Method for synergistically preparing glass body from hazardous waste incineration ash residues and for decarburizing

A technology for hazardous waste and incineration of ash and slag, which is applied in the removal of solid waste, glass production, chemical instruments and methods, etc., can solve the problems of high cost of iron oxide scale, increased ash melting treatment cost, and increased treatment cost.

Active Publication Date: 2021-07-16
EVERBRIGHT ENVIRONMENTAL PROTECTION TECH RES INST SHENZHEN CO LTD +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Invention patent (publication number CN 106224979 A) discloses a method for resource utilization of hazardous waste incineration bottom slag. The method is to mix SiO 2 、Al 2 o 3 Clay, fly ash, zeolite, etc. as the main components are used as auxiliary materials to form a mixture, which is melted in an electric arc furnace to obtain highly inert slag; however, the auxiliary materials used need to be purchased and shipped outside, further increasing the processing cost of bottom slag melting
Invention patent (publication number CN 108545933 A) discloses a method for preparing a glass body from incineration ash of hazardou

Method used

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  • Method for synergistically preparing glass body from hazardous waste incineration ash residues and for decarburizing
  • Method for synergistically preparing glass body from hazardous waste incineration ash residues and for decarburizing
  • Method for synergistically preparing glass body from hazardous waste incineration ash residues and for decarburizing

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0056] Example 1 II Slag with flying gray

[0057] For the sage and flying ash of 1 # dangerous abines, the amount of carbon content and chemical composition is analyzed. The main components of the base residue are shown in Table 1 below, and the carbon content in the base residue is 0.8%, and there is no need to add CACO. 3 As a de-carbon, according to the grades, fly ash CAO, SIO 2 , Al 2 O 3 The component content is recorded in Table 1.

[0058] Table 1 Example 1 Main component content of the flying ash in Example 1 / %

[0059]

[0060] 1 # Stock on the ratio of the ratio of calcium oxide and silica and alumina y = cao / (SiO 2 + Al 2 O 3 = 0.24, belongs to I: I need to add flying ash to 1 # onseeing, which is now taking 100 sub-grades, 40 parts of fly ash mix. The slag and fly ash's matching is to make Y = CaO / (SiO in the mixture 2 + Al 2 O 3 = 0.51, in the range of 0.3-0.75. The formulated mixture is put into the plasma oven, the plasma furnace is warmed to 1400 ° C, and ...

Example Embodiment

[0062] Example 2 Add a decarbonate Caco 3 The subsequent type III slag, and then prepared a glass body with type I

[0063] Carbon content and chemical composition analysis of 2 # dangerous abines factory, the main components of the dregs are shown in Table 2: the original bulk is a class II residue, the residue is 6.9%, and CaCo is added. 3 As a de-carbon;

[0064] Table 2 Substand, fly ash, main component content / %

[0065]

[0066] When the slag is 100, Caco 3 Add amount M = 100 × m1 × W1 / 12 = 100 × 100 × 6.9% / 12 = 57.5 copies, add CACO 3 The composition of rear grades (named: 2-1 # on a slag) is shown in Table 3.

[0067] Table 3 2-1 # Main ingredient content / %

[0068]

[0069] 2-1 # = Y = CAO / (SIO 2 + Al 2 O 3 ) = 1.06, belongs to III slag. According to 2-1 # onseng, 1 # on the slag CAO, SIO 2 , Al 2 O 3 The component content, 100 parts of 2-1 # on a dreg, 50 parts of 1 # underlying, Y = CaO / (SIO) in the mixture 2 + Al 2 O 3 = 0.4, in the range of 0.3-0.75. The...

Example Embodiment

[0072] Example 3 Adding Decarbon Caco 3 After II Slag, melt-prepared glass body

[0073]Carbon content and chemical composition analysis of the grades of the 3 # dangerous abutting plant, the main component content of the dregs is shown in Table 4: 2.4% carbon content in the gravel is 2.4%, which needs to be added to CaCO. 3 As a de-carbon.

[0074] Table 4 Main ingredient content / % of the substrate in Example 3

[0075]

[0076] When the slag is 100, Caco 3 Add amount m = 100 × m1 × W1 / 12 = 100 × 100 × 2.4% / 12 = 20 copies, add CACO 3 The composition of the rear graded (named: 3-1 # on a slag) is shown in Table 5.

[0077] Table 5 3-1 # Main ingredient content / %

[0078]

[0079] 3-1 # 渣 Y = CAO / (SIO 2 + Al 2 O 3 ) = 0.4, belongs to II slag. Directly put the type II residue into the plasma oven, the plasma furnace is warmed to 1450 ° C, and the mixture is all melted in the furnace mixture, and the slag melting time is 30 min. The slag is measured by a portable temperat...

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Abstract

The invention discloses a method for synergistically preparing a glass body from hazardous waste incineration ash residues and for decarburizing. The method comprises the following specific steps that the content of residual carbon in hazardous waste bottom slag is measured, and if the content of the residual carbon is greater than or equal to 1%, and CaCO3 is added into the bottom slag; chemical components of the hazardous waste bottom slag are detected, and the bottom slag is divided into three types according to the ratio of calcium oxide to the sum of silicon oxide and aluminum oxide in the hazardous waste bottom slag; different types of bottom slag as well as the bottom slag and fly ash are synergistically blended, and it is guaranteed that the ratio of the calcium oxide to the sum of the silicon oxide and the aluminum oxide is within 0.3-0.75; and the mixture is added into a plasma furnace for melting and heat preservation, the molten slag flows out of a slag discharging outlet, and the glass body is obtained after water quenching and cooling. Through compounding of the bottom slag, different waste materials are synergistically used for preparing the glass body, the effects of treating waste with waste and co-treating are achieved, and the treatment cost is reduced. Meanwhile, calcium carbonate is used as the decarburizing agent to remove the carbon in the bottom slag, and the residual carbon content in the glass body is reduced.

Description

technical field [0001] The invention belongs to the technical field of reuse of hazardous waste incineration bottom slag and fly ash, and in particular relates to a method for synergistically preparing glass body and decarbonization from hazardous waste incineration ash. Background technique [0002] According to the China Statistical Yearbook, in 2017 my country produced 69.3689 million tons of hazardous waste, and the disposal volume reached 25.5156 million tons, of which about 50% were incinerated, and the amount of hazardous waste incineration bottom slag generated was about 2.55 million tons. The "National Hazardous Waste List" (2016 edition) stipulates that the bottom slag produced in the process of hazardous waste incineration, pyrolysis, etc. is still hazardous waste (waste category HW18, waste code 772-003-18). For the final disposal of incineration bottom slag in my country, the method of safe landfill is mainly used. A large amount of bottom slag has caused increa...

Claims

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Application Information

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IPC IPC(8): B09B3/00C03C1/00
CPCC03C1/002B09B3/29Y02P40/50
Inventor 胡明虎训宗肖李小明齐景伟宫臣徐鹏程周飞飞张亮王婷婷赵彬肖诚斌
Owner EVERBRIGHT ENVIRONMENTAL PROTECTION TECH RES INST SHENZHEN CO LTD
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