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High-wear-resistance composite resin for denture matrix, and preparation method thereof

A composite resin and matrix technology, applied in the field of stomatology, can solve the problems of poor wear resistance of denture matrix

Active Publication Date: 2021-07-30
深圳市一诺牙科技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to solve the problems in the above-mentioned prior art, to provide a high wear-resistant composite resin for denture matrix and its preparation method, and to prepare a high-uniformity wear-resistant composite resin by modifying inorganic nanoparticles, effectively solving the problem of denture Problems caused by poor wear resistance of the substrate

Method used

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  • High-wear-resistance composite resin for denture matrix, and preparation method thereof
  • High-wear-resistance composite resin for denture matrix, and preparation method thereof
  • High-wear-resistance composite resin for denture matrix, and preparation method thereof

Examples

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Effect test

Embodiment 1

[0030] A high wear-resistant composite resin for a denture base, comprising the following raw materials in parts by weight: 50 parts of n-butyl methacrylate, 30 parts of bifunctional bisphenol-A dimethacrylate, 5 parts of β-hydroxypropyl methacrylate Parts, 2.5 parts of a-hydroxy-cyclohexyl phenyl ketone, 1.5 parts of stabilizer, 1.5 parts of plasticizer, 35 parts of inorganic filler.

[0031] In this example, the surface of the inorganic filler is modified by an isolation modifier. The isolation modifier is a series of modifiers with double-terminal single epoxy functional groups, specifically ethylene glycol diglycidyl ethers with different molecular weights and molecular chain lengths. And its polymer, the isolation modifier is attached to the surface of the inorganic filler after being bonded by the terminal functional group, and the plurality of inorganic filler particles are isolated from each other by the isolation modifier on the surface.

[0032] In this embodiment, t...

Embodiment 2

[0042] A high wear-resistant composite resin for a denture base, comprising the following raw materials in parts by weight: 50 parts of n-butyl methacrylate, 30 parts of bifunctional bisphenol-A dimethacrylate, 5 parts of β-hydroxypropyl methacrylate Parts, 2.5 parts of a-hydroxy-cyclohexyl phenyl ketone, 1.5 parts of stabilizer, 1.5 parts of plasticizer, 36.5 parts of inorganic filler.

[0043]In this example, the surface of the inorganic filler is modified by an isolation modifier. The isolation modifier is a series of modifiers with double-terminal single epoxy functional groups, specifically ethylene glycol diglycidyl ethers with different molecular weights and molecular chain lengths. And its polymer, the isolation modifier is attached to the surface of the inorganic filler after being bonded by the terminal functional group, and the plurality of inorganic filler particles are isolated from each other by the isolation modifier on the surface.

[0044] In this embodiment, ...

Embodiment 3

[0054] A high wear-resistant composite resin for a denture base, comprising the following raw materials in parts by weight: 50 parts of n-butyl methacrylate, 30 parts of bifunctional bisphenol-A dimethacrylate, 5 parts of β-hydroxypropyl methacrylate Parts, 2.5 parts of a-hydroxy-cyclohexyl phenyl ketone, 1.5 parts of stabilizer, 1.5 parts of plasticizer, 37.5 parts of inorganic filler.

[0055] In this example, the surface of the inorganic filler is modified by an isolation modifier. The isolation modifier is a series of modifiers with double-terminal single epoxy functional groups, specifically ethylene glycol diglycidyl ethers with different molecular weights and molecular chain lengths. And its polymer, the isolation modifier is attached to the surface of the inorganic filler after being bonded by the terminal functional group, and the plurality of inorganic filler particles are isolated from each other by the isolation modifier on the surface.

[0056] In this embodiment,...

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Abstract

The invention relates to the technical field of oral medicine, and discloses a high-wear-resistance composite resin for a denture matrix. The composite resin is prepared from, by weight, 50 parts of n-butyl methacrylate, 30 parts of bifunctional bisphenol-A dimethacrylate, 5 parts of methacrylic acid beta-hydroxypropyl ester, 2.5 parts of alpha-hydroxy-cyclohexyl phenyl ketone, 1.5 parts of a stabilizer, 1.5 parts of a plasticizer and 35 parts of an inorganic filler. According to the high-wear-resistance composite resin for the denture matrix, and a preparation method thereof, provided by the invention, an isolation type modifier is innovatively utilized to perform surface modification on the inorganic filler, and the modifier with epoxy matrixes at two ends and hydroxyl groups on the surfaces of particles are adopted to form chemical bond acting force, so that a relatively strong network structure is formed among the particles; and due to strong interaction force between organic molecular chains in the composite resin and the inorganic filler, when the composite resin is chewed, the biting force does not cause mutual movement among particles of the inorganic filler, so that the wear resistance of the composite resin is greatly improved.

Description

technical field [0001] The patent of the present invention relates to the technical field of stomatology, in particular, to a high wear-resistant composite resin for a denture matrix and a preparation method thereof. Background technique [0002] Dentures are artificial dentures. Dentures are mainly composed of three parts: implants, abutments and artificial dentures. They are used to fix inside the oral cavity to make up for oral tooth defects. The loss of teeth will affect the function of pronunciation and chewing, and affect the appearance Sex, now there are many problems with the human oral cavity and teeth, and many people accept implant dentures to improve oral problems. [0003] After some existing denture bases are installed, the friction performance between them and the denture is limited. After long-term use, the teeth often chew, and the friction between the denture and the base is relatively large, and it is easy to loosen; through some nano-inorganic fillers (su...

Claims

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Application Information

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IPC IPC(8): A61K6/891A61K6/71A61K6/76A61K6/887A61K6/15A61K6/60
CPCA61K6/891A61K6/71A61K6/76A61K6/887A61K6/15A61K6/60C08L71/02C08L33/10
Inventor 郭科宏
Owner 深圳市一诺牙科技术有限公司