour it into a reaction tank for reaction, and stir; the reaction time is 1h, and the reaction temperature is 255 ℃, in the reaction process, a pH regulator needs to be used to cont...

Embodiment 3

[0040] A kind of heteropolyacid air sterilizer, comprises the raw material of following parts by weight: 3 parts of N, N-dimethylformamide, 3.25 parts of propionic acid, 2.75 parts of silicotungstic acid, silicon molybdenum acid silicon (tungstic acid and silicon molybdenum The addition ratio of acid is 1:1), 6.5 parts of silane coupling agent, 20 parts of chlorine dioxide, and 37.5 parts of water.

[0041] A preparation method of heteropolyacid air bactericide, comprising the following steps:

[0042] (A) After mixing N,N-dimethylformamide and propionic acid in proportion, add water in proportion and stir to dissolve it completely to obtain a mixed solution; the stirring time is 45min, the stirring speed is 1400rpm, and the temperature is 45- 65°C.

[0043] (B) Under the protection of inert gas, add silicotungstic acid, silicomolybdic acid and silane coupling agent in proportion to the mixed solution obtained in step (A), then pour it into the reaction tank for reaction, and...

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PUM

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Abstract

The invention relates to the technical field of disinfectants, in particular to a heteropolyacid air bactericide as well as a preparation method and application thereof. The heteropolyacid air bactericide provided by the invention is prepared from the following raw materials in parts by weight: 1-5 parts of N, N-dimethylformamide, 1.5-5 parts of propionic acid, 2.5-3 parts of heteropolyacid, 3-10 parts of a coupling agent, 10-30 parts of chlorine dioxide and 30-45 parts of water. The heteropolyacid air bactericide has the following beneficial effects: (1) the catalytic performance is controllable, and the catalyst design is facilitated; (2) the heteropolyacid air bactericide is easily soluble in water and an organic solvent, can be loaded on substances such as silica gel or activated carbon, shows very high catalytic ability and selectivity, and can be used for homogeneous and heterogeneous catalytic reaction systems; (3) the stability is better, and the continuous and efficient sterilization can be realized; and (4) safety and greenness are achieved, and the bactericidal effective components are harmless to human bodies.

Description

technical field [0001] The invention relates to the technical field of disinfectants, in particular to a heteropolyacid air sterilant and its preparation method and application. Background technique [0002] Air is an important transmission route for microorganisms such as bacteria and viruses. In our work and living places, we are always facing the dangers of bacteria and viruses in the air. The new coronavirus that has ravaged the world this year is an example of airborne viruses. Therefore, in order to effectively avoid the spread of related diseases, it is necessary to effectively kill microorganisms such as bacteria and viruses in the air. [0003] Existing air sterilization technologies have certain deficiencies in use: for example, [China Invention] CN201810776498.9 discloses an air sterilization device for intensive care units, which uses negative ions to sterilize air, but the effect of negative ion air sterilization is not obvious, and negative ions are The reside...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N59/00A01N25/22A01N25/06A01P1/00
Inventor 周泽安安胜欣李文志
Owner 安徽稞馨环境科技有限公司