Microcapsule and preparation method thereof, electrolyte and preparation method thereof and battery

A technology of microcapsules and electrolytes, applied in microcapsule preparations, non-aqueous electrolyte batteries, electrolyte battery manufacturing, etc., can solve the problems of negative impact of battery SEI film, increase electrolyte viscosity, reduce electrolyte activity, etc.

Inactive Publication Date: 2021-06-25
KUNSHAN BAOTRON NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Existing lithium-ion batteries add flame-retardant additives and high-temperature-resistant additives to their electrolytes to prevent lithium-ion batteries from smoking at high temperatures, or even catching fire and exploding. This type of additives in the electrolyte increases the viscosity of the electrolyte and reduces the electrolysis The activity of the liquid, on the other hand, will have a greater negative impact on the formation of the battery SEI film

Method used

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  • Microcapsule and preparation method thereof, electrolyte and preparation method thereof and battery
  • Microcapsule and preparation method thereof, electrolyte and preparation method thereof and battery
  • Microcapsule and preparation method thereof, electrolyte and preparation method thereof and battery

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preparation example Construction

[0061] The present application provides a method for preparing microcapsules, which includes: mixing a first material and a first solvent to obtain a first mixed solution, mixing the first mixed solution with a second material to obtain a second mixed solution, and mixing the second mixed solution Mixing with the second solvent to obtain the third mixed liquid, drying the third mixed liquid to obtain microcapsules.

[0062] Wherein, the first solvent is a good solvent for the first material, and the second solvent is a poor solvent for the first material.

[0063] The microcapsules of the present application are prepared by coacervation phase separation. In the second mixed solution, the first material is the continuous phase, and the second material is the dispersed phase. After the second mixed solution is mixed with the second solvent, at this time, due to the first solvent to The solubility of the first material changes, and the continuous phase separation of the first mat...

Embodiment 1

[0096] The embodiment of the present application provides a kind of microcapsule and preparation method thereof, it comprises:

[0097] At room temperature 25°C, dissolve polyethylene powder in toluene to obtain a polyethylene toluene solution. The mass volume ratio of polyethylene to toluene is 40g:350mL, and then add methylphenyl silicone resin to the polyethylene toluene solution. , stir evenly to obtain polyethylene as the continuous phase, methylphenyl silicone resin as the second mixed solution of the dispersed phase, the mass volume ratio of methylphenyl silicone resin and toluene is 8g: 350mL, and then add to the second mixed solution Acetone was added to obtain a third mixed solution, the volume ratio of acetone to toluene was 130mL:350mL, and finally the third mixed solution was dried at 90° C. for 11 h to obtain dry microcapsule powder.

Embodiment 2

[0099] The embodiment of the present application provides a kind of microcapsule and preparation method thereof, it comprises:

[0100] At room temperature 25°C, dissolve polyethylene powder in toluene to obtain a polyethylene toluene solution. The mass volume ratio of polyethylene to toluene is 30g:200mL, and then add methylphenyl silicone resin to the polyethylene toluene solution. , and stir evenly to obtain polyethylene as the continuous phase, and methylphenyl silicone resin as the second mixed solution of the dispersed phase. The mass volume ratio of methylphenyl silicone resin and toluene is 5g:200mL, and then add to the second mixed solution Acetone was added to obtain a third mixed solution, the volume ratio of acetone to toluene was 80mL:200mL, and finally the third mixed solution was dried at 80° C. for 12 hours to obtain dry microcapsule powder.

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Abstract

The invention provides a microcapsule and a preparation method thereof, an electrolyte and a preparation method thereof and a battery, and belongs to the technical field of batteries. The microcapsule comprises a capsule wall and a capsule core. The capsule wall is made of a first material. The capsule core is made of a second material, and the second material comprises silicon resin with flame retardance. The capsule wall covers the capsule core below a target temperature, the capsule wall is broken above the target temperature and releases the capsule core, and the first material is not dissolved in the electrolyte at least below the target temperature. The microcapsule is dispersed in the electrolyte of the battery, so that the electrical property of the battery is basically not influenced. When the temperature of the battery is higher than the target temperature, the capsule wall of the microcapsule is softened and broken, the microcapsule can release the capsule core of the microcapsule, and the silicon resin with flame retardance forms a diffusion shielding layer to prevent vaporized organic matters generated by high-temperature thermal decomposition of an internal high polymer material from diffusing to a combustion area. Meanwhile, the silicon resin has a very good heat insulation effect, heat transfer in the combustion process can be blocked to prevent continuous reaction, and then the high-temperature safety performance of the battery is improved.

Description

technical field [0001] The present application relates to the field of battery technology, in particular, to a microcapsule and a preparation method thereof, an electrolyte and a preparation method thereof, and a battery. Background technique [0002] Due to its high voltage, energy density and good cycle performance, lithium-ion batteries are increasingly used in energy storage systems such as electric vehicles. [0003] The working efficiency of lithium-ion batteries is greatly affected by temperature, and its performance will be in an optimal state only within a suitable temperature range. Lithium-ion batteries will generate a certain amount of heat during charging and discharging, and the temperature of the battery itself will change during charging and discharging, which is mainly manifested as a temperature rise, especially in the case of high current and high power operation. . [0004] Existing lithium-ion batteries add flame-retardant additives and high-temperatur...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/058H01M10/0525H01M10/42B01J13/02A62C35/10A62C3/16
CPCA62C3/16A62C35/10B01J13/02H01M10/0525H01M10/0567H01M10/058H01M10/4235Y02E60/10Y02P70/50
Inventor 何欢吕豪杰褚林波齐士博平丽娜
Owner KUNSHAN BAOTRON NEW ENERGY TECH CO LTD
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