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A kind of formaldehyde removal catalyst and preparation method thereof

A catalyst and formaldehyde technology, applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems such as difficulty in meeting the requirements of rapid purification of formaldehyde, complicated preparation process, unfavorable cost saving, etc. Decomposition efficiency and stability, and the effect of degradation intermediate product accumulation and inhibition of intermediate product accumulation

Active Publication Date: 2022-06-21
NINGBO FOTILE KITCHEN WARE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent is the first to prepare MnO modified by alkali metal or rare earth metal 2 carrier, and then Pt is loaded on the carrier to catalyze the degradation of formaldehyde; the preparation process of this two-step method is complicated, which is not conducive to saving costs, and the test space velocity is still small, which is difficult to meet the actual indoor rapid purification of formaldehyde requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] In this example, nano-alumina (Sinopharm Group Chemical Reagent Co., Ltd.) is used as the carrier, Pt is used as the active component, and the Pt source is selected from diethanolammonium hexahydroxyplatinate (Sinopharm Group Chemical Reagent Co., Ltd.), magnesium nitrate (Sinopharm Group Chemical Reagent Co., Ltd.), magnesium nitrate (Sinopharm Group Chemical Reagent Co., Ltd.) Chemical Reagent Co., Ltd.) as the Mg source, with a Pt loading of 0.5% and a Mg loading of 2% to obtain Pt-Mg / Al 2 O 3 catalyst. The loading refers to the weight of the carrier nano-alumina.

[0024] The preparation method of the formaldehyde-removing catalyst of the present embodiment comprises the following steps:

[0025] (1) prepare Mg source solution: dissolve magnesium nitrate hexahydrate in deionized water; of course, anhydrous magnesium nitrate can also be used;

[0026] (2) Disperse the nano-alumina carrier in the Mg source solution, stir for 30min, and disperse the nano-alumina car...

Embodiment 2

[0030] In this example, nano-alumina is used as the carrier, Pt is used as the active component, diethanolammonium hexahydroxyplatinate is selected as the Pt source, and magnesium nitrate is used as the Mg source, the Pt loading is 0.1%, and the Mg loading is 2%. Pt-Mg / Al 2 O 3 catalyst. Refer to Example 1 for specific preparation steps.

Embodiment 3

[0032] In this example, nano-alumina is used as the carrier, Pt is used as the active component, diethanolammonium hexahydroxyplatinate is used as the Pt source, and magnesium nitrate is used as the Mg source, the Pt loading is 1%, and the Mg loading is 2%. Pt-Mg / Al 2 O 3 catalyst. Refer to Example 1 for specific preparation steps.

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PUM

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Abstract

The invention relates to a formaldehyde removal catalyst and a preparation method thereof, wherein the general formula of the formaldehyde removal catalyst is A-Mg / Al 2 o 3 ; Wherein A is one of Pt, Pd, Au, Al 2 o 3 As a carrier, the loading amount of A is Al 2 o 3 0.1~1% of the carrier weight, Mg loading is Al 2 o 3 0.1% to 5% of the weight of the carrier. The catalyst of the present invention includes Mg as an auxiliary agent, and the synergistic effect of Mg is as follows: on the one hand, the addition of an appropriate amount of Mg can improve the dispersion of noble metals through the electrostatic force of anions and cations, and significantly improve the ability to activate oxygen, thereby improving the efficiency of catalytic oxidation of formaldehyde; On the one hand, the addition of an appropriate amount of Mg is beneficial to reduce the Al 2 o 3 The strong acid site of the carrier is conducive to the activation of lattice oxygen, which is beneficial to inhibit and degrade the accumulation of intermediate products, improve the decomposition efficiency and stability, and can adapt to a higher space velocity environment.

Description

technical field [0001] The invention belongs to the technical field of catalytic materials, and in particular relates to a formaldehyde-removing catalyst and a preparation method thereof. Background technique [0002] Formaldehyde is the main indoor air pollutant, which has serious harm to the human body. The main harm of formaldehyde is the irritation to the skin and mucous membranes. When formaldehyde reaches a certain concentration indoors, people will feel uncomfortable, more than 0.08mg / m 3 High formaldehyde concentration can cause eye redness, itching, throat discomfort or pain, hoarseness, sneezing, chest tightness, asthma, dermatitis, etc. At present, one of the more feasible methods for the removal of indoor formaldehyde pollutants is to oxidize formaldehyde and CO to CO through room temperature catalytic oxidation. 2 , thereby removing contaminants. [0003] The room temperature catalytic oxidation of formaldehyde decomposition mechanism is that formaldehyde is ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/42B01J23/44B01J23/52B01J37/02B01D53/72B01D53/86
CPCB01J23/58B01J23/52B01J23/66B01J37/0201B01J37/0205B01D53/8668B01D2258/06B01D2257/708B01J35/394
Inventor 韩晨阳汪鹤郭国良王原原霍彦强郑军妹
Owner NINGBO FOTILE KITCHEN WARE CO LTD