A kind of water-based epoxy ester modified acrylate emulsion for woodware and its preparation method
A technology of acrylate and epoxy ester, applied in the direction of coating, etc., can solve the problem of slow drying of water-based wood paint, achieve the effect of reducing VOC, reducing viscosity, and preventing yellowing
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Embodiment 1
[0059] A preparation method for water-based epoxy ester modified acrylate emulsion on woodware, comprising the following steps:
[0060] (1) Preparation of waterborne epoxy ester dispersion
[0061] Add E-20 epoxy resin, ricinoleic acid and stearic acid into the reactor and heat to form a homogeneous phase, add 1% lithium neodecanoate accounting for the total amount of reactants in the previous step, and react at 180°C until the acid value When it is less than 1mgKOH / g, add butyl acrylate accounting for 20% of the total amount of reactants in the previous step, adjust the temperature to 120°C, add succinic anhydride, react for 2h, cool down to 60-65°C, and add to triethylamine and 30min, add water to disperse for 2h, and adjust the solid content to 40% to obtain a water-based epoxy ester dispersion;
[0062] The total molar ratio of E-20 to ricinoleic acid and stearic acid is 1:2, the molar ratio of ricinoleic acid to stearic acid is 1:3, the molar ratio of E-20 to succinic a...
Embodiment 2
[0068] A preparation method for water-based epoxy ester modified acrylate emulsion on woodware, comprising the following steps:
[0069] (1) Preparation of water-based epoxy ester dispersion
[0070] Add E-44 epoxy resin, 2-hydroxypropionic acid and stearic acid into the reactor and heat to form a homogeneous phase, add 0.8% of tetrabutylammonium bromide accounting for the total amount of reactants in the previous step, at 100 ° C React until the acid value is less than 1mgKOH / g, add butyl acrylate accounting for 10% of the total amount of reactants in the previous step, adjust the temperature to 80°C, add maleic anhydride, react for 2 hours, cool down to 60-65°C, add N,N-Dimethylethanolamine reacted for 30 minutes, added water to disperse for 2 hours, and adjusted the solid content to 40% to obtain a water-based epoxy ester dispersion;
[0071] The total molar ratio of E-44 to 2-hydroxypropionic acid and stearic acid is 1:2; the molar ratio of stearic acid to 2-hydroxypropio...
Embodiment 3
[0077] A preparation method for water-based epoxy ester modified acrylate emulsion on woodware, comprising the following steps:
[0078] (1) Preparation of water-based epoxy ester dispersion
[0079] Add E-44 epoxy resin, ricinoleic acid and abietic acid into the reactor and heat to form a homogeneous phase, add 0.8% lithium neodecanoate accounting for the total amount of reactants in the previous step, and react at 180°C until the acid value is less than 1mgKOH / g, add butyl acrylate accounting for 12% of the total amount of reactants in the previous step, adjust the temperature to 120°C, add succinic anhydride, react for 2h, cool down to 60-65°C, add triethylamine to react for 30min, add water to disperse 2h, adjust the solid content to 35% to obtain the aqueous epoxy ester dispersion;
[0080] The molar ratio of E-44 to ricinoleic acid and abietic acid is 1:2; the molar ratio of abietic acid to ricinoleic acid is 1:1, the molar ratio of E-44 to succinic anhydride is 1:1, tr...
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Abstract
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