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Sodium ion conductor and solid-state sodium-ion battery

A sodium ion and conductor technology, applied in the field of sodium ion conductors and sodium ion solid batteries, can solve problems such as soaring raw material prices

Pending Publication Date: 2021-05-07
TOYOTA JIDOSHA KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] But fears of surging raw material prices for lithium

Method used

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  • Sodium ion conductor and solid-state sodium-ion battery
  • Sodium ion conductor and solid-state sodium-ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0074] The sodium ion conductor of the present disclosure will be described below using examples.

[0075] NaCB 9 h 10 (manufactured by Katchem), NaCB 11 h 12 (manufactured by Katchem) and NaF (manufactured by High Purity Chemical Research Institute) were vacuum-dried overnight at 160°C, and each case was weighed at the ratio of mol% shown in Table 1, and put into a 45mL ball mill jar (ZrO 2 system). In this ball mill jar further put 20 ZrO 2 The prepared spheres (diameter 5 mm) were mixed at 500 rpm for 20 hours and ball milled. Thus, a sodium ion conductor was obtained.

[0076] [Table 1]

[0077] NaCB 9 h 10

NaCB 11 h 12

NaF Comparative example 1 0 0 100 Example 1 21 9 70 Example 2 35 15 50 Example 3 49 21 30 Example 4 63 27 10 Reference example 70 30 0 Comparative example 2 50 50 0

[0078] Unit: mol%

[0079] [Evaluation of conductivity of sodium ions]

[0080] The sodium ion...

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Abstract

The invention relates to a sodium ion conductor and a solid-state sodium-ion battery. Provided is a sodium ion conductor whose sodium ion conductivity is improved more than the conventional. The sodium ion conductor is a molecular crystal constituted of NaCB9H10, NaCB11H12, and a sodium halide, the sodium halide having a mol fraction of more than 0 and at most 70 on the basis of the total mol ratio of NaCB9H10, NaCB11H12, and the sodium halide.

Description

technical field [0001] The present application relates to sodium ion conductors and sodium ion solid batteries. Background technique [0002] Lithium-ion secondary batteries are used as power sources for mobile devices and vehicles, taking advantage of their high capacity and light weight. As an electrolyte, the use of a solid solid electrolyte instead of a liquid electrolyte is also being studied. [0003] However, there are fears that the price of raw materials for lithium will soar. Therefore, a sodium-ion solid battery using sodium, which is abundant in resources, has attracted attention as a lithium-substituting material. For sodium ion solid batteries, a sodium ion conductor having sodium ion conductivity is required. [0004] In non-patent literature 1, it is disclosed that NaCB 9 h 10 with NaCB 11 h 12 A sodium ion conductor obtained by mixing. [0005] prior art literature [0006] non-patent literature [0007] Non-Patent Document 1: Wan Si Tang et al., "...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0562H01M10/054H01M10/42
CPCH01M10/0562H01M10/054H01M10/4235H01M2300/0091H01M2300/008H01M2300/0068Y02E60/10H01M10/3918
Inventor 穗积正人后田伸二井谷启太桑田纮子
Owner TOYOTA JIDOSHA KK
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